13 research outputs found

    Detecting initial aragonite and calcite variations in limestoneā€“marl alternations

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    Limestoneā€“marl alternations are commonly used for high-resolution cyclostratigraphic studies and palaeoenvironmental reconstructions, but diagenetic studies indicate that not all limestoneā€“marl alternations reflect genuine differences in the initial sediment composition driven by environmental changes. Differences in the ratios of diagenetically inert trace elements between limestones and marls indicate changes affecting the terrigenous fraction of the precursor sediment. Contrarily, limestoneā€“marl alternations without these differences can be the product of: (i) variations in CaCO3 input (aragonite, calcite); (ii) distortion of the latter by diagenetic CaCO3 redistribution; or (iii) diagenetic CaCO3 redistribution in a homogeneous precursor sediment. The aim of this study is to provide a method to differentiate these cases and to identify variations in the proportion of calcite and aragonite in the precursor sediment composition. The model of differential diagenesis assumes that the concentration of diagenetically inert elements is inversely proportional to the amount of redistributed CaCO3. Consequently, the difference between ratios of diagenetically inert elements from two adjacent beds is a measure for CaCO3 redistribution. This is quantifiable by the vector length between ratios from two adjacent beds. The approach is illustrated here by evaluation of a case study from the Silurian of Gotland, Sweden. Trace elements were compared according to their solubility during diagenesis. All elements bound to clay minerals or calcite show similar patterns of vector length, while vector length of elements which fit into the aragonite lattice, and are diagenetically mobile, differ. The vector length approach provides a tool to test the diagenetic origin of limestoneā€“marl alternations, to identify initial variations in CaCO3 input and to test a limestoneā€“marl alternationā€™s suitability for cyclostratigraphic analyses

    Brackish water algal reefs ā€“ facies analysis as a tool to identify palaeoenvironmental variations in Miocene deposits (Mainzā€Weisenau, Germany)

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    Brackishā€water carbonates are far less studied than their marine or limnic counterparts. However, their association with few, specialized species enables the documentation of fineā€scale changes in the depositional environment. The Cenozoic Mainz Basin (Germany) was only sporadically connected to the North Sea and the Paratethys, exposing several transitions from marine to fresh water influence. Focusing on one outcrop of the RĆ¼ssingen Formation of Mainzā€Weisenau (Aquitanian, Miocene), we present a detailed analysis of the faunal and sedimentological responses to changing salinities and water depth, including algal reef growth and facies development. The deposits include allochthonous limestones surrounding an autochthonous reef complex and several smaller reef patches. The allochthonous facies is dominated by the gastropod Hydrobia inflata, and the reef facies is mainly made up by the green alga Cladophorites sp. The algal thalli are overgrown by cryptocrystalline, organic precipitations, and laminated, chemical precipitations. Locally, quiverā€shaped structures of Trichoptera sp. protective cases occur. The depositional setting was a shallow, low energy, and brackish environment supersaturated by carbonate. We could not confirm a general trend of reducing salinities as reported for the RĆ¼ssingen Formation. Our results question previously reported episodic desiccation events, because apparent caliche horizons actually represent thin beds of increased Cladophorites growth. Setā€up, distribution of the reef facies, and reef debris indicate shortā€time variations of temperature, salinity and water depth. We conclude that these variations are based on the geographic position at the edge of an algal reef barrier, separating the Mainz Basin from the Rhine Rift Valley.This study investigates the record of smallā€scale changes in the depositional environment of Miocene brackishā€water deposits from the Mainz Basin (Germany) by facies analysis. Setā€up, distribution of the reef facies, and reef debris indicate shortā€time variations of temperature, salinity and water depth. The apparent caliche horizons actually represent thin beds of increase Cladophorites growth. The example demonstrates that these brackish deposits are a sensitive recorder of palaeoenvironmental change.Open access funding enabled and organized by Projekt DEAL. WOA Institution: FRIEDRICHā€ALEXANDERā€UNIVERSITAET ERLANGENā€NURNBERG Blended DEAL: ProjektDEA

