Chromium recovery by membranes for process reuse in the tannery industry

Leather tanning is a wide common industry all over the world. In leather processing, water is one of the most important medium, almost 40-45 L water kg-1 raw-hide or skin is used by tanneries for processing finished leathers. The composition of tannery wastewater presents considerable dissimilarities in the concentration range of pollutants both of inorganic (chlorides, with concentration ranging from several hundred to over 10,000 mg L-1 Cl–; sulphate (VI), ammonium ions and sulphide ions, exhibiting concentration that ranges from tens to several hundred mg L-1) and organic (the COD value is usually several thousand mg L-1 O2). Throughout the years, many conventional processes have been carried out to treat wastewater from tannery industry: unfortunately, in this case, biological treatment methods give rise to an excessive production of sludge, whereas physical and chemical methods are too expensive in terms of energy and reagent costs. In this work, a membrane process based on NF membrane modules was adopted to treat the tannery feedstock after primary conventional treatment. In a first step, the determination of all boundary flux parameters, in order to inhibit severe fouling formation during operation, were performed. After this, experimental work was carried out to validate the approach. The target of water purification was reached, that is the legal discharge to municipal sewer system in Italy of 90% of the initial wastewater stream volume. This allows having an immediate cost saving of 21%. Moreover, the developed process leads to a second benefit, that is the production of 5% of the initial volume as a highly chromium-rich concentrate at no cost suitable to tannery process recycle and reuse. In this case, cost saving rates exceeds 40%. At the end, scale-up of the investigated process will be discussed from technical and economic point of view

Forgotten exogenous corticosteroid as a cause of central serous chorioretinopathy

Central serous chorioretinopathy (CSCR) is an idiopathic ocular condition – first described in 1866 – that is well known to ophthalmologists. It is less well known to other practitioners. Glucocorticoids have been strongly implicated as a pathogenic factor. We report three patients who developed CSCR following exogenous administration of corticosteroid. Because our patients did not suspect the use of corticosteroid to be important or causative, they did not volunteer the historical detail, and admitted to exogenous corticosteroid injection only with intensive questioning. For their part, physicians should be cognizant of the risk of corticosteroid-induced CSCR, particularly in patients with a prior history of the potentially sight-threatening disease. The development of CSCR is an important iatrogenic and often unrecognized side effect of exogenously administered corticosteroid

Active galactic nuclei synapses: X-ray versus optical classifications using artificial neural networks

(Abridged) Many classes of active galactic nuclei (AGN) have been defined entirely throughout optical wavelengths while the X-ray spectra have been very useful to investigate their inner regions. However, optical and X-ray results show many discrepancies that have not been fully understood yet. The aim of this paper is to study the "synapses" between the X-ray and optical classifications. For the first time, the new EFLUXER task allowed us to analyse broad band X-ray spectra of emission line nuclei (ELN) without any prior spectral fitting using artificial neural networks (ANNs). Our sample comprises 162 XMM-Newton/pn spectra of 90 local ELN in the Palomar sample. It includes starbursts (SB), transition objects (T2), LINERs (L1.8 and L2), and Seyferts (S1, S1.8, and S2). The ANNs are 90% efficient at classifying the trained classes S1, S1.8, and SB. The S1 and S1.8 classes show a wide range of S1- and S1.8-like components. We suggest that this is related to a large degree of obscuration at X-rays. The S1, S1.8, S2, L1.8, L2/T2/SB-AGN (SB with indications of AGN), and SB classes have similar average X-ray spectra within each class, but these average spectra can be distinguished from class to class. The S2 (L1.8) class is linked to the S1.8 (S1) class with larger SB-like component than the S1.8 (S1) class. The L2, T2, and SB-AGN classes conform a class in the X-rays similar to the S2 class albeit with larger fractions of SB-like component. This SB-like component is the contribution of the star-formation in the host galaxy, which is large when the AGN is weak. An AGN-like component seems to be present in the vast majority of the ELN, attending to the non-negligible fraction of S1-like or S1.8-like component. This trained ANN could be used to infer optical properties from X-ray spectra in surveys like eRosita.Comment: 15 pages, 7 figures, accepted for publication in A&A. Appendix B only in the full version of the paper here: https://dl.dropboxusercontent.com/u/3484086/AGNSynapsis_OGM_online.pd

Short-Term Effect of Daily Herbage Allowance Restriction on Pasture Condition and the Performance of Grazing Dairy Cows during Autumn

The aim of this study was to evaluate the short-term effects of daily herbage allowance (DHA, defined as the product of pre-grazing herbage mass and offered area per animal) on pasture conditions and milk production of Holstein-Friesian dairy cows. Forty-four early lactation dairy cows were randomly assigned to one of four treatments in a 2 × 2 factorial design that tested two levels of DHA (17 and 25 kg DM/cow.day) and two levels of maize silage supplementation (MSS, 4.5 and 9 kg DM/cow.day) over a 77-day period. Low DHA decreased the post-grazing herbage mass from 1546 to 1430 kg DM/ha and the compressed sward height from 5 to 4.4 cm, while the grazing efficiency remained unaffected. Low DHA induced a faster herbage mass reduction, while the sward-height and pasture characteristics did not differ from the high DHA regime. Low DHA decreased the tiller production rates and daily lamina growth, while the leaf-production rate was not affected by the DHA. Daily increases of herbage mass were greater in the high DHA than in the low DHA treatments. Individual milk production and milk protein concentration decreased at a low DHA compared to high DHA, while the milk fat concentration was greater and the milk output per hectare increased by 1510 kg. Neither the MSS level nor the interaction DHA by the MSS level had any effect on the sward characteristics or the productivity of the cows. From these results, it is suggested that,in a high-quality pasture, using 17 kg DM/cow.day was appropriate for improving both herbage utilization and milk production per hectare while maintaining the short-term conditions of a pasture grazed by dairy cows in the autumn

