1,349 research outputs found
Elucidating the NuclearQuantum Dynamics of Intramolecular Double Hydrogen Transfer in Porphycene
We address the double hydrogen transfer (DHT) dynamics of the porphycene
molecule: A complex paradigmatic system where the making and breaking of
H-bonds in a highly anharmonic potential energy surface requires a quantum
mechanical treatment not only of the electrons, but also of the nuclei. We
combine density-functional theory calculations, employing hybrid functionals
and van der Waals corrections, with recently proposed and optimized
path-integral ring-polymer methods for the approximation of quantum vibrational
spectra and reaction rates. Our full-dimensional ring-polymer instanton
simulations show that below 100 K the concerted DHT tunneling pathway
dominates, but between 100 K and 300 K there is a competition between concerted
and stepwise pathways when nuclear quantum effects are included. We obtain
ground-state reaction rates of at 150 K
and at 100 K, in good agreement with
experiment. We also reproduce the puzzling N-H stretching band of porphycene
with very good accuracy from thermostatted ring-polymer molecular dynamics
simulations. The position and lineshape of this peak, centered at around 2600
cm and spanning 750 cm, stems from a combination of very strong
H-bonds, the coupling to low-frequency modes, and the access to -like
isomeric conformations, which cannot be appropriately captured with
classical-nuclei dynamics. These results verify the appropriateness of our
general theoretical approach and provide a framework for a deeper physical
understanding of hydrogen transfer dynamics in complex systems
Inhomogeneous electronic structure probed by spin-echo experiments in the electron doped high-Tc superconductor Pr_{1.85}Ce_{0.15}CuO_{4-y}
63Cu nuclear magnetic resonance (NMR) spin-echo decay rate (T_2^{-1})
measurements are reported for the normal and superconducting states of a single
crystal of Pr_{1.85}Ce_{0.15}CuO_{4-y} (PCCO) in a magnetic field B_0=9T over
the temperature range 2K<T<200K. The spin-echo decay rate is
temperature-dependent for T<55K, and has a substantial dependence on the radio
frequency (rf) pulse parameters below T~25K. This dependence indicates that
T_2^{-1} is strongly effected by a local magnetic field distribution that can
be modified by the rf pulses, including ones that are not at the nuclear Larmor
frequency. The low-temperature results are consistent with the formation of a
static inhomogeneous electronic structure that couples to the rf fields of the
pulses.Comment: 4 pages, 4 figure
Phase diagram of YBaCuO at TT based on Cu(2) transverse nuclear relaxation
Two maxima in transverse relaxation rate of Cu(2) nuclei in
YBaCuO are observed, at T = 35 K and T = 47 K. Comparison of
the Cu(2) and Cu(2) rates at T = 47 K indicates the magnetic
character of relaxation. The enhancement at T = 47 K of fluctuating local
magnetic fields perpendicular to the CuO planes is connected with the
critical fluctuations of orbital currents. Maximum at T = 35 K is connected
with the appearance of inhomogeneous supeconducting phase. Together with data
published to date, our experimental results allow to suggest a qualitatively
new phase diagram of the superconducting phase.Comment: 4 LaTEX pages + 3 figures in *.ps forma
High-resolution microwave frequency dissemination on an 86-km urban optical link
We report the first demonstration of a long-distance ultra stable frequency
dissemination in the microwave range. A 9.15 GHz signal is transferred through
a 86-km urban optical link with a fractional frequency stability of 1.3x10-15
at 1 s integration time and below 10-18 at one day. The optical link phase
noise compensation is performed with a round-trip method. To achieve such a
result we implement light polarisation scrambling and dispersion compensation.
