Fracture of Carbon Nanotube - Amorphous Carbon Composites: Molecular Modeling

Carbon nanotubes (CNTs) are promising candidates for use as reinforcements in next generation structural composite materials because of their extremely high specific stiffness and strength. They cannot, however, be viewed as simple replacements for carbon fibers because there are key differences between these materials in areas such as handling, processing, and matrix design. It is impossible to know for certain that CNT composites will represent a significant advance over carbon fiber composites before these various factors have been optimized, which is an extremely costly and time intensive process. This work attempts to place an upper bound on CNT composite mechanical properties by performing molecular dynamics simulations on idealized model systems with a reactive forcefield that permits modeling of both elastic deformations and fracture. Amorphous carbon (AC) was chosen for the matrix material in this work because of its structural simplicity and physical compatibility with the CNT fillers. It is also much stiffer and stronger than typical engineering polymer matrices. Three different arrangements of CNTs in the simulation cell have been investigated: a single-wall nanotube (SWNT) array, a multi-wall nanotube (MWNT) array, and a SWNT bundle system. The SWNT and MWNT array systems are clearly idealizations, but the SWNT bundle system is a step closer to real systems in which individual tubes aggregate into large assemblies. The effect of chemical crosslinking on composite properties is modeled by adding bonds between the CNTs and AC. The balance between weakening the CNTs and improving fiber-matrix load transfer is explored by systematically varying the extent of crosslinking. It is, of course, impossible to capture the full range of deformation and fracture processes that occur in real materials with even the largest atomistic molecular dynamics simulations. With this limitation in mind, the simulation results reported here provide a plausible upper limit on achievable CNT composite properties and yield some insight on the influence of processing conditions on the mechanical properties of CNT composites

Determination of the Far-Infrared Cosmic Background Using COBE/DIRBE and WHAM Data

Determination of the cosmic infrared background (CIB) at far infrared wavelengths using COBE/DIRBE data is limited by the accuracy to which foreground interplanetary and Galactic dust emission can be modeled and subtracted. Previous determinations of the far infrared CIB (e.g., Hauser et al. 1998) were based on the detection of residual isotropic emission in skymaps from which the emission from interplanetary dust and the neutral interstellar medium were removed. In this paper we use the Wisconsin H-alpha Mapper (WHAM) Northern Sky Survey as a tracer of the ionized medium to examine the effect of this foreground component on determination of the CIB. We decompose the DIRBE far infrared data for five high Galactic latitude regions into H I and H-alpha correlated components and a residual component. We find the H-alpha correlated component to be consistent with zero for each region, and we find that addition of an H-alpha correlated component in modeling the foreground emission has negligible effect on derived CIB results. Our CIB detections and 2 sigma upper limits are essentially the same as those derived by Hauser et al. and are given by nu I_nu (nW m-2 sr-1) < 75, < 32, 25 +- 8, and 13 +- 3 at 60, 100, 140, and 240 microns, respectively. Our residuals have not been subjected to a detailed anisotropy test, so our CIB results do not supersede those of Hauser et al. We derive upper limits on the 100 micron emissivity of the ionized medium that are typically about 40% of the 100 micron emissivity of the neutral atomic medium. This low value may be caused in part by a lower dust-to-gas mass ratio in the ionized medium than in the neutral medium, and in part by a shortcoming of using H-alpha intensity as a tracer of far infrared emission.Comment: 38 pages, 8 figures. Accepted for publication in Ap

The future of food: scenarios and the effect on natural resource use in agriculture in 2050

Industrial Ecolog

Three-Year Wilkinson Microwave Anisotropy Probe (WMAP) Observations: Foreground Polarization

We present a full-sky model of polarized Galactic microwave emission based on three years of observations by the Wilkinson Microwave Anisotropy Probe (WMAP) at frequencies from 23 to 94 GHz. The model compares maps of the Stokes Q and U components from each of the 5 WMAP frequency bands in order to separate synchrotron from dust emission, taking into account the spatial and frequency dependence of the synchrotron and dust components. This simple two-component model of the interstellar medium accounts for at least 97% of the polarized emission in the WMAP maps of the microwave sky. Synchrotron emission dominates the polarized foregrounds at frequencies below 50 GHz, and is comparable to the dust contribution at 65 GHz. The spectral index of the synchrotron component, derived solely from polarization data, is -3.2 averaged over the full sky, with a modestly flatter index on the Galactic plane. The synchrotron emission has mean polarization fraction 2--4% in the Galactic plane and rising to over 20% at high latitude, with prominent features such as the North Galactic Spur more polarized than the diffuse component. Thermal dust emission has polarization fraction 1% near the Galactic center, rising to 6% at the anti-center. Diffuse emission from high-latitude dust is also polarized with mean fractional polarization 0.036 +/- 0.011.Comment: 9 pages with 8 figures. For higher quality figures, see the version posted at http://lambda.gsfc.nasa.gov/product/map/dr2/map_bibliography.cf