    Detecting initial aragonite and calcite variations in limestoneā€“marl alternations

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    Limestoneā€“marl alternations are commonly used for high-resolution cyclostratigraphic studies and palaeoenvironmental reconstructions, but diagenetic studies indicate that not all limestoneā€“marl alternations reflect genuine differences in the initial sediment composition driven by environmental changes. Differences in the ratios of diagenetically inert trace elements between limestones and marls indicate changes affecting the terrigenous fraction of the precursor sediment. Contrarily, limestoneā€“marl alternations without these differences can be the product of: (i) variations in CaCO3 input (aragonite, calcite); (ii) distortion of the latter by diagenetic CaCO3 redistribution; or (iii) diagenetic CaCO3 redistribution in a homogeneous precursor sediment. The aim of this study is to provide a method to differentiate these cases and to identify variations in the proportion of calcite and aragonite in the precursor sediment composition. The model of differential diagenesis assumes that the concentration of diagenetically inert elements is inversely proportional to the amount of redistributed CaCO3. Consequently, the difference between ratios of diagenetically inert elements from two adjacent beds is a measure for CaCO3 redistribution. This is quantifiable by the vector length between ratios from two adjacent beds. The approach is illustrated here by evaluation of a case study from the Silurian of Gotland, Sweden. Trace elements were compared according to their solubility during diagenesis. All elements bound to clay minerals or calcite show similar patterns of vector length, while vector length of elements which fit into the aragonite lattice, and are diagenetically mobile, differ. The vector length approach provides a tool to test the diagenetic origin of limestoneā€“marl alternations, to identify initial variations in CaCO3 input and to test a limestoneā€“marl alternationā€™s suitability for cyclostratigraphic analyses

    Palynomorphs, carbon isotopes and trace elements from Bodudd section in Gotland, Sweden and R codes to create age models

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    Bulk-rock carbon isotopes (d13C), redox-sensitive trace elements and carbonate content measured in the Bodudd section in Gotland, Sweden. The age of the section is Ludfordian (Ludlow, Silurian) and it was deposited on a tropical carbonate platform. Funded by Deutsche Forschungsgemeinschaft project JA 2718/3-1

    Detecting initial aragonite and calcite variations in limestoneā€“marl alternations

    No full text
    Limestoneā€“marl alternations are commonly used for high-resolution cyclostratigraphic studies and palaeoenvironmental reconstructions, but diagenetic studies indicate that not all limestoneā€“marl alternations reflect genuine differences in the initial sediment composition driven by environmental changes. Differences in the ratios of diagenetically inert trace elements between limestones and marls indicate changes affecting the terrigenous fraction of the precursor sediment. Contrarily, limestoneā€“marl alternations without these differences can be the product of: (i) variations in CaCO3 input (aragonite, calcite); (ii) distortion of the latter by diagenetic CaCO3 redistribution; or (iii) diagenetic CaCO3 redistribution in a homogeneous precursor sediment. The aim of this study is to provide a method to differentiate these cases and to identify variations in the proportion of calcite and aragonite in the precursor sediment composition. The model of differential diagenesis assumes that the concentration of diagenetically inert elements is inversely proportional to the amount of redistributed CaCO3. Consequently, the difference between ratios of diagenetically inert elements from two adjacent beds is a measure for CaCO3 redistribution. This is quantifiable by the vector length between ratios from two adjacent beds. The approach is illustrated here by evaluation of a case study from the Silurian of Gotland, Sweden. Trace elements were compared according to their solubility during diagenesis. All elements bound to clay minerals or calcite show similar patterns of vector length, while vector length of elements which fit into the aragonite lattice, and are diagenetically mobile, differ. The vector length approach provides a tool to test the diagenetic origin of limestoneā€“marl alternations, to identify initial variations in CaCO3 input and to test a limestoneā€“marl alternationā€™s suitability for cyclostratigraphic analyses
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