Investigating the mechanism of deep-focus earthquakes via in-situ acoustic emission experiments on Fe2SiO4 at high temperature and pressure

In subduction zones, earthquakes are thought to be associated with faulting that arises from phase transformations. In order to test the viability of this mechanism experimentally, it was necessary to make microseismic measurements while the mineral under investigation was subjected to the pressure and temperature (P,T) conditions corresponding to their environment at depth. A system has been developed capable of making in situ acoustic emission (AE) measurements on samples under P,T conditions representative of the upper mantle and transition zone. Experiments were performed in a 3000-ton multi-anvil press using an 18/11 octahedral cell with 6 piezoelectric transducers mounted on the rear side of the anvils. AE signals were collected at a sampling rate of 40 MHz using a triggered system and a data buffer for capturing full waveforms of AE events. The use of multiple transducers distributed in a microseismic array allowed for events to be located within the sample through manual or automatic arrival time picking and least squares inversion techniques. Uncertainty in location estimates was ~1mm. The multi-anvil apparatus constitutes an inherently noisy environment both acoustically and electrically, therefore methods of noise reduction were developed. This technique has been used to measure acoustic signals generated from the fracturing of quartz beads during high pressure deformation and to investigate the possibility that the phase transformation from olivine to spinel, known to occur in subduction zones, is associated with deep-focus earthquakes (300 – 690 km depth). The analog material fayalite (Fe2SiO4) was examined. Information about its synthesis and sintering is discussed. Results of AE experiments on samples under high pressure (P = 4-9 GPa) and high temperature (T = 773-1273 K) conditions in the spinel stability field, while experiencing deviatoric stress, showed acoustic events that locate within the sample in multiple experiments defined by the P,T envelope P = 3.8 – 8.4 GPa and T = 650 – 950 K. This is the first time an olivine→spinel structured transition in a silicate mineral has demonstrated macroscopic faulting and associated microstructures, as well acoustic activity, under conditions that would normally promote plastic deformation. The system was also used to detect liquid↔solid phase transformations in Hg by measuring the abrupt change in sound velocity due to the intrinsic change in velocity between phases, and a change in delay between the triggering of an amplitude threshold and the arrival of the waveform

Choosing the right nanoparticle size - designing novel ZnO electrode architectures for efficient dye-sensitized solar cells

A novel concept for constructing optimized ZnO-based photoanodes as integrative components of dye-sensitized solar cells (DSSCs) is realized by deploying differently sized nanoparticles, ranging from 2 to 10 nm, together with commercially available 20 nm nanoparticles. The 2 nm nanoparticles were used to construct an efficient buffer layer for transparent electrodes based on 10 nm nanoparticles, resulting in a relative increase of device efficiency from 1.8 to 3.0% for devices without and with a buffer layer, respectively. A mixture of 10 and 20 nm nanoparticles was optimized to maximize the diffuse reflection and to minimize the charge transport resistance in a light-scattering layer. This optimization resulted in a homogenous layer of more than 15 μm that provided a device efficiency of 3.3%. The buffer layer, transparent electrode, and light-scattering electrode, were then combined to give an overall efficiency of around 5%. Thus, this work demonstrates that varying the electrode architecture with nanoparticles of different diameters is a powerful strategy for improving the overall efficiency of ZnO-based DSSCs

Twisted-layer boron nitride ceramic with high deformability and strength

Moiré superlattices formed by twisted stacking in van der Waals materials have emerged as a new platform for exploring the physics of strongly correlated materials and other emergent phenomena. However, there remains a lack of research on the mechanical properties of twisted-layer van der Waals materials, owing to a lack of suitable strategies for making three-dimensional bulk materials. Here we report the successful synthesis of a polycrystalline boron nitride bulk ceramic with high room-temperature deformability and strength. This ceramic, synthesized from an onion-like boron nitride nanoprecursor with conventional spark plasma sintering and hot-pressing sintering, consists of interlocked laminated nanoplates in which parallel laminae are stacked with varying twist angles. The compressive strain of this bulk ceramic can reach 14% before fracture, about one order of magnitude higher compared with traditional ceramics (less than 1% in general), whereas the compressive strength is about six times that of ordinary hexagonal boron nitride layered ceramics. The exceptional mechanical properties are due to a combination of the elevated intrinsic deformability of the twisted layering in the nanoplates and the three-dimensional interlocked architecture that restricts deformation from propagating across individual nanoplates. The advent of this twisted-layer boron nitride bulk ceramic opens a gate to the fabrication of highly deformable bulk ceramics