Low-Velocity Halo Clouds

Models that reproduce the observed high-velocity clouds (HVCs) also predict clouds at lower radial velocities that may easily be confused with Galactic disk (|z| < 1 kpc) gas. We describe the first search for these low-velocity halo clouds (LVHCs) using IRAS data and the initial data from the Galactic Arecibo L-band Feed Array survey in HI (GALFA-HI). The technique is based upon the expectation that such clouds should, like HVCs, have very limited infrared thermal dust emission as compared to their HI column density. We describe our 'displacement-map' technique for robustly determining the dust-to-gas ratio of clouds and the associated errors that takes into account the significant scatter in the infrared flux from the Galactic disk gas. We find that there exist lower-velocity clouds that have extremely low dust-to-gas ratios, consistent with being in the Galactic halo - candidate LVHCs. We also confirm the lack of dust in many HVCs with the notable exception of complex M, which we consider to be the first detection of warm dust in HVCs. We do not confirm the previously reported detection of dust in complex C. In addition, we find that most Intermediate- and Low-Velocity clouds that are part of the Galactic disk have a higher 60 micron/100 micron flux ratio than is typically seen in Galactic HI, which is consistent with a previously proposed picture in which fast-moving Galactic clouds have smaller, hotter dust grains.Comment: 30 pages, 7 figures. Accepted to the Ap

The Wilkinson Microwave Anisotropy Probe (WMAP) Source Catalog

We present the list of point sources found in the WMAP 5-year maps. The technique used in the first-year and three-year analysis now finds 390 point sources, and the five-year source catalog is complete for regions of the sky away from the galactic plane to a 2 Jy limit, with SNR > 4.7 in all bands in the least covered parts of the sky. The noise at high frequencies is still mainly radiometer noise, but at low frequencies the CMB anisotropy is the largest uncertainty. A separate search of CMB-free V-W maps finds 99 sources of which all but one can be identified with known radio sources. The sources seen by WMAP are not strongly polarized. Many of the WMAP sources show significant variability from year to year, with more than a 2:1 range between the minimum and maximum fluxes.Comment: 31 pages Latex with 4 embedded figures. Version accepted by the ApJ Supplement

Nine-Year Wilkinson Microwave Anisotropy Probe (WMAP) Observations: Cosmological Parameter Results

We present cosmological parameter constraints based on the final nine-year WMAP data, in conjunction with additional cosmological data sets. The WMAP data alone, and in combination, continue to be remarkably well fit by a six-parameter LCDM model. When WMAP data are combined with measurements of the high-l CMB anisotropy, the BAO scale, and the Hubble constant, the densities, Omegabh2, Omegach2, and Omega_L, are each determined to a precision of ~1.5%. The amplitude of the primordial spectrum is measured to within 3%, and there is now evidence for a tilt in the primordial spectrum at the 5sigma level, confirming the first detection of tilt based on the five-year WMAP data. At the end of the WMAP mission, the nine-year data decrease the allowable volume of the six-dimensional LCDM parameter space by a factor of 68,000 relative to pre-WMAP measurements. We investigate a number of data combinations and show that their LCDM parameter fits are consistent. New limits on deviations from the six-parameter model are presented, for example: the fractional contribution of tensor modes is limited to r<0.13 (95% CL); the spatial curvature parameter is limited to -0.0027 (+0.0039/-0.0038); the summed mass of neutrinos is <0.44 eV (95% CL); and the number of relativistic species is found to be 3.84+/-0.40 when the full data are analyzed. The joint constraint on Neff and the primordial helium abundance agrees with the prediction of standard Big Bang nucleosynthesis. We compare recent PLANCK measurements of the Sunyaev-Zel'dovich effect with our seven-year measurements, and show their mutual agreement. Our analysis of the polarization pattern around temperature extrema is updated. This confirms a fundamental prediction of the standard cosmological model and provides a striking illustration of acoustic oscillations and adiabatic initial conditions in the early universe.Comment: 32 pages, 12 figures, v3: Version accepted to Astrophysical Journal Supplement Series. Includes improvements in response to referee and community; corrected 3 entries in Table 10, (w0 & wa model). See the Legacy Archive for Microwave Background Data Analysis (LAMBDA): http://lambda.gsfc.nasa.gov/product/map/current/ for further detai