Electron acceleration in a JET disruption simulation

Runaways are suprathermal electrons having sufficiently high energy to be continuously accelerated up to tens of MeV by a driving electric field [1]. Highly energetic runaway electron (RE) beams capable of damaging the tokamak first wall can be observed after a plasma disruption [2]. Therefore, it is of primary importance to fully understand their generation mechanisms in order to design mitigation systems able to guarantee safe tokamak operations. In a previous work, [3], a test particle tracker was introduced in the JOREK 3D non-linear MHD code and used for studying the electron confinement during a simulated JET-like disruption. It was found in [3] that relativistic electrons are not completely deconfined by the stochastic magnetic field taking place during the disruption thermal quench (TQ). This is due to the reformation of closed magnetic surfaces at the beginning of the current quench (CQ). This result was obtained neglecting the inductive electric field in order to avoid the unrealistic particle acceleration which otherwise would have happened due to the absence of collision effects. The present paper extends [3] analysing test electron dynamics in the same simulated JET-like disruption using the complete electric field. For doing so, a simplified collision model is introduced in the particle tracker guiding center equations. We show that electrons at thermal energies can become RE during or promptly after the TQ due to a combination of three phenomena: a first REs acceleration during the TQ due to the presence of a complex MHD-induced electric field, particle reconfinement caused by the fast reformation of closed magnetic surfaces after the TQ and a secondary acceleration induced by the CQ electric field

NIR-emission from Yb(III)- and Nd(III)-based complexes in the solid state sensitized by a ligand system absorbing in a broad UV and visible spectral window

In this contribution, we present the synthesis, characterization and spectroscopic investigation of the heteroleptic (R,R)-YbL1(tta) and (R,R)-NdL1(tta) complexes (with tta = 2-thenoyltrifluoroacetonate and L1 = N,N'-bis(2-(8-hydroxyquinolinate)methylidene)-1,2-(R,R or S,S)-cyclohexanediamine) in the solid state. The f-f metal-centered NIR luminescence emission of Nd(III) and Yb(III) is efficiently sensitized by both chromophoric ligands in a very broad range of wavelengths [from 250 to 600 nm, in the case of Nd(III) and from 250 to 650 nm, for Yb(III)]. A possible energy transfer mechanism is proposed: for (R,R)-NdL1(tta) complex a classical Ligand-to-Metal Energy Transfer (LMET) mechanism (antenna effect) is suggested, whilst in the case of the (R,R)-YbL1(tta) complex, the presence of a ligand-to-metal charge transfer (LMCT) state determines the sensitization of Yb(III) luminescence. We propose that this level is populated by the singlet and triplet excited states belonging to pi -> pi* and n -> pi* transitions of both ligands and it can transfer the excitation energy to F-2(5/2)

Non-linear Simulations of MHD Instabilities in Tokamaks Including Eddy Current Effects and Perspectives for the Extension to Halo Currents

The dynamics of large scale plasma instabilities can strongly be influenced by the mutual interaction with currents flowing in conducting vessel structures. Especially eddy currents caused by time-varying magnetic perturbations and halo currents flowing directly from the plasma into the walls are important. The relevance of a resistive wall model is directly evident for Resistive Wall Modes (RWMs) or Vertical Displacement Events (VDEs). However, also the linear and non-linear properties of most other large-scale instabilities may be influenced significantly by the interaction with currents in conducting structures near the plasma. The understanding of halo currents arising during disruptions and VDEs, which are a serious concern for ITER as they may lead to strong asymmetric forces on vessel structures, could also benefit strongly from these non-linear modeling capabilities. Modeling the plasma dynamics and its interaction with wall currents requires solving the magneto-hydrodynamic (MHD) equations in realistic toroidal X-point geometry consistently coupled with a model for the vacuum region and the resistive conducting structures. With this in mind, the non-linear finite element MHD code JOREK has been coupled with the resistive wall code STARWALL, which allows to include the effects of eddy currents in 3D conducting structures in non-linear MHD simulations. This article summarizes the capabilities of the coupled JOREK-STARWALL system and presents benchmark results as well as first applications to non-linear simulations of RWMs, VDEs, disruptions triggered by massive gas injection, and Quiescent H-Mode. As an outlook, the perspectives for extending the model to halo currents are described.Comment: Proceeding paper for Theory of Fusion Plasmas (Joint Varenna-Lausanne International Workshop), Varenna, Italy (September 1-5, 2014); accepted for publication in: to Journal of Physics: Conference Serie

On the efficient application of the repeated Richardson extrapolation technique to option pricing

