3,423 research outputs found
Balancing the Tradeoff between Profit and Fairness in Rideshare Platforms During High-Demand Hours
Rideshare platforms, when assigning requests to drivers, tend to maximize profit for the system and/or minimize waiting time for riders. Such platforms can exacerbate biases that drivers may have over certain types of requests. We consider the case of peak hours when the demand for rides is more than the supply of drivers. Drivers are well aware of their advantage during the peak hours and can choose to be selective about which rides to accept. Moreover, if in such a scenario, the assignment of requests to drivers (by the platform) is made only to maximize profit and/or minimize wait time for riders, requests of a certain type (e.g. from a non-popular pickup location, or to a non-popular drop-off location) might never be assigned to a driver. Such a system can be highly unfair to riders. However, increasing fairness might come at a cost of the overall profit made by the rideshare platform. To balance these conflicting goals, we present a flexible, non-adaptive algorithm, \lpalg, that allows the platform designer to control the profit and fairness of the system via parameters and respectively. We model the matching problem as an online bipartite matching where the set of drivers is offline and requests arrive online. Upon the arrival of a request, we use \lpalg to assign it to a driver (the driver might then choose to accept or reject it) or reject the request. We formalize the measures of profit and fairness in our setting and show that by using \lpalg, the competitive ratios for profit and fairness measures would be no worse than and respectively. Extensive experimental results on both real-world and synthetic datasets confirm the validity of our theoretical lower bounds. Additionally, they show that \lpalg under some choice of can beat two natural heuristics, Greedy and Uniform, on \emph{both} fairness and profit
Surface excitonic emission and quenching effects in ZnO nanowire/nanowall systems: limiting effects on device potential.
We report ZnO nanowire/nanowall growth using a two-step vapour phase transport method on a-plane sapphire. X-ray diffraction and scanning electron microscopy data establish that the nanostructures are vertically well-aligned with c-axis normal to the substrate, and have a very low rocking curve width. Photoluminescence data at low temperatures demonstrate the exceptionally high optical quality of these structures, with intense emission and narrow bound exciton linewidths. We observe a high energy excitonic emission at low temperatures close to the band-edge which we assign to the surface exciton in ZnO at ~ 3.366 eV, the first time this feature has been reported in ZnO nanorod systems. This assignment is consistent with the large surface to volume ratio of the nanowire systems and indicates that this large ratio has a significant effect on the luminescence even at low temperatures. The band-edge intensity decays rapidly with increasing temperature compared to bulk single crystal material, indicating a strong temperature-activated non-radiative mechanism peculiar to the nanostructures. No evidence is seen of the free exciton emission due to exciton delocalisation in the nanostructures with increased temperature, unlike the behaviour in bulk material. The use of such nanostructures in room temperature optoelectronic devices appears to be dependent on the control or elimination of such surface effects
Synthesis, Characterization and Performance Study of Phosphosilicate Gel-Sulfonated Poly (Ether Ether Ketone) Nanocomposite Membrane for Fuel Cell Application
Phosphosilicate gel – SPEEK (Sulfonated Poly Ether Ether Ketone) hybrid nanocomposite membranes
are proposed for performance enhancement of polymer electrolyte fuel cell. The nanocomposite membranes
are synthesized and characterized at 50 and 60 weight percent of inorganic loading. Phosphosilicate gel particles
of varying size (sub micro to nanometer) are synthesized using sol gel approach followed by grinding using
planetary ball mill for different time. Transmission Electron Microscopy (TEM) reveals less than 10 nm
particle size for 20 hr grinding. Nano composite membrane having inorganic particles of size less than 10 nm
exhibits higher values of proton conductivity, ion exchange capacity and water uptake compared to composite
membrane comprising of larger (400 nm and above) inorganic particles. The membrane is assembled with the
electrode in the unit cell and the polarization characteristics are measured at different operating temperatures.
Performance study reveals that between 70 to 80 C the membrane offers best performance in terms of
peak power generation and of allowable load current. For the same conditions 40-50 % nano-enhancement of
peak power generation is achieved by reducing the average gel particle size from sub micro to less than
10 nm. At medium temperature (between 70 to 80 C) the nanocomposite membrane offers more than 100 enhancement
of peak power generation compared to that generated by SPEEK membrane.
