Interfacial transport with mobile surface charges and consequences for ionic transport in carbon nanotubes

In this paper, we explore the effect of a finite surface charge mobility on the interfacial transport: conductance, streaming currents, electro- and diffusio-osmotic flows. We first show that the surface charge mobility modifies the hydrodynamic boundary condition for the fluid, which introduces a supplementary term depending on the applied electric field. In particular, the resulting slip length is found to decrease inversely with the surface charge. We then derive expressions for the various transport mobilities, high-lighting that the surface charge mobility merely moderates the amplification effect of interfacial slippage, to the noticeable exception of diffusio-osmosis and surface conductance. Our calculations, obtained within Poisson-Boltzmann framework, highlight the importance of non-linear electrostatic contributions to predict the small concentration/large charge limiting regimes for the transport mobilities. We discuss these predictions in the context of recent electrokinetic experiments with carbon nanotubes

Datos estratigráficos sobre la serie mesozica del río de las Juntas (Montillana, Zona Subbética, Granada)

Se describe un corte de la serie mesozoica correspondiente al dominio Subbético medio. Una abundante fauna de Amonites precisa la edad Aalenense-Bajocense de una colada volcánica submarina interestratificada en la serie

A biotechnological strategy for the valorization of cellulose through Levoglucosenone

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Toarcian GSSP candidate: the Peniche section at Ponta do Trovão

The Peniche section (Ponta do Trovão) in Portugal is presented as potential stratotype (GSSP) for the Pliensbachian/Toarcian boundary. The lithostratigraphic succession is described and the chronostratigraphy, based on ammonite assemblages, is presented; the change in foraminifera assemblages occurs later, only at the base of beds 16 (base of Semicelatum Subzone, Crosbeyi ? Horizon). An extensive bibliographical list of all scientific articles containing specific reference to this stratigraphic boundary, whether from the Lusitanian or Algarve basins, is also presented

Discrimination à longue distance des signatures vocales individuelles chez un oiseau chanteur : des contraintes de propagation au substrat neuronal

In communication systems, one of the biggest challenges is that the information encoded by the emitter is always modified before reaching the receiver, who has to process this altered information in order to recover the intended message. In acoustic communication particularly, the transmission of sound through the environment is a major source of signal degradation, caused by attenuation, absorption and reflections, all of which lead to decreases in the signal relative to the background noise. How animals deal with the need for exchanging information in spite of constraining conditions has been the subject of many studies either at the emitter or at the receiver's levels. However, a more integrated research about auditory scene analysis has seldom been used, and is needed to address the complexity of this process. The goal of my research was to use a transversal approach to study how birds adapt to the constraints of long distance communication by investigating the information coding at the emitter's level, the propagation-induced degradation of the acoustic signal, and the discrimination of this degraded information by the receiver at both the behavioral and neural levels. Taking into account the everyday issues faced by animals in their natural environment, and using stimuli and paradigms that reflected the behavioral relevance of these challenges, has been the cornerstone of my approach. Focusing on the information about individual identity in the distance calls of zebra finches Taeniopygia guttata, I investigated how the individual vocal signature is encoded, degraded, and finally discriminated, from the emitter to the receiver. This study shows that the individual signature of zebra finches is very resistant to propagation-induced degradation, and that the most individualized acoustic parameters vary depending on distance. Testing female birds in operant conditioning experiments, I showed that they are experts at discriminating between the degraded vocal signatures of two males, and that they can improve their ability substantially when they can train over increasing distances. Finally, I showed that this impressive discrimination ability also occurs at the neural level: we found a population of neurons in the avian auditory forebrain that discriminate individual voices with various degrees of propagation-induced degradation without prior familiarization or training. The finding of such a high-level auditory processing, in the primary auditory cortex, opens a new range of investigations, at the interface of neural processing and behaviorL'un des plus grands défis posés par la communication est que l'information codée par l'émetteur est toujours modifiée avant d'atteindre le récepteur, et que celui-ci doit traiter cette information altérée afin de recouvrer le message. Ceci est particulièrement vrai pour la communication acoustique, où la transmission du son dans l'environnement est une source majeure de dégradation du signal, ce qui diminue l'intensité du signal relatif au bruit. La question de savoir comment les animaux transmettent l'information malgré ces conditions contraignantes a été l'objet de nombreuses études, portant soit sur l'émetteur soit sur le récepteur. Cependant, une recherche plus intégrée sur l'analyse de scènes auditives est nécessaire pour aborder cette tâche dans toute sa complexité. Le but de ma recherche était d'utiliser une approche transversale afin d'étudier comment les oiseaux s'adaptent aux contraintes de la communication à longue distance, en examinant le codage de l'information au niveau de l'émetteur, les dégradations du signal acoustiques dues à la propagation, et la discrimination de cette information dégradée par le récepteur, au niveau comportemental comme au niveau neuronal. J'ai basé mon travail sur l'idée de prendre en compte les problèmes réellement rencontrés par les animaux dans leur environnement naturel, et d'utiliser des stimuli reflétant la pertinence biologique des problèmes posés à ces animaux. J'ai choisi de me focaliser sur l'information d'identité individuelle contenue dans le cri de distance des diamants mandarins (Taeniopygia guttata) et d'examiner comment la signature vocale individuelle est codée, dégradée, puis discriminée et décodée, depuis l'émetteur jusqu'au récepteur. Cette étude montre que la signature individuelle des diamants mandarins est très résistante à la propagation, et que les paramètres acoustiques les plus individualisés varient selon la distance considérée. En testant des femelles dans les expériences de conditionnement opérant, j'ai pu montrer que celles-ci sont expertes pour discriminer entre les signature vocales dégradées de deux mâles, et qu'elles peuvent s'améliorer en s'entraînant. Enfin, j'ai montré que cette capacité de discrimination impressionnante existe aussi au niveau neuronal : nous avons montré l'existence d'une population de neurones pouvant discriminer des voix individuelles à différent degrés de dégradation, sans entrainement préalable. Ce niveau de traitement évolué, dans le cortex auditif primaire, ouvre la voie à de nouvelles recherches, à l'interface entre le traitement neuronal de l'information et le comportemen

