698 research outputs found
Weather on Other Worlds. IV. H emission and photometric variability are not correlated in L0T8 dwarfs
Recent photometric studies have revealed that surface spots that produce flux
variations are present on virtually all L and T dwarfs. Their likely magnetic
or dusty nature has been a much-debated problem, the resolution to which has
been hindered by paucity of diagnostic multi-wavelength observations. To test
for a correlation between magnetic activity and photometric variability, we
searched for H emission among eight L3T2 ultra-cool dwarfs with
extensive previous photometric monitoring, some of which are known to be
variable at 3.6 m or 4.5 m. We detected H only in the
non-variable T2 dwarf 2MASS J125453930122474. The remaining seven objects do
not show H emission, even though six of them are known to vary
photometrically. Combining our results with those for 86 other L and T dwarfs
from the literature show that the detection rate of H emission is very
high (94) for spectral types between L0 and L3.5 and much smaller (20)
for spectral types L4, while the detection rate of photometric variability
is approximately constant (3055) from L0 to T8 dwarfs. We conclude
that chromospheric activity, as evidenced by H emission, and
large-amplitude photometric variability are not correlated. Consequently, dust
clouds are the dominant driver of the observed variability of ultra-cool dwarfs
at spectral types at least as early as L0.Comment: 12 pages, 4 figures, accepted for publication in Ap
Resonant tunneling through protected quantum dots at phosphorene edges
We theoretically investigate phosphorene zigzag nanorribons as a platform for
constriction engineering. In the presence of a constriction at the upper edge,
quantum confinement of edge protected states reveals resonant tunnelling
Breit-Wigner transmission peaks, if the upper edge is uncoupled to the lower
edge. Coupling between edges in thin constrictions gives rise to Fano-like and
anti-resonances in the transmission spectrum of the system.Comment: 8 pages,7 figure
Effects of group membership on the transmission of negative historical events
Los estudios muestran que la fuente de un rumor, o el que implica al endogrupo o exogrupo son aspectos fundamentales a tener en cuenta en cĂłmo las personas se enfrentan a la transmisiĂłn de informa-ciĂłn. Los tres trabajos que se presentan aunando los resultados de estudios lleva-dos a cabo sobre las emociones colecti-vas, los rumores y las variables que inci-den en su transmisiĂłn, y los mecanismos de defensa de las identidades sociales, analizarĂĄn la manera en la que los miem-bros de un grupo se enfrentan con hechos negativos para este mismo endogrupo
New properties of a bioinspired pyridine benzimidazole compound as a novel differential staining agent for endoplasmic reticulum and Golgi apparatus in fluorescence live cell imaging
IndexaciĂłn: Scopus.In this study, we explored new properties of the bioinspired pyridine benzimidazole compound B2 (2,4-di-tert-butyl-6-(3H-imidazo[4,5-c]pyridine-2-yl)phenol) regarding its potential use as a differential biomarker. For that, we performed 1D 1HNMR (TOCSY), UV-Vis absorption spectra in different organic solvents, voltammetry profile (including a scan-rate study), and TD-DFT calculations that including NBO analyses, to provide valuable information about B2 structure and luminescence. In our study, we found that the B2 structure is highly stable, where the presence of an intramolecular hydrogen bond (IHB) seems to have a crucial role in the stability of luminescence, and its emission can be assigned as fluorescence. In fact, we found that the relatively large Stokes Shift observed for B2 (around 175 nm) may be attributed to the stability of the B2 geometry and the strength of its IHB. On the other hand, we determined that B2 is biocompatible by cytotoxicity experiments in HeLa cells, an epithelial cell line. Furthermore, in cellular assays we found that B2 could be internalized by passive diffusion in absence of artificial permeabilization at short incubation times (15 min to 30 min). Fluorescence microscopy studies confirmed that B2 accumulates in the endoplasmic reticulum (ER) and Golgi apparatus, two organelles involved in the secretory pathway. Finally, we determined that B2 exhibited no noticeable blinking or bleaching after 1 h of continuous exposure. Thus, B2 provides a biocompatible, rapid, simple, and efficient way to fluorescently label particular organelles, producing similar results to that obtained with other well-established but more complex methods. © 2018 Llancalahuen, Fuentes, Carreño, ZĂșñiga, PĂĄez-HernĂĄndez, GacitĂșa, Polanco, Preite, Arratia-PĂ©rez and Otero.https://www.frontiersin.org/articles/10.3389/fchem.2018.00345/ful
A simulational and theoretical study of the spherical electrical double layer for a size-asymmetric electrolyte: the case of big coions
Monte Carlo simulations of a spherical macroion, surrounded by a
size-asymmetric electrolyte in the primitive model, were performed. We
considered 1:1 and 2:2 salts with a size ratio of 2 (i.e., with coions twice
the size of counterions), for several surface charge densities of the
macrosphere. The radial distribution functions, electrostatic potential at the
Helmholtz surfaces, and integrated charge are reported. We compare these
simulational data with original results obtained from the Ornstein-Zernike
integral equation, supplemented by the hypernetted chain/hypernetted chain
(HNC/HNC) and hypernetted chain/mean spherical approximation (HNC/MSA)
closures, and with the corresponding calculations using the modified
Gouy-Chapman and unequal-radius modified Gouy-Chapman theories. The HNC/HNC and
HNC/MSA integral equations formalisms show good concordance with Monte Carlo
"experiments", whereas the notable limitations of point-ion approaches are
evidenced. Most importantly, the simulations confirm our previous theoretical
predictions of the non-dominance of the counterions in the size-asymmetric
spherical electrical double layer [J. Chem. Phys. 123, 034703 (2005)], the
appearance of anomalous curvatures at the outer Helmholtz plane and the
enhancement of charge reversal and screening at high colloidal surface charge
densities due to the ionic size asymmetry.Comment: 11 pages, 7 figure
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