This link outperforms all the previous radiofrequency links and compares well
with recently demonstrated full optical links.Comment: 11 pages, 5 figure
Stripe order, depinning, and fluctuations in LaBaCuO and LaBaSrCuO
We present a neutron scattering study of stripe correlations measured on a
single crystal of LaBaCuO. Within the
low-temperature-tetragonal (LTT) phase, superlattice peaks indicative of spin
and charge stripe order are observed below 50 K. For excitation energies
meV, we have characterized the magnetic excitations that
emerge from the incommensurate magnetic superlattice peaks. In the ordered
state, these excitations are similar to spin waves. Following these excitations
as a function of temperature, we find that there is relatively little change in
the {\bf Q}-integrated dynamical spin susceptibility for
meV as stripe order disappears and then as the structure transforms from LTT to
the low-temperature-orthorhombic (LTO) phase. The {\bf Q}-integrated signal at
lower energies changes more dramatically through these transitions, as it must
in a transformation from an ordered to a disordered state. We argue that the
continuous evolution through the transitions provides direct evidence that the
incommensurate spin excitations in the disordered state are an indicator of
dynamical charge stripes. An interesting feature of the thermal evolution is a
variation in the incommensurability of the magnetic scattering. Similar
behavior is observed in measurements on a single crystal of
LaBaSrCuO; maps of the scattered intensity
in a region centered on the antiferromagnetic wave vector and measured at
meV are well reproduced by a model of disordered stripes with a
temperature-dependent mixture of stripe spacings. We discuss the relevance of
our results to understanding the magnetic excitations in cuprate
superconductors.Comment: 12 pages, 11 figures, 1 tabl
On the exciton binding energy in a quantum well
We consider a model describing the one-dimensional confinement of an exciton
in a symmetrical, rectangular quantum-well structure and derive upper and lower
bounds for the binding energy of the exciton. Based on these bounds, we
study the dependence of on the width of the confining potential with a
higher accuracy than previous reports. For an infinitely deep potential the
binding energy varies as expected from at large widths to at
small widths. For a finite potential, but without consideration of a mass
mismatch or a dielectric mismatch, we substantiate earlier results that the
binding energy approaches the value for both small and large widths,
having a characteristic peak for some intermediate size of the slab. Taking the
mismatch into account, this result will in general no longer be true. For the
specific case of a quantum-well
structure, however, and in contrast to previous findings, the peak structure is
shown to survive.Comment: 32 pages, ReVTeX, including 9 figure
Josephson Plasma in RuSr2GdCu2O8
Josephson plasma in RuSrGdCuO,
RuSrGdCuO (x = 0.3), and
RuSrEuCeCuO (x = 0.5) compounds is
investigated by the sphere resonance method. The Josephson plasma is observed
in a low-frequency region (around 8.5 cm at T ) for
ferromagnetic RuSrGdCuO, while it increases to 35 cm
for non-ferromagnetic RuSrGdCuO (x = 0.3), which
represents a large reduction in the Josephson coupling at ferromagnetic
RuO block layers. The temperature dependence of the plasma does not shift
to zero frequency ({\it i.e.} = 0) at low temperatures, indicating that
there is no transition from the 0-phase to the -phase in these compounds.
The temperature dependence and the oscillator strength of the peak are
different from those of other non-magnetic cuprates, and the origins of these
anomalies are discussed.Comment: to appear in Phys. Rev.B Rapid Com
Faddeev calculations for the A=5,6 Lambda-Lambda hypernuclei
Faddev calculations are reported for Lambda-Lambda-5H, Lambda-Lambda-5He and
Lambda-Lambda-6He in terms of two Lambda hyperons plus the respective nuclear
clusters, using Lambda-Lambda central potentials considered in past non-Faddeev
calculations of Lambda-Lambda-6He. The convergence with respect to the
partial-wave expansion is studied, and comparison is made with some of these
Lambda-Lambda hypernuclear calculations. The Lambda-Lambda Xi-N mixing
effect is briefly discussed.Comment: submitted for publicatio
Measurement of the decay width of He
We have precisely measured decay width of \5LHe and
demonstrated significantly larger - overlap than expected
from the central repulsion - potential, which is derived from
YNG \Lambda$-nucleon interaction.Comment: 4 pages, 3 figure
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