Leather tanning is a wide common industry all over the
world. In leather processing, water is one of the most
important medium, almost 40-45 L water kg-1 raw-hide or
skin is used by tanneries for processing finished leathers.
The composition of tannery wastewater presents
considerable dissimilarities in the concentration range of
pollutants both of inorganic (chlorides, with concentration
ranging from several hundred to over 10,000 mg L-1 Cl–;
sulphate (VI), ammonium ions and sulphide ions,
exhibiting concentration that ranges from tens to several
hundred mg L-1) and organic (the COD value is usually
several thousand mg L-1 O2). Throughout the years, many
conventional processes have been carried out to treat
wastewater from tannery industry: unfortunately, in this
case, biological treatment methods give rise to an
excessive production of sludge, whereas physical and
chemical methods are too expensive in terms of energy and
reagent costs. In this work, a membrane process based on
NF membrane modules was adopted to treat the tannery
feedstock after primary conventional treatment. In a first
step, the determination of all boundary flux parameters, in
order to inhibit severe fouling formation during operation,
were performed. After this, experimental work was carried
out to validate the approach. The target of water
purification was reached, that is the legal discharge to
municipal sewer system in Italy of 90% of the initial
wastewater stream volume. This allows having an
immediate cost saving of 21%. Moreover, the developed
process leads to a second benefit, that is the production of
5% of the initial volume as a highly chromium-rich
concentrate at no cost suitable to tannery process recycle
and reuse. In this case, cost saving rates exceeds 40%. At
the end, scale-up of the investigated process will be
discussed from technical and economic point of view
