Letter, P. F. Johnes to Peleg Clarke Jr., March 9, 1864

This handwritten letter, dated March 9, 1864, is written from P. F. Johnes to Peleg Clarke Jr. informing Clarke that a receipt in his favor was located in Captain C. D. Robinson\u27s files for purchases made by Captain Springsteed.https://scholarsjunction.msstate.edu/fvw-manuscripts-clarke/1049/thumbnail.jp

Letter, P. F. Johnes to Peleg Clarke Jr., April 22, 1864

This handwritten letter, dated April 22, 1864, is written from P. F. Johnes to Peleg Clarke Jr., informing Clarke that Johnes will not be in Washington for quite some time and requests him to not send any money to the camp is army is moving to as it would be stolen.https://scholarsjunction.msstate.edu/fvw-manuscripts-clarke/1050/thumbnail.jp

Lakes - Classification & Monitoring: a strategy for the classification of lakes

This is the report on Lakes – Classification and Monitoring, a strategy for the classification of lakes by the National Rivers Authority. This report describes a scheme for the assessment and monitoring of water and ecological quality in standing waters, greater than about 1ha in area, in England and Wales although it is generally relevant to Northwest Europe. Thirteen hydrological, chemical and biological variables are used to characterize the standing water body in any current sampling. Statistical testing on the chemical variables showed that at least six samples during a year would be needed to produce a representative sampling mean; but in this scheme the choice of variables minimizes logistic cost by not using boat sampling and time costs by not demanding extensive taxonomic work. Standing waters are classified in a state-changed system in which the contemporary values of the variables are compared with a reference baseline state and then placed in categories of percentage change from this baseline. The scheme is presently designed for use at about five year intervals on all lakes greater than 2ha area plus additional lakes of significant amenity or conservation interest

Technical note: testing an improved index for analysing storm discharge-concentration hysteresis

Analysis of hydrochemical behaviour during storm events can provide new insights into the process controls on nutrient transport in catchments. The examination of storm behaviours using hysteresis analysis has increased in recent years, partly due to the increased availability of high temporal resolution data sets for discharge and water quality parameters. A number of these analyses involve the use of an index to describe the characteristics of a hysteresis loop in order to compare storm behaviours both within and between catchments. This technical note reviews the methods for calculation of the hysteresis index (HI) and explores a new more effective methodology. Each method is systematically tested and the impact of the chosen calculation on the results is examined. Recommendations are made regarding the most effective method of calculating a HI which can be used for comparing data between storms and between different water quality parameters and catchments

High-frequency monitoring of nitrogen and phosphorus response in three rural catchments to the end of the 2011–2012 drought in England

This paper uses high-frequency bankside measurements from three catchments selected as part of the UK government-funded Demonstration Test Catchments (DTC) project. We compare the hydrological and hydrochemical patterns during the water year 2011–2012 from the Wylye tributary of the River Avon with mixed land use, the Blackwater tributary of the River Wensum with arable land use and the Newby Beck tributary of the River Eden with grassland land use. The beginning of the hydrological year was unusually dry and all three catchments were in states of drought. A sudden change to a wet summer occurred in April 2012 when a heavy rainfall event affected all three catchments. The year-long time series and the individual storm responses captured by in situ nutrient measurements of nitrate and phosphorus (total phosphorus and total reactive phosphorus) concentrations at each site reveal different pollutant sources and pathways operating in each catchment. Large storm-induced nutrient transfers of nitrogen and or phosphorus to each stream were recorded at all three sites during the late April rainfall event. Hysteresis loops suggested transport-limited delivery of nitrate in the Blackwater and of total phosphorus in the Wylye and Newby Beck, which was thought to be exacerbated by the dry antecedent conditions prior to the storm. The high rate of nutrient transport in each system highlights the scale of the challenges faced by environmental managers when designing mitigation measures to reduce the flux of nutrients to rivers from diffuse agricultural sources. It also highlights the scale of the challenge in adapting to future extreme weather events under a changing climate

