Impact des traitement de potabilisation sur le CODB et la distribution des substances humiques et non humiques de la matière organique naturelle

Cette étude a consisté à évaluer et à comparer l'impact des traitements de coagulation-floculation, ozonation et filtration sur charbon actif en grains sur la matière organique dissoute de différentes eaux de rivières et de retenues françaises en s'appuyant sur le suivi de deux paramètres principaux, la fraction biodégradable du carbone organique dissous (CODB) et la distribution des substances humiques et non humiques (établie sur la base d'un protocole de filtration en série sur résines XAD-8 et XAD-4 ).Dans le cas des eaux étudiées, la coagulation-floculation s'est accompagnée d'une diminution importante du COD, soit 38 à 70 %, impact qui se répercute dans des proportions équivalentes au niveau de sa fraction biodégradable soit 38 à 88%. Dans la majorité des cas, la clarification conduit à l'élimination préférentielle des substances humiques (définies comme hydrophobes), qui correspondent aux fractions de plus hautes masses moléculaires. Comparativement, et pour des taux supérieurs à 1 mg O3/mg C, l'ozonation entra"ne une réduction de la fraction des substances humiques qui se traduit par une augmentation de la fraction des substances non humiques et en particulier des substances hydrophiles non adsorbées sur résines XAD-8 et XAD-4. Cette modification, d'autant plus marquée que le taux d'ozone est important, s'accompagne d'une augmentation proportionnelle de la fraction biodégradable du COD. Le suivi en usine a montré que les taux d'ozone appliqués lors d'une interozonation modifient peu la nature du COD. Par contre, la filtration sur charbon actif en aval change de manière importante la distribution de la matière organique dissoute avec une augmentation relative de la fraction hydrophobe et des composés de faibles masses moléculaires apparentes (< 1 000 daltons).The goal of our study was to evaluate the impact of water treatment processes (i.e. coagulation- flocculation, ozonation and GAC filtration) on the natural organic matter (NOM) of various river and reservoir waters based on DOC and BDOC analyses and the determination of the humic/non humic NOM distribution (fractionation of the DOC at acidic pH using two successive XAD-8 and XAD-4 resin columns). Analyses carried out on ten French raw surface waters have shown that the BDOC fraction accounted for 11 to 38 % of the DOC. The humic/non humic distribution of the NOM varied slightly with the origin of the studied water. About 50 to 60 % of the DOC was found to be incorporated into the humic fraction (NOM adsorbed on the XAD-8 resin), the hydrophilic acids (adsorbed on the XAD-4 resin) accounted for 10 to 25 % of the DOC while the non adsorbed hydrophilic solutes (hydrophilic neutrals that constitute the XAD-8/XAD-4 effluent) represented 15 to 30 % of the DOC.Clarified water samples were collected from water treatment plants after coagulation/flocculation/sand filtration when no preoxidation was used. For water utilities which included a preoxidation step in their treatment process, raw water samples were coagulated and flocculated at a laboratory scale with Jar Test equipment using the same conditions (nature of the coagulant, pH, dose) as those used in the corresponding treatment plant. Globally, 38 to 70 % of the DOC and 38 to 88 % of the BDOC were removed during coagulation-flocculation, depending on the water site. In general, the humic/non humic NOM distribution of clarified waters showed a slight increase in the proportion of the non humic organic fraction as compared to raw waters, which indicates that humic substances (higher molecular weight organics) are preferentially removed during coagulation-flocculation. Ozonation experiments were carried out on a raw water and a clarified water sampled from the same water site using a semi batch reactor (ozone was generated from high purity oxygen). For both waters, very little variation of the humic/non humic NOM distribution was observed for applied ozone doses around 0.5 mg O3/mg C or below. For higher ozone doses, the NOM distribution was dramatically changed despite only a small reduction of the DOC. The large reduction of the humic fraction was followed by a proportional increase of the non adsorbed hydrophilic solute fraction (small reduction of the DOC). As the applied ozone dose was increased from 1 to 3 mg O3/mg DOC, the non-adsorbed hydrophilic solute fraction also increased. The shift from high molecular weight organics such as humic materials to more hydrophilic organics (high polarity and low molecular weight organic solutes) during ozonation has often been mentioned in the literature. The increase of the non humic substances was followed by an increase of the BDOC. Results have also shown that higher ozone doses yield higher BDOC. Similar observations could be made with the raw and the clarified water.As a conclusion of this work, samples were collected at the different steps of a water treatment plant (raw water, clarified water, intermediate ozonated water, GAC filtered water). The impact of coagulation/flocculation, and intermediate ozonation on BDOC and the humic/non humic NOM distribution confirmed the previous observations. The GAC filtration had a large impact on the DOC distribution while the BDOC was only slightly reduced. The NOM of the treated water was found to be more hydrophobic in nature with compounds that showed apparent molecular weights below 1 000 daltons (more than 80 % of the DOC)

Identifying frequency decorrelated dust residuals in B-mode maps by exploiting the spectral capability of bolometric interferometry

Astrophysical polarized foregrounds represent the most critical challenge in Cosmic Microwave Background (CMB) B-mode experiments. Multi-frequency observations can be used to constrain astrophysical foregrounds to isolate the CMB contribution. However, recent observations indicate that foreground emission may be more complex than anticipated. We investigate how the increased spectral resolution provided by band splitting in Bolometric Interferometry (BI) through a technique called spectral imaging can help control the foreground contamination in the case of unaccounted Galactic dust frequency decorrelation along the line-of-sight. We focus on the next generation ground-based CMB experiment CMB-S4, and compare its anticipated sensitivities, frequency and sky coverage with a hypothetical version of the same experiment based on BI. We perform a Monte-Carlo analysis based on parametric component separation methods (FGBuster and Commander) and compute the likelihood on the recovered tensor-to-scalar ratio. The main result of this analysis is that spectral imaging allows us to detect systematic uncertainties on r from frequency decorrelation when this effect is not accounted for in component separation. Conversely, an imager would detect a biased value of r and would be unable to spot the presence of a systematic effect. We find a similar result in the reconstruction of the dust spectral index, where we show that with BI we can measure more precisely the dust spectral index also when frequency decorrelation is present. The in-band frequency resolution provided by BI allows us to identify dust LOS frequency decorrelation residuals where an imager of similar performance would fail. This opens the prospect to exploit this potential in the context of future CