Adsorption-Induced Deformation of Mesoporous Solids

The Derjaguin - Broekhoff - de Boer theory of capillary condensation is employed to describe deformation of mesoporous solids in the course of adsorption-desorption hysteretic cycles. We suggest a thermodynamic model, which relates the mechanical stress induced by adsorbed phase to the adsorption isotherm. Analytical expressions are derived for the dependence of the solvation pressure on the vapor pressure. The proposed method provides a description of non-monotonic hysteretic deformation during capillary condensation without invoking any adjustable parameters. The method is showcased drawing on the examples of literature experimental data on adsorption deformation of porous glass and SBA-15 silica.Comment: 21 pages, 3 figure

Mechanical systems subjected to generalized nonholonomic constraints

We study mechanical systems subject to constraint functions that can be dependent at some points and independent at the rest. Such systems are modelled by means of generalized codistributions. We discuss how the constraint force can transmit an impulse to the motion at the points of dependence and derive an explicit formula to obtain the ``post-impact'' momentum in terms of the ``pre-impact'' momentum.Comment: 24 pages, no figure

Counting and computing regions of DD-decomposition: algebro-geometric approach

New methods for $D$-decomposition analysis are presented. They are based on topology of real algebraic varieties and computational real algebraic geometry. The estimate of number of root invariant regions for polynomial parametric families of polynomial and matrices is given. For the case of two parametric family more sharp estimate is proven. Theoretic results are supported by various numerical simulations that show higher precision of presented methods with respect to traditional ones. The presented methods are inherently global and could be applied for studying $D$-decomposition for the space of parameters as a whole instead of some prescribed regions. For symbolic computations the Maple v.14 software and its package RegularChains are used.Comment: 16 pages, 8 figure

Synchrony in networks of coupled non-smooth dynamical systems: extending the master stability function

The master stability function is a powerful tool for determining synchrony in high-dimensional networks of coupled limit cycle oscillators. In part, this approach relies on the analysis of a low-dimensional variational equation around a periodic orbit. For smooth dynamical systems, this orbit is not generically available in closed form. However, many models in physics, engineering and biology admit to non-smooth piece-wise linear caricatures, for which it is possible to construct periodic orbits without recourse to numerical evolution of trajectories. A classic example is the McKean model of an excitable system that has been extensively studied in the mathematical neuroscience community. Understandably, the master stability function cannot be immediately applied to networks of such non-smooth elements. Here, we show how to extend the master stability function to non-smooth planar piece-wise linear systems, and in the process demonstrate that considerable insight into network dynamics can be obtained. In illustration, we highlight an inverse period- doubling route to synchrony, under variation in coupling strength, in globally linearly coupled networks for which the node dynamics is poised near a homoclinic bifurcation. Moreover, for a star graph, we establish a mechanism for achieving so-called remote synchronisation (where the hub oscillator does not synchronise with the rest of the network), even when all the oscillators are identical. We contrast this with node dynamics close to a non-smooth Andronov–Hopf bifurcation and also a saddle node bifurcation of limit cycles, for which no such bifurcation of synchrony occurs

Rotating saddle trap as Foucault's pendulum

One of the many surprising results found in the mechanics of rotating systems is the stabilization of a particle in a rapidly rotating planar saddle potential. Besides the counterintuitive stabilization, an unexpected precessional motion is observed. In this note we show that this precession is due to a Coriolis-like force caused by the rotation of the potential. To our knowledge this is the first example where such force arises in an inertial reference frame. We also propose an idea of a simple mechanical demonstration of this effect.Comment: 13 pages, 9 figure

Decorated vertices with 3-edged cells in 2D foams: exact solutions and properties

The energy, area and excess energy of a decorated vertex in a 2D foam are calculated. The general shape of the vertex and its decoration are described analytically by a reference pattern mapped by a parametric Moebius transformation. A single parameter of control allows to describe, in a common framework, different types of decorations, by liquid triangles or 3-sided bubbles, and other non-conventional cells. A solution is proposed to explain the stability threshold in the flower problem.Comment: 13 pages, 17 figure

Heat Transfer Model of Hyporthermic Intracarotid Infusion of Cold Saline for Stroke Therapy

A 3-dimensional hemispheric computational brain model is developed to simulate infusion of cold saline in the carotid arteries in terms of brain cooling for stroke therapy. The model is based on the Pennes bioheat equation, with four tissue layers: white matter, gray matter, skull, and scalp. The stroke lesion is simulated by reducing blood flow to a selected volume of the brain by a factor of one-third, and brain metabolism by 50%. A stroke penumbra was also generated surrounding the core lesion (blood volume reduction 25%, metabolism reduction 20%). The finite difference method was employed to solve the system of partial differential equations. This model demonstrated a reduction in brain temperature, at the stroke lesion, to 32°C in less than 10 minutes

Cartesian approach for constrained mechanical system with three degree of freedom

In the history of mechanics, there have been two points of view for studying mechanical systems: The Newtonian and the Cartesian. According the Descartes point of view, the motion of mechanical systems is described by the first-order differential equations in the $N$ dimensional configuration space \textsc{Q}. In this paper we develop the Cartesian approach for mechanical systems with three degrees of freedom and with constraint which are linear with respect to velocity. The obtained results we apply to discuss the integrability of the geodesic flows on the surface in the three dimensional Euclidian space and to analyze the integrability of a heavy rigid body in the Suslov and the Veselov cases