Bioelectrochemical systems using microalgae − A concise research update

Excess consumption of energy by humans is compounded by environmental pollution, the greenhouse effect and climate change impacts. Current developments in the use of algae for bioenergy production offer several advantages. Algal biomass is hence considered a new bio−material which holds the promise to fulfil the rising demand for energy. Microalgae are used in effluents treatment, bioenergy production, high value added products synthesis and CO2 capture. This review summarizes the potential applications of algae in bioelectrochemically mediated oxidation reactions in fully biotic microbial fuel cells for power generation and removal of unwanted nutrients. In addition, this review highlights the recent developments directed towards developing different types of microalgae MFCs. The different process factors affecting the performance of microalgae MFC system and some technological bottlenecks are also addressed

A review of research trends in the enhancement of biomass-to-hydrogen conversion

Different types of biomass are being examined for their optimum hydrogen production potentials and actual hydrogen yields in different experimental set-ups and through different chemical synthetic routes. In this review, the observations emanating from research findings on the assessment of hydrogen synthesis kinetics during fermentation and gasification of different types of biomass substrates have been concisely surveyed from selected publications. This review revisits the recent progress reported in biomass-based hydrogen synthesis in the associated disciplines of microbial cell immobilization, bioreactor design and analysis, ultrasound-assisted, microwave-assisted and ionic liquid-assisted biomass pretreatments, development of new microbial strains, integrated production schemes, applications of nanocatalysis, subcritical and supercritical water processing, use of algae-based substrates and lastly inhibitor detoxification. The main observations from this review are that cell immobilization assists in optimizing the biomass fermentation performance by enhancing bead size, providing for adequate cell loading and improving mass transfer; there are novel and more potent bacterial and fungal strains which improve the fermentation process and impact on hydrogen yields positively; application of microwave irradiation and sonication and the use of ionic liquids in biomass pretreatment bring about enhanced delignification, and that supercritical water biomass processing and dosing with metal-based nanoparticles also assist in enhancing the kinetics of hydrogen synthesis. The research areas discussed in this work and their respective impacts on hydrogen synthesis from biomass are arguably standalone. Thence, further work is still required to explore the possibilities and techno-economic implications of combining these areas for developing robust and integrated biomass-to-hydrogen synthetic schemes

Biogas Production: Pretreatment Methods in Anaerobic Digestion

This volume covers the most cutting-edge pretreatment processes being used and studied today for the production of biogas during anaerobic digestion processes using different feedstocks, in the most efficient and economical methods possible. As an increasingly important piece of the "energy pie," biogas and other biofuels are being used more and more around the world in every conceivable area of industry and could be a partial answer to the energy problem and the elimination of global warming

Arsenic: An Overview of Applications, Health, and Environmental Concerns and Removal Processes

Arsenic is a toxic element and has been responsible for many accidental, occupational, deliberate, and therapeutic poisonings since its discovery in 1250. It occurs in natural waters as the arsenite As3+ and arsenate As5 + ions. The solubility of arsenite and arsenate compounds is relatively high so that these ions are readily transported through aqueous routes into the environment. Arsenic can be transferred from soils to crops and accumulates in various food crops and aquatic plants. The fascinating chemistry and toxicity potential make arsenic and its compounds of particular scientific interest and environmental concern. The conventional removal of heavy metals from wastewater, natural waters, and drinking water has only limited effects on arsenic removal. In this review, the main engineering and medical applications, salient health and environmental concerns, novel research on treatment for arsenic poisoning, and removal technologies for arsenic and their derivatives are discussed and enumerated with a view to pursue valuable applied research in order to protect the environment from arsenic toxicity

Natural Attenuation

This chapter contains sections titled: The Natural Attenuation and Sustainability Link Contaminant Transformation Under Natural Site Conditions Monitoring for Natural Attenuation Source Area Evaluation Quantitative Analysis of Natural Attenuation Data Concluding Not

Biohydrogen production and bioprocess enhancement : a review

This paper provides an overview of the recent advances and trends in research in the biological production of hydrogen (biohydrogen). Hydrogen from both fossil and renewable biomass resources is a sustainable source of energy that is not limited and of different applications. The most commonly used techniques of biohydrogen production, including direct biophotolysis, indirect biophotolysis, photo-fermentation and dark-fermentation, conventional or "modern" techniques are examined in this review. The main limitations inherent to biochemical reactions for hydrogen production and design are the constraints in reactor configuration which influence biohydrogen production, and these have been identified. Thereafter, physical pretreatments, modifications in the design of reactors, and biochemical and genetic manipulation techniques that are being developed to enhance the overall rates and yields of biohydrogen generation are revisited

Biohydrogen production and bioprocess enhancement : a review

This paper provides an overview of the recent advances and trends in research in the biological production of hydrogen (biohydrogen). Hydrogen from both fossil and renewable biomass resources is a sustainable source of energy that is not limited and of different applications. The most commonly used techniques of biohydrogen production, including direct biophotolysis, indirect biophotolysis, photo-fermentation and dark-fermentation, conventional or "modern" techniques are examined in this review. The main limitations inherent to biochemical reactions for hydrogen production and design are the constraints in reactor configuration which influence biohydrogen production, and these have been identified. Thereafter, physical pretreatments, modifications in the design of reactors, and biochemical and genetic manipulation techniques that are being developed to enhance the overall rates and yields of biohydrogen generation are revisited

CODEN: RJCABP BIOSORPTION CHARACTERISTICS OF Cr BIOSORPTION CHARACTERISTICS OF Cr 6+ FROM AQUEOUS SOLUTIONS BY PINUS SYLVESTRIS L. TIMBER FILLINGS

ABSTRACT Pinus Slyvestris L. timber fillings were boiled and utilized as a biosorbent for the removal of Cr 6+ from a synthetic wastewater. The Cr 6+ removal increased from 34.8% to 69.41% as biosorbent dosage increased from 3.0 to 8.0 g/L, while the uptake of Cr 6+ decreased from 6.09 mg/g to 4.78 mg/g as the biosorbent dosage increased from 3.0 to 8.0 g/L, when the initial Cr 6+ concentration was 50 mg/L. The experimental equilibrium data were well described by both the Langmuir and Dubinin-Radushkevich adsorption isotherm models. Based on R 2 values, the Langmuir model fitted the equilibrium biosorption data best, confirming monolayer adsorption of Cr 6+ onto the biosorbent surface. The biosorption kinetics of Cr 6+ was best described by pseudo-second-order kinetics since at all concentrations, the R 2 values were higher than the corresponding pseudo-first order values. The overall results indicated that P. Slyvestris L. is a promising biosorbent for Cr 6+ removal from dilute aqueous solutions

A review of research trends in the enhancement of biomass-to-hydrogen conversion

Different types of biomass are being examined for their optimum hydrogen production potentials and actual hydrogen yields in different experimental set-ups and through different chemical synthetic routes. In this review, the observations emanating from research findings on the assessment of hydrogen synthesis kinetics during fermentation and gasification of different types of biomass substrates have been concisely surveyed from selected publications. This review revisits the recent progress reported in biomass-based hydrogen synthesis in the associated disciplines of microbial cell immobilization, bioreactor design and analysis, ultrasound-assisted, microwave-assisted and ionic liquid-assisted biomass pretreatments, development of new microbial strains, integrated production schemes, applications of nanocatalysis, subcritical and supercritical water processing, use of algae-based substrates and lastly inhibitor detoxification. The main observations from this review are that cell immobilization assists in optimizing the biomass fermentation performance by enhancing bead size, providing for adequate cell loading and improving mass transfer; there are novel and more potent bacterial and fungal strains which improve the fermentation process and impact on hydrogen yields positively; application of microwave irradiation and sonication and the use of ionic liquids in biomass pretreatment bring about enhanced delignification, and that supercritical water biomass processing and dosing with metal-based nanoparticles also assist in enhancing the kinetics of hydrogen synthesis. The research areas discussed in this work and their respective impacts on hydrogen synthesis from biomass are arguably standalone. Thence, further work is still required to explore the possibilities and techno-economic implications of combining these areas for developing robust and integrated biomass-to-hydrogen synthetic schemes