El populismo punitivo de los medios de comunicaci?n frente a la detenci?n preventiva del procesado en Colombia

62 p. Recurso Electr?nicoEn el presente art?culo de reflexi?n, se abordar? el tema del endurecimiento de las leyes hacia el sujeto procesal en el sistema penal punitivo, sobre la base del aumento de las penas y nuevas conductas delictivas, lo que se ha venido denominando como populismo punitivo; dicho fen?meno se encuentra apoyado por juicios sentenciadores dados por los medios masivos de comunicaci?n, quienes legitiman soluciones medi?ticas a los problemas sociales existentes y cuya pretensi?n es sosegar el clamor por la seguridad que exige la poblaci?n, difundiendo los m?s escandalosos casos judiciales; situaci?n que ha creado una falsa expectativa de lo que es la justicia, afectando por medio de la detenci?n preventiva de la libertad, m?ltiples derechos fundamentales tales como el buen nombre, honra y presunci?n de inocencia del procesado, al caer en juzgamientos anticipados, sin la prevalencia de principios constitucionales, sociales y penales; garantes del sistema acusatorio y acogidos por un Estado Social y Democr?tico de Derecho. Palabras Clave: libertad, poder, populismo punitivo, medios masivos de comunicaci?n, presunci?n de inocencia, honra, buen nombre.In the present article of reflection, will be approached the topic of the hardening of the laws towards the subject procedural in the punitive penal system, on the base of the increase of the penalties and new criminal conducts, which has been denominated like punitive populism; this phenomenon is supported by sentencing judgments given by the mass media, who legitimize media solutions to existing social problems whose aim is to calm the clamor for security demanded by the population, spreading the most scandalous court cases; a situation that has created a false expectation of what is justice, and affecting through the preventive detention of freedom, multiple fundamental rights such as the good name, honor and presumption of innocence of the defendant, to fall in anticipated judgments, without the prevalence of constitutional principles, social and criminal; guarantors of the accusatory system and welcomed by a Social and Democratic State of Law. Keywords: freedom, power, punitive populism, mass media, presumption of innocence, honor, good name

Infrared and optical polarimetry around the low-mass star-forming region NGC 1333 IRAS 4A

We performed J- and R-band linear polarimetry with the 4.2 m William Herschel Telescope at the Observatorio del Roque de los Muchachos and with the 1.6 m telescope at the Observat\'orio do Pico dos Dias, respectively, to derive the magnetic field geometry of the diffuse molecular cloud surrounding the embedded protostellar system NGC 1333 IRAS 4A. We obtained interstellar polarization data for about two dozen stars. The distribution of polarization position angles has low dispersion and suggests the existence of an ordered magnetic field component at physical scales larger than the protostar. Some of the observed stars present intrinsic polarization and evidence of being young stellar objects. The estimated mean orientation of the interstellar magnetic field as derived from these data is almost perpendicular to the main direction of the magnetic field associated with the dense molecular envelope around IRAS 4A. Since the distribution of the CO emission in NGC 1333 indicates that the diffuse molecular gas has a multi-layered structure, we suggest that the observed polarization position angles are caused by the superposed projection along the line of sight of different magnetic field components.Comment: 37 pages, 9 figures, 5 tables, accepted for publication in A

The nuclear and extended mid-infrared emission of Seyfert galaxies

We present subarcsecond resolution mid-infrared (MIR) images obtained with 8-10 m-class ground-based telescopes of a complete volume-limited (DL<40 Mpc) sample of 24 Seyfert galaxies selected from the Swift/BAT nine month catalog. We use those MIR images to study the nuclear and circumnuclear emission of the galaxies. Using different methods to classify the MIR morphologies on scales of ~400 pc, we find that the majority of the galaxies (75-83%) are extended or possibly extended and 17-25% are point-like. This extended emission is compact and it has low surface brightness compared with the nuclear emission, and it represents, on average, ~30% of the total MIR emission of the galaxies in the sample. We find that the galaxies whose circumnuclear MIR emission is dominated by star formation show more extended emission (650+-700 pc) than AGN-dominated systems (300+-100 pc). In general, the galaxies with point-like MIR morphologies are face-on or moderately inclined (b/a~0.4-1.0), and we do not find significant differences between the morphologies of Sy1 and Sy2. We used the nuclear and circumnuclear fluxes to investigate their correlation with different AGN and SF activity indicators. We find that the nuclear MIR emission (the inner ~70 pc) is strongly correlated with the X-ray emission (the harder the X-rays the better the correlation) and with the [O IV] lambda 25.89 micron emission line, indicating that it is AGN-dominated. We find the same results, although with more scatter, for the circumnuclear emission, which indicates that the AGN dominates the MIR emission in the inner ~400 pc of the galaxies, with some contribution from star formation.Comment: 27 pages, 12 figures, accepted by MNRA