Synthesis, physicochemical and photophysical characterization of 4-(1-Pyrenyl)-Butyl-α-d-mannopyranoside

Indexación: Web of Science; Scopus; Scielo.Glycolipids are biomolecules composed of a lipid chain (lipophilic) and a monosaccharide or oligosaccharide as hydrophilic group. Their chemical structure and biological role make them undoubtedly good candidates for a large and continuously growing number of biotechnological applications. Mannose is a carbohydrate present on membrane glycolipids of a wide number of pathogenic microorganisms (bacteria, fungi, protozoa, and viruses) and specifically recognized by several lectins. We synthesized a mannose derivative linked through a short methylene chain to a pyrene moiety which behaves as a surfactant, able to aggregate, and retains the photophysical properties of pyrene: showing comparable absorption and emission spectra, having lower fluorescence quantum yield and the ability to form excimer, and finally the ability to produce O-2((1)Delta(g)) with high quantum yields. Thus, this novel molecule would open future applications for detection (fluorescence) or inactivation (singlet oxygen) of bacterial pathogens, viruses, tumor cells, or particular cells.http://ref.scielo.org/pcn4d

Dissipative dynamics of an extended magnetic nanostructure: Spin necklace in a metallic environment

We study theoretically the dynamics of an ``xxz'' spin necklace coupled to a conduction electron sea, a model system for a nanostructure in a dissipative environment. We extract the long-time behavior via a mapping to a multichannel Coulomb gas problem followed by a scaling analysis. The strong quantum fluctuations of the necklace cause a nontrivial dependence of couplings on system size which we extract via an analysis involving the ``boundary condition changing operator'', and confirm via a detailed numerical evaluation of one case.Comment: 4 pages, 4 figure

Spin relaxation in Mn12-acetate

We present a comprehensive derivation of the magnetization relaxation in a Mn12-acetate crystal based on thermally assisted spin tunneling induced by quartic anisotropy and weak transverse magnetic fields. The overall relaxation rate as function of the magnetic field is calculated and shown to agree well with data including all resonance peaks. The Lorentzian shape of the resonances is also in good agreement with recent data. A generalized master equation including resonances is derived and solved exactly. It is shown that many transition paths with comparable weight exist that contribute to the relaxation process. Previously unknown spin-phonon coupling constants are calculated explicitly.Comment: 4 pages,4 EPS figures,LaTeX(europhys.sty);final version accepted for EP

Macroscopic Quantum Phase Interference in Antiferromagnetic Particles

The tunnel splitting in biaxial antiferromagnetic particles is studied with a magnetic field applied along the hard anisotropy axis. We observe the oscillation of tunnel splitting as a function of the magnetic field due to the quantum phase interference of two tunneling paths of opposite windings. The oscillation is similar to the recent experimental result with Fe}$_8$\textrm{\ molecular clusters.}Comment: 8 pages, 2 postscript figures, to appear in J. Phys.: Condes. Matte

Spheres, Deficit Angles and the Cosmological Constant

We consider compactifications of six dimensional gravity in four dimensional Minkowski or de Sitter space times a two dimensional sphere, S^2. As has been recently pointed out, it is possible to introduce 3-branes in these backgrounds with arbitrary tension without affecting the effective four dimensional cosmological constant, since its only effect is to induce a deficit angle in the sphere. We show that if a monopole like configuration of a 6D U(1) gauge field is used to produce the spontaneous compactification of the two extra dimensions in a sphere a fine tuning between brane and bulk parameters is reintroduced once the quantization condition for the gauge field is taken into account, so the 4D cosmological constant depends on the brane tension. This problem is absent if instead of the monopole we consider a four form field strength in the bulk to obtain the required energy-momentum tensor. Also, making use of the four form field, we generalize the solution to an arbitrary number of dimensions (\ge 6), keeping always four noncompact dimensions and compactifying the rest in a n-dimensional sphere. We show that a (n+1)-brane with arbitrary tension can be introduced in this background without affecting the effective 4D cosmological constant.Comment: 14 pages, LaTe

Conservation equation on braneworlds in six dimensions

We study braneworlds in six-dimensional Einstein-Gauss-Bonnet gravity. The Gauss-Bonnet term is crucial for the equations to be well-posed in six dimensions when non-trivial matter on the brane is included (the also involved induced gravity term is not significant for their structure), and the matching conditions of the braneworld are known. We show that the energy-momentum of the brane is always conserved, independently of any regular bulk energy-momentum tensor, contrary to the situation of the five-dimensional case.Comment: References added, minor changes, 3 pages, RevTeX, to app. in Class. Quant. Gra

Low-Temperature Quantum Relaxation in a System of Magnetic Nanomolecules

We argue that to explain recent resonant tunneling experiments on crystals of Mn$_{12}$ and Fe$_8$, particularly in the low-T limit, one must invoke dynamic nuclear spin and dipolar interactions. We show the low-$T$, short-time relaxation will then have a $\sqrt{t/\tau}$ form, where $\tau$ depends on the nuclear $T_2$, on the tunneling matrix element $\Delta_{10}$ between the two lowest levels, and on the initial distribution of internal fields in the sample, which depends very strongly on sample shape. The results are directly applicable to the $Fe_8$ system. We also give some results for the long-time relaxation.Comment: 4 pages, 3 PostScript figures, LaTe

Anisotropic Inflation and the Origin of Four Large Dimensions

In the context of (4+d)-dimensional general relativity, we propose an inflationary scenario wherein 3 spatial dimensions grow large, while d extra dimensions remain small. Our model requires that a self-interacting d-form acquire a vacuum expectation value along the extra dimensions. This causes 3 spatial dimensions to inflate, whilst keeping the size of the extra dimensions nearly constant. We do not require an additional stabilization mechanism for the radion, as stable solutions exist for flat, and for negatively curved compact extra dimensions. From a four-dimensional perspective, the radion does not couple to the inflaton; and, the small amplitude of the CMB temperature anisotropies arises from an exponential suppression of fluctuations, due to the higher-dimensional origin of the inflaton. The mechanism triggering the end of inflation is responsible, both, for heating the universe, and for avoiding violations of the equivalence principle due to coupling between the radion and matter.Comment: 24 pages, 2 figures; uses RevTeX4. v2: Minor changes and added references. v3: Improved discussion of slow-rol