Henri Tintant face au problème "Science et Foi"

From an early age Henri Tintant was conforted with the problematic relationships between Science and Faith. After a traditional religious education, he took responsabilities within groups of teenagers and adults through scouting and the J. E. C. (an organisation of catholic students). In 1940 he was at Montpellier distributing unauthorised leaflets defending religious faith. But more significant is his intellectual contribution. He was an active and inspiring member of several workshops and in one in particumar initiated by the Catholic University of Lyon entitled : "From Naturalist to Theologians" where he would start a very fruitful and compelling intellectual collaboration with Father Gustave Martelet a jesuit theologian and a strong supporter of a permanent dialog with the scientists. Throughout the years they will gradually come to the conclusion of a necessary synergy between the scientific and the theologic approach when dealing with the mystery of religious faith . Even in the last months of his life, Henri Tintant was writing to his friendon the subject, with the same profound religious faith that brought him the serenity and the open mindness he has showed throughout his teaching and scientific career. His legacy will remain in two of his last thoughts: "Almost 50 years of scientific research have brought me a lot of pleausures and satisfactions but no answer to the essential questions. In my personal case, science and researching have not driven me away from my religious faith, on the contrary the helped me in my awareness of its utmost necessity". "Faithful to my religious belief, I am convinced that with the death, the inevitable human destiny, not everything disapears completely but another form of live, unimaginable for our limited minds, emerges, bearing in itself the perfect realization of all our hopes and desires"

Essai de biozonation du Domérien portugais

The biozonation of the portuguese Domerian is presented. This biozonation is based essentially on fauna from the following sections: S. Pedro de Muel, Peniche (Stokesi zone and lower part of the Margaritatus zone) and Brenha (Margaritatus and Spinatum zones). The distribution of the main fossil groups enabled an accurate division of the Stokesi zone into three horizons: Occidentale, Monestieri-Nitescens and Lusitanicum. In the Middle Domerian, the extension of the Ragazzonii horizon was reduced. An Elisa horizon was individualized at the top of the Upper Domerian

Les acanthopleurocératinés portugais et leurs relations avec les formes subboréales

The evolution of the Portuguese Acanthopleuroceratinae is similar to the celto-souabe succession such as it was described in the collects of the Cottards (Cher, France). A subspecies of one of the oldest Acanthopleuroceras (A. carinatum atlanticum) is abundant in the lower part of the Portuguese Ibex zone; this form is described here. The species is recognized in France by several nuclei associated with A. arietiforme (Cottards-22). Generally the similarity between the successive French and Portuguese populations (A. maugenesti, A. valdani, A. alisiense, junior synonym of A. lepidum TUTCHER and TRUEMAN, 1925), is very good. This fact suggests their specific identity. It is typical for A. lepidum of which the greatest populations allow the biometric comparaisons. In Portugal, the mesogean Tropidaceras are missing. This absence of the subboreal Acanthopleuroceras ancestors suggests the straight celto-souabe derivation of the Portuguese Acanthopleuroceras and not a similar local evolution. A. lepidum the last Acanthopleuroceras reaches the western coast of Canada (British Columbia) probably by the Arctic ocean

Microwave-Assisted Knoevenagel-Doebner Reaction: An Efficient Method for Naturally Occurring Phenolic Acids Synthesis

The common chemical method to synthesize Phenolic Acids (PAs) involves a relatively considerable energy intake. In order to solve this issue, microwave-assisted Knoevenagel-Doebner condensations were developed. Nevertheless, these synthetic procedures prove difficult to reproduce. Herein, we developed and optimized—by using a combination of a Design of Experiment and a standard optimization approach—a reliable procedure that converts naturally occuring p-hydroxybenzaldehydes into the corresponding PAs with conversions of 86–99% and in 85–97% yields