When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/2491
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Do laws influence the cost of real estate brokerage services? A state fixed effects approach
A FTC-DOJ study argues that state laws and regulations may inhibit the unbundling of real estate brokerage services in response to new technology. Our data show that 18 states have changed laws in ways that promote unbundling since 2000. We model brokerage costs as measured by number of agents in a state-level annual panel vector autoregressive framework, a novel way of analyzing wasteful competition. Our findings support a positive relationship between brokerage costs and lagged house price and transactions. We find that change in full-service brokers responds negatively (by well over two percentage points per year) to legal changes facilitating unbundlin
Structural brain imaging correlates of ASD and ADHD across the lifespan:a hypothesis-generating review on developmental ASD-ADHD subtypes
Contains fulltext :
169832.pdf (publisher's version ) (Open Access)We hypothesize that it is plausible that biologically distinct developmental ASD-ADHD subtypes are present, each characterized by a distinct time of onset of symptoms, progression and combination of symptoms. The aim of the present narrative review was to explore if structural brain imaging studies may shed light on key brain areas that are linked to both ASD and ADHD symptoms and undergo significant changes during development. These findings may possibly pinpoint to brain mechanisms underlying differential developmental ASD-ADHD subtypes. To this end we brought together the literature on ASD and ADHD structural brain imaging symptoms and particularly highlight the adolescent years and beyond. Findings indicate that the vast majority of existing MRI studies has been cross-sectional and conducted in children, and sometimes did include adolescents as well, but without explicitly documenting on this age group. MRI studies documenting on age effects in adults with ASD and/or ADHD are rare, and if age is taken into account, only linear effects are examined. Data from various studies suggest that a crucial distinctive feature underlying different developmental ASD-ADHD subtypes may be the differential developmental thinning patterns of the anterior cingulate cortex and related connections towards other prefrontal regions. These regions are crucial for the development of cognitive/effortful control and socio-emotional functioning, with impairments in these features as key to both ASD and ADHD
Trabeculectomy with or without mitomycin-C for paediatric glaucoma in aphakia and pseudophakia following congenital cataract surgery
Characteristic studies on the biochars produced by hydro-thermal and steam gasification of canola hull and canola meal fuel pellets
Biochars, based on their production process and biomass precursor, can have a broad range of structural, compositional, chemical, and physical properties. These properties are important for identifying the biochar performance and stability in further applications. Non-food biomass has a great potential to produce biochars. Two inherent agricultural biomasses from Canadian prairies including canola hull and canola meal were used for the production of fuel pellets. This study provides information on the specific features of biochars produced by steam and hydro-thermal gasification of these fuel pellets compared with those of well-known pyrolysis biochars. For steam gasification, the steam to biomass ratio (SBR=0.31, 0.47, and 0.62) and gasification temperature (T=650, 750 and 850 oC) were used as the main process parameters. In contrast, for hydro-thermal (supercritical water) gasification, the effects of gasification temperature (T= 350, 450, 550, and 650 oC) were studied on the biochar properties at a constant pressure, feed concentration and reaction time. Different characterization techniques were used to study the physical, chemical, and structural characteristics of biochar products.
Characterization results, for steam-gasified biochars confirmed development of aromatic carbon structure and formation of composite char. XRD spectra for biochars produced through steam gasification showed no retention of biochemical features from the parent precursors in the biochars prepared in different levels of operating conditions. FTIR spectra confirmed the rearrangement of biomass structure at the early stages of steam gasification for all used operating conditions. Elemental analysis and Van Krevelen plot showed that for pellets, the H/C and O/C atomic ratios were in the range of biomass material. However, after gasification, the these atomic ratios for biochars were in the range of them for coal material, especially lignite coal. SEM analysis showed that steam-gasified biochars had much more cracked surface as compared with hydro-thermally prepared biochars. This observation was consistent with the results of porous characteristics for biochars which showed low BET surface area (\u3c11 \u3em2/g) for hydro-thermally produced biochars but it was much larger (\u3e 400 m2/g) for steam-gasified biochars. XRD results for hydro-thermally prepared biochars at 350 oC showed the presence of cellulose I and cellulose II in the material structure, but the related peaks were not observed for the biochar prepared at hydro-thermal gasification temperature of 650 oC. For prepared biochars prepared at the highest temperature of hydro-thermal gasification, Raman analysis showed a large change in ID/IG ratio compared with that for biochar prepared at temperature of 350 oC confirming a drastic structural change in biochar structure. Results from other characterization techniques such as XRD, ICP-MS, and thermogravimetric analysis will be also discussed in the presentation.
The degradation of biochars was progressive with the rise in hydro-thermal gasification temperature from 350 to 650°C. Hydro-thermally produced biochars showed characteristics of transition char at low temperature (350 oC as gasification temperature) and properties of amorphous char at high temperature (≥550 oC). For steam-gasified biochars, higher BET surface area indicated the development of composite char. It is noteworthy that characterization results showed that the steam-gasified biochars did not have the compact aromatic structure of turbostratic char and their aromatic structure is not developed as biochars produced via pyrolysis. However, properties of steam-gasified biochars showed their great potential for industrial applications such as adsorptive and/or catalytic applications. In addition, both types of biochars due to their mineral contents can be tested for agricultural applications(soil amendment and productivity)
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