Single-crystalline, wormlike hematite photoanodes for efficient solar water splitting

A hematite photoanode showing a stable, record-breaking performance of 4.32 mA/cm(2) photoelectrochemical water oxidation current at 1.23 V vs. RHE under simulated 1-sun (100 mW/cm(2)) irradiation is reported. This photocurrent corresponds to ca. 34% of the maximum theoretical limit expected for hematite with a band gap of 2.1 V. The photoanode produced stoichiometric hydrogen and oxygen gases in amounts close to the expected values from the photocurrent. The hematitle has a unique single-crystalline "wormlike" morphology produced by in-situ two-step annealing at 550 degrees C and 800 degrees C of beta-FeOOH nanorods grown directly on a transparent conducting oxide glass via an all-solution method. In addition, it is modified by platinum doping to improve the charge transfer characteristics of hematite and an oxygen-evolving co-catalyst on the surface.open2

INITIAL CHECKOUT RESULTS OF THE COMPACT INFRARED CAMERA (CIRC) FOR EARTH OBSERVATION

Compact Infrared Camera (CIRC) is a technology-demonstration instrument equipped with an uncooled infrared array detector (microbolometer) for space application. CIRC is the first microbolometer sensor without a calibration function in orbit, like a shutter system or an onboard blackbody. The main objective of the CIRC is to detect wildfires, which are major and chronic disasters affecting various countries of Southeast Asia, particularly considering the effects of global warming and climate change. The CIRC achieves a small size (approximately 200 mm), light mass (approximately 3 kg), and low electrical power consumption (<20 W) by employing athermal optics and a shutterless system. The CIRC can be consequently mounted on multiple satellites to enable highfrequency observation. Installation of CIRCs on the ALOS-2 and on the JEM/CALET is expected to increase observation frequency. We present the initial check-out results of the CIRC onboard ALOS-2. Since the initial check-out phase (July 4&ndash;14, 2014), the CIRC has acquired the images of Earth. CIRC was demonstrated to function according to its intended design. After the early calibration validation phase, which confirmed the temperature accuracy of observed data, CIRC data has been available to the public January 2015 onward. We also introduce a few observational results about wildfire, volcanoes, and heat-island

Effective use of indigenous technology with particular reference to earth stabilised material for rural housing in Sindh

Earth was one of earliest materials used for construction of human shelters. In its raw state, it does not meet the basic physical properties required of a material for use in construction, i. e. compressive strength and durability (water resistance). The raw material can be stabilised to improve these properties through chemical, physical and mechanical methods. Chemical and physical methods involve mixing and compacting the earth with various materials to increase its compressive strength and reduce its propensity to shrink and swell. Mechanical methods of stabilisation involve only compaction of the raw material to produce blocks. Stabilised blocks have adequate compressive strength and durability for use in lowincome housing. They are also easy to handle, can be moulded to a variety of shapes and are suitable for use as structural blocks. The latest developments in the design of moulding machines means that stabilised blocks can be produced on-site at approximately half the cost of the next cheapest construction material (hollow concrete block). The most important consideration in the stabilisation process is the choice of material for mixing. The choice is based on three criteria: (i) composition of the earth, (ii) local availability of the stabilising material and (iii) cost of the stabilising material. For example, in terms of composition, earth with a high clay content, such as the samples used in this study from Sindh Province, Pakistan, was found unsuitable for construction purposes. This is because the clay minerals cause excessive shrinkage and expansion of the material. However, work conducted in this study found that the effects of clay can be mitigated by correcting particle size distribution and stabilisation. Specimens of stabilised material were produced to measure the affects of mixing various additives, including cement, lime, linseed oil, and calcium chloride, with earth. The key findings from research carried out on these specimens are: (a) Cement can not be used without correction of particle size distribution. (b) Previous research work has found lime to be the most effective stabiliser in terms of improving compressive strength. However, it was found that, in the case of the high clay content earth used in this study, cement provided better results. (c) In earth stabilised through correction of particle size distribution, linseed oil provided the most improvement to water resistance. (d) Calcium Chloride is not suitable for use as a stabiliser with earth containing a high proportion of clay minerals. This is because it reacts with the clay minerals to produce water. -(e) A comparative study of the cost and engineering benefits of various stabilised specimens showed that cement provides the greatest improvement to durability, but at the highest cost. Lime was found to be the best stabilising material for high clay content earth in terms of overall cost and engineering benefit. It provides adequate improvement to durability at low cost. Linseed oil was the cheapest stabilising material but, although greatly improving water resistance, it provided little improvement to compressive strength