Richardson extrapolation (RE) is a commonly used technique in financial applications for accelerating the convergence of numerical methods. Particularly in option pricing, it is possible to refine the results of several approaches by applying RE, in order to avoid the difficulties of employing slowly converging schemes. But the effectiveness of such a technique is fully achieved when its repeated version (RRE) is applied. Nevertheless, repeated RE received little attention in the financial literature; this is probably due to the necessity of paying special attention to the numerical aspects of its implementation, such as the choice of both the sequence of the stepsizes and the order of the method. In this contribution, we consider different numerical schemes for the valuation of American options and investigate the possibility of an appropriate application of RRE. As a result, we find that, in the analyzed approaches in which the convergence is monotonic, RRE can be used as an effective tool for improving the accuracy of the approximations

On the efficient application of the repeated Richardson extrapolation technique to option pricing

Richardson extrapolation (RE) is a commonly used technique in financial applications for accelerating the convergence of numerical methods. Particularly in option pricing, it is possible to refine the results of several approaches by applying RE, in order to avoid the difficulties of employing slowly converging schemes. But the effectiveness of such a technique is fully achieved when its repeated version (RRE) is applied. Nevertheless, its application in financial literature is pretty rare. This is probably due to the necessity to pay special attention to the numerical aspects of its implementation, such as the choice of both the sequence of the stepsizes and the order of the method. In this contribution, we consider several numerical schemes for the valuation of American options and investigate the possibility of an appropriate application of RRE. As a result, we find that, in the analyzed approaches in which the convergence is monotonic, RRE can be used as an effective tool for improving significantly the accuracy

Lanthanide-Based Complexes Containing a Chiral trans-1,2-Diaminocyclohexane (DACH) Backbone: Spectroscopic Properties and Potential Applications

In this minireview, we give an overview on the use of the chiral molecule trans-1,2-diaminocyclohexane (DACH) in several fields of application. This chiral backbone is present in a variety of metal complexes which are employed in (enantioselective) catalysis, chiral discrimination, molecular recognition and supramolecular chemistry. Metal extraction and biochemical and pharmaceutical applications also use the DACH molecule. This contribution is particularly focused on the interesting chemical-physical properties discussed so far in the literature concerning lanthanide-based complexes containing chiral ligands characterized by the presence of DACH in the structure. In particular, the interconnection between luminescence (total and circularly polarized), structure and thermodynamics of Eu(III), Tb(III) and Sm(III) complexes will be discussed also in light of their use as optical or chiroptical probes for the sensing of important analytes dissolved in aprotic and protic polar solvents. Several complexes show potential interest in the solid state as phosphors for light emitting devices or for the detection of volatile organic compounds

Au(III)-Proline derivatives exhibiting selective antiproliferative activity against HepG2/SB3 apoptosis-resistant cancer cells

This paper deals with the combination of a proline-based moiety with biologically active gold centers in the oxidation states +1 and +3. In particular, six Au(i)/(iii)-proline dithiocarbamato (DTC) complexes with general formulae [AuI2(DTC)(2)] and [(AuX2)-X-III(DTC)] (X = Cl, Br) are reported here. After the synthesis of the ligand and the complexes, all derivatives were characterized via several techniques and tested for their stability in DMSO/water media. This study was focused on the demonstration of a peculiar behavior of Au(iii)-DTC species in solution. Finally, the complexes were screened for their antiproliferative activity against 2 human cancer cell lines, namely HepG2 and HepG2/SB3, taken as models of hepatocellular carcinoma. The latter, chosen for its aggressiveness due to the upregulation of the anti-apoptotic protein SerpinB3, was selectively inhibited in terms of growth by some Au(iii)-DTC complexes

Resistência anti-helmíntica em ovinos na região do Médio Paranapanema, SP.

O objetivo deste trabalho foi determinar a eficácia de vários medicamentos antiparasitários contra nematóides gastrintestinais de ovinos na região do Médio Paranapanema, SP. Foi utilizado o teste de redução da contagem de ovos nas fezes (TRCOF) em cinco propriedades, com cinco princípios ativos: ivermectina, albendazol, levamisol, moxidectina e closantel, que foram comparados a um grupo controle, sem vermífugo. Foram feitas coproculturas para identificar o gênero/espécie dos parasitas. O TRCOF demonstrou que apenas em uma propriedade o levamisole apresentou 92% de eficácia, e, nesta mesma propriedade, o albendazole teve 87% de eficácia. Em outra propriedade, o closantel teve 87% de eficácia. Nas demais, nenhuma droga alcançou eficácia superior a 80%. O nematóide encontrado com maior frequência foi Haemonchus contortus, o verme mais prevalente e patogênico para os ovinos. Conclui-se que na região do Médio Paranapanema ocorre resistência anti-helmíntica múltipla do H. contortus