to the source. The Purchasing Power Parity Debate

Originally propounded by the sixteenth-century scholars of the University of Salamanca, the concept of purchasing power parity (PPP) was revived in the interwar period in the context of the debate concerning the appropriate level at which to re-establish international exchange rate parities. Broadly accepted as a long-run equilibrium condition in the post-war period, it first was advocated as a short-run equilibrium by many international economists in the first few years following the breakdown of the Bretton Woods system in the early 1970s and then increasingly came under attack on both theoretical and empirical grounds from the late 1970s to the mid 1990s. Accordingly, over the last three decades, a large literature has built up that examines how much the data deviated from theory, and the fruits of this research have provided a deeper understanding of how well PPP applies in both the short run and the long run. Since the mid 1990s, larger datasets and nonlinear econometric methods, in particular, have improved estimation. As deviations narrowed between real exchange rates and PPP, so did the gap narrow between theory and data, and some degree of confidence in long-run PPP began to emerge again. In this respect, the idea of long-run PPP no

ALSUntangled #75: Portable neuromodulation stimulator therapy

Spurred by patient interest, ALSUntangled herein examines the potential of the Portable Neuromodulation Stimulator (PoNS™) in treating amyotrophic lateral sclerosis (ALS). The PoNS™ device, FDA-approved for the treatment of gait deficits in adult patients with multiple sclerosis, utilizes translingual neurostimulation to stimulate trigeminal and facial nerves via the tongue, aiming to induce neuroplastic changes. While there are early, promising data for PoNS treatment to improve gait and balance in multiple sclerosis, stroke, and traumatic brain injury, no pre-clinical or clinical studies have been performed in ALS. Although reasonably safe, high costs and prescription requirements will limit PoNS accessibility. At this time, due to the lack of ALS-relevant data, we cannot endorse the use of PoNS as an ALS treatment

Neotectonics of Puerto Rico and the Virgin Islands, Northeastern Caribbean, from GPS Geodesy

The boundary between the North American and Caribbean plates is characterized primarily by left-lateral motion along predominantly east-west striking faults. Seismicity and marine geophysical survey data are consistent with at least two, and possibly three, microplates in the diffuse boundary zone in the northeastern Caribbean: (1) the Gonave, (2) the Hispaniola, and (3) the Puerto Rico-northern Virgin Islands (PRVI). We discuss results from GPS geodetic measurements acquired since 1994 to test the microplate hypothesis, define PRVI translation and rotation within the boundary zone, and constrain PRVI neotectonics. GPS-derived velocities are analyzed with respect to both North American and Caribbean plate reference frames. Integrated displacements across PRVI are limited to a few millimeters per year, consistent with a rigid PRVI and permitting calculation of an average velocity for PRVI. The motions of PRVI relative to North America and the Caribbean are 16.9±1.1 mm/yr toward N68°E±3° (1σ) and 2.4±1.4 mm/yr toward S79°W±26° (1σ), respectively. In contrast with some recent models, ongoing rotation of PRVI about a nearby (\u3c 25° distant) vertical axis is not supported by the geodetic data. In addition, we argue against eastward tectonic escape of PRVI and favor a simple, progressive increase in velocity across the plate boundary zone, requiring that the summed magnitude of strike-slip fault slip rates will equal the total plate motion rate between the Caribbean and North America. GPS data are consistent with components of left-lateral strike-slip faulting along the Muertos trough south of Puerto Rico and shortening across the Puerto Rico trench. Comparison of GPS velocities for PRVI with respect to North America with total North America-Caribbean relative motion suggests up to 85% of North American-Caribbean plate motion is accommodated by the Puerto Rico trench and offshore faults north of Puerto Rico. Differences in GPS-derived velocities from Hispaniola and PRVI yield east-west extension across the N-S trending Mona rift of a few millimeters per year when estimated elastic strain accumulation effects along the north Hispaniola deformed belt and the Septentrional fault zone are considered. The opening rate implies an age of the Mona rift of 2–3 million years, agreeing with marine geophysical data that support a young age for the structure