160 research outputs found
A liberal versus an entrepreneurial university? How universities communicate their values
This study explores the extent to which universities declare their orientation to liberal and neoliberal values and how it reflects in the university’s mission. The research analyses the values declared by universities in Lithuania and shows that institutes of higher education demonstrate a balance between liberal and neoliberal ideas. In the process of globalisation, universities have become homogeneous, which has alarming implications for higher educa-tion in Lithuania. Despite the existence of a third way, the danger is that liberal values will gradually disappear over time
MÉTODO PARA DETERMINAÇÃO DE HEPTACLORO, ALDRIN, DIELDRIN E ENDRIN EM PRÓPOLIS
Desenvolveu-se método para determinação de Heptacloro,
Aldrin, Dieldrin e Endrin em própolis (sólida e solução). Após
homogeneização da amostra com Celite, a extração dos
pesticidas foi efetuada com hexano e o extrato purificado
em cartucho de Florisil. A eluição dos pesticidas foi realizada
com hexano:diclorometano (9:1 v/v) e o eluato concentrado
e analisado por cromatografia em fase gasosa com
detecção por captura de elétrons (CGDCE). A eficiência
do método proposto foi demonstrada pelos valores médios
de recuperação entre 79 e 100%, com valores de desvio
padrão relativo entre 2,7 e 16,6%, obtidos nas análises de
recuperação realizadas com amostras fortificadas nos
níveis 0,6 e 1,2 µg/g.
METHOD FOR THE DETERMINATION OF HEPTACHLOR, ALDRIN, DIELDRIN
AND ENDRIN IN PROPOLIS
Abstract
A method for the determination of Heptachlor, Aldrin, Dieldrin and Endrin in propolis (solid
and solution) was developed. After the samples homogenization with Celite the pesticides
extraction was carried out with hexane and the extract was purified in Florisil cartridge.
The pesticides elution was processed with hexane:dichloromethane (9:1 v/v) and the
concentrated eluate was analysed using gas-liquid chromatography with electron capture
detection (GCECD). The efficiency of the proposed method was demonstrated by
mean recoveries, ranging from 79 to 100% with relative standard deviation values
between 2.7 to 16.6%, obtained in the recovery analysis with fortified samples at levels
of 0.6 and 1.2 µg/
MSPD procedure combined with GC-MS for the determination of procymidone, bifenthrin, malathion and pirimicarb in honey
A method based on matrix solid-phase dispersion and gas chromatography-mass spectrometry to determine procymidone, malathion, bifenthrin and pirimicarb in honey is described. The best results were obtained using 1.0 g of honey, 1.0 g of silica-gel as dispersant sorbent and acetonitrile as eluting solvent. The method was validated by fortified honey samples at three concentration levels (0.2, 0.5 to 1.0 mg kg-1). Average recoveries (n=7) ranged from 54 to 84%, with relative standard deviations between 3.7 and 8.5%. Detection and quantification limits attained by the developed method ranged from 0.02 to 0.08 mg kg-1 and 0.07 to 0.25 mg kg-1 for the honey, respectively
Tropical peat as a versatile material for solid-phase extraction of pesticides from medicinal plant Cordia salicifolia
Natural peat was tested for solid-phase extraction of acephate, chlorpropham, pirimicarb, bifenthrin, tetradifon and phosalone from the medicinal plant Cordia salicifolia, using gas chromatography-mass spectrometry with selected ion monitoring (GC/MS, SIM). Considering that there are no Brazilian regulations concerning maximum permissible pesticide residue concentrations in medicinal herbs, recovery experiments were carried out (three replicates) at two arbitrary fortification levels (0.5 and 1.0 mg kg-1), resulting in recoveries ranging from 64% to 118% and relative standard deviations between 5.6% and 26.4% for peat sorbent. Detection and quantification limits for herb ranged from 0.10 to 0.15 mg kg-1 and from 0.15 to 0.25 mg kg-1, respectively, for the different pesticides studied. The developed method was linear over the range assayed, 0.1-5.0 μg g-1, with correlation coefficients ranging from 0.9975 to 0.9986 for all pesticides. Comparison between natural peat and conventional sorbent (neutral alumina) showed similar performance of peat for the six pesticides tested
OVICIDAL EFFECT OF PIPERACEAE SPECIES ON Biomphalaria glabrata, Schistosoma mansoni HOST
SUMMARY Schistosomiasis is a neglected disease with public health importance in tropical and subtropical regions. An alternative to the disease control is the use of molluscicides to eliminate or reduce the intermediate host snail population causing a reduction of transmission in endemic regions. In this study nine extracts from eight Piperaceae species were evaluated against Biomphalaria glabrata embryos at blastula stage. The extracts were evaluated in concentrations ranging from 100 to 10 mg/L. Piper crassinervium and Piper tuberculatum extracts were the most active (100% of mortality at 20 mg/L and 30 mg/L respectively)
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