Short-term biotic removal of dissolved organic nitrogen (DON) compounds from soil solution and subsequent mineralisation in contrasting grassland soils

Cycling of low molecular weight dissolved organic nitrogen compounds constitutes an important component of soil organic matter turnover in soils. We determined how rapidly grassland soils can cycle urea, compared to the amino acid l-alanine, and the peptide l-trialanine. Using naturally occurring concentrations of 14C-labelled compounds the rates of removal from soil solution and subsequent mineralisation were measured. Biotic removal of all three compounds and subsequent mineralisation to CO2 occurred within minutes. This research has demonstrated, for the first time, the potential for rapid removal of urea at low concentrations by the soil microbial biomass

Rapid depletion of dissolved organic sulphur (DOS) in freshwaters

Sulphur (S) is a key macronutrient for all organisms, with similar cellular requirements to that of phosphorus (P). Studies of S cycling have often focused on the inorganic fraction, however, there is strong evidence to suggest that freshwater microorganisms may also access dissolved organic S (DOS) compounds (e.g. S-containing amino acids). The aim of this study was to compare the relative concentration and depletion rates of organic 35S-labelled amino acids (cysteine, methionine) with inorganic S (Na235SO4) in oligotrophic versus mesotrophic river waters draining from low nutrient input and moderate nutrient input land uses respectively. Our results showed that inorganic SO42− was present in the water column at much higher concentrations than free amino acids. In contrast to SO42−, however, cysteine and methionine were both rapidly depleted from the mesotrophic and oligotrophic waters with a halving time < 1 h. Only a small proportion of the DOS removed from solution was mineralized and excreted as SO42− (< 16% of the total taken up) suggesting that the DOS could be satisfying a demand for carbon (C) and S. In conclusion, even though inorganic S was abundant in freshwater, it appears that the aquatic communities retained the capacity to take up and assimilate DOS

Determining the Impact of Riparian Wetlands on Nutrient Cycling, Storage and Export in Permeable Agricultural Catchments

The impact of riparian wetlands on the cycling, retention and export of nutrients from land to water varies according to local environmental conditions and is poorly resolved in catchment management approaches. To determine the role a specific wetland might play in a catchment mitigation strategy, an alternative approach is needed to the high-frequency and spatially detailed monitoring programme that would otherwise be needed. Here, we present a new approach using a combination of novel and well-established geochemical, geophysical and isotope ratio methods. This combined approach was developed and tested against a 2-year high-resolution sampling programme in a lowland permeable wetland in the Lambourn catchment, UK. The monitoring programme identified multiple pathways and water sources feeding into the wetland, generating large spatial and temporal variations in nutrient cycling, retention and export behaviours within the wetland. This complexity of contributing source areas and biogeochemical functions within the wetland were effectively identified using the new toolkit approach. We propose that this technique could be used to determine the likely net source/sink function of riparian wetlands prior to their incorporation into any catchment management plan, with relatively low resource implications when compared to a full high-frequency nutrient speciation and isotope geochemistry-based monitoring approach

Impact of microbial activity on the leaching of soluble N forms in soil

The hydrological transport of low-molecular weight organic nitrogen (LMWON) compounds has received little attention in the literature, particularly relative to inorganic nitrogen (N), with less attention given to the decoupling of the carbon (C) and N cycles following rainfall events. We determined the impacts of the soil biota on the transport of N compounds in a loam soil, using 15N and 13C to trace the vertical transport of 15N13C-urea, 15N13C-amino acids, 15NO3, and 15NH4 through the soil profile, following simulated rainfall events. This research has demonstrated that biotic assimilation leads to rapid decoupling of the C and N cycles during leaching, with C transport limited to the soil surface (< 2 cm), whereas N which was stored within the soil profile during a single rainfall event could be remobilised and leached (a further 2–6 cm) following an additional rainfall event