A Fourier transform infrared trace gas and isotope analyser for atmospheric applications

Concern in recent decades about human impacts on Earth's climate has led to the need for improved and expanded measurement capabilities of greenhouse gases in the atmosphere. In this paper we describe in detail an in situ trace gas analyser based on Fourier Transform Infrared (FTIR) spectroscopy that is capable of simultaneous and continuous measurements of carbon dioxide (CO<sub>2</sub>), methane (CH<sub>4</sub>), carbon monoxide (CO), nitrous oxide (N<sub>2</sub>O) and <sup>13</sup>C in CO<sub>2</sub> in air with high precision. High accuracy is established by reference to measurements of standard reference gases. Stable water isotopes can also be measured in undried airstreams. The analyser is automated and allows unattended operation with minimal operator intervention. Precision and accuracy meet and exceed the compatibility targets set by the World Meteorological Organisation – Global Atmosphere Watch for baseline measurements in the unpolluted troposphere for all species except <sup>13</sup>C in CO<sub>2</sub>. <br><br> The analyser is mobile and well suited to fixed sites, tower measurements, mobile platforms and campaign-based measurements. The isotopic specificity of the optically-based technique and analysis allows its application in isotopic tracer experiments, for example in tracing variations of <sup>13</sup>C in CO<sub>2</sub> and <sup>15</sup>N in N<sub>2</sub>O. We review a number of applications illustrating use of the analyser in clean air monitoring, micrometeorological flux and tower measurements, mobile measurements on a train, and soil flux chamber measurements

Contributions of order O(mquark2){\cal O}(m_{\rm quark}^2) to Kℓ3K_{\ell 3} form factors and unitarity of the CKM matrix

The form factors for the $K_{\ell 3}$ semileptonic decay are computed to order $O(p^4)$ in generalized chiral perturbation theory. The main difference with the standard $O(p^4)$ expressions consists in contributions quadratic in quark masses, which are described by a single divergence-free low-energy constant, $A_3$. A new simultaneous analysis is presented for the CKM matrix element $V_{us}$, the ratio $F_K/F_{\pi}$, $K_{\ell 3}$ decay rates and the scalar form factor slope $\lambda_0$. This framework easily accommodates the precise value for $V_{ud}$ deduced from superallowed nuclear $\beta$-decays

Producing valid statistics when legislation, culture, and medical practices differ for births at or before the threshold of survival: Report of a European workshop

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πK\pi K Scattering in Three Flavour ChPT

We present the scattering lengths for the $\pi K$ processes in the three flavour Chiral Perturbation Theory (ChPT) framework at next-to-next-to-leading order (NNLO). The calculation has been performed analytically but we only include analytical results for the dependence on the low-energy constants (LECs) at NNLO due to the size of the expressions. These results, together with resonance estimates of the NNLO LECs are used to obtain constraints on the Zweig rule suppressed LECs at NLO, $L_4^r$ and $L_6^r$. Contrary to expectations from NLO order calculations we find them to be compatible with zero. We do a preliminary study of combining the results from $\pi\pi$ scattering, $\pi K$ scattering and the scalar form-factors and find only a marginal compatibility with all experimental/dispersive input data.Comment: 23 page

A global fit of ππ\pi\pi and πK\pi K elastic scattering in ChPT with dispersion relations

We apply the one-loop results of the $SU(3)_L\times SU(3)_R$ ChPT suplemented with the inverse amplitude method to fit the available experimental data on $\pi\pi$ and $\pi K$ scattering. With esentially only three parameters we describe accurately data corresponding to six different channels, namely $(I,J)=(0,0), (2,0), (1,1), (1/2,0), (3/2,0)$ and $(1/2,1)$. In addition we reproduce the first resonances of the $(1,1)$ and $(1/2,1)$ channel with the right mass corresponding to the $\rho$ and the $K^*(892)$ particles.Comment: 19 pages, 5 figures available on request, FT/UCM/10/9

pi-pi scattering in a QCD based model field theory

A model field theory, in which the interaction between quarks is mediated by dressed vector boson exchange, is used to analyse the pionic sector of QCD. It is shown that this model, which incorporates dynamical chiral symmetry breaking, asymptotic freedom and quark confinement, allows one to calculate $f_\pi$, $m_\pi$, $r_\pi$ and the partial wave amplitudes in $\pi$-$\pi$ scattering and obtain good agreement with the experimental data, with the latter being well described up to energies \mbox{$E\simeq 700$ MeV}.Comment: 23 Pages, 4 figures in PostScript format, PHY-7512-TH-93, REVTEX Available via anonymous ftp in /pub: login anonymou get pipi93.tex Fig1.ps Fig2.ps Fig3.ps Fig4.p

Isospin breaking corrections to low-energy pi-K scattering

We evaluate the matrix elements for the processes pi^0 K^0 -> pi^0 K^0 and pi^- K^+ -> pi^0 K^0 in the presence of isospin breaking terms at leading and next-to-leading order. As a direct application the releveant combination of the S-wave scattering lengths involved in the pion-kaon atom lifetime is determined. We discuss the sensitivity of the results with respect to the input parameters.Comment: 33 pages, plain latex, 2 figure

Chiral symmetry and the pion gas virial expansion

In this work we study the thermodynamic properties of the pion gas starting from the realistic elastic scattering phase-shifts obtained from Chiral Perturbation Theory and using the virial expansion. In particular we study the state equation and the behavior of the quark condensate as a function of the temperature and the density.Comment: 16 Pages, 12 figure

Isospin breaking in Kl4 decays

Data on Ke4 decays allow one to extract experimental information on the elastic pi pi scattering amplitude near threshold, and to confront the outcome of the analysis with predictions made in the framework of QCD. These predictions concern an isospin symmetric world, while experiments are carried out in the real world, where isospin breaking effects - generated by electromagnetic interactions and by the mass difference of the up and down quarks - are always present. We discuss the corrections required to account for these, so that a meaningful comparison with the predictions becomes possible. In particular, we note that there is a spectacular isospin breaking effect in Ke4 decays. Once it is taken into account, the previous discrepancy between NA48/2 data on Ke4 decays and the prediction of pi pi scattering lengths disappears.Comment: 33 pages, 12 figure

What π−π\pi-\pi Scattering Tells Us About Chiral Perturbation Theory

We describe a rearrangement of the standard expansion of the symmetry breaking part of the QCD effective Lagrangian that includes into each order additional terms which in the standard chiral perturbation theory ($\chi$PT) are relegated to higher orders. The new expansion represents a systematic and unambiguous generalization of the standard $\chi$PT, and is more likely to converge rapidly. It provides a consistent framework for a measurement of the importance of additional ``higher order'' terms whose smallness is usually assumed but has never been checked. A method of measuring, among other quantities, the QCD parameters $\hat{m}\langle\bar{q}q\rangle$ and the quark mass ratio $m_s/\hat{m}$ is elaborated in detail. The method is illustrated using various sets of available data. Both of these parameters might be considerably smaller than their respective leading order standard $\chi$PT values. The importance of new, more accurate, experimental information on low-energy $\pi-\pi$ scattering is stressed.Comment: RevTeX 62 pages (6 figures not added, request from any author), IPNO/TH 92-106, PURD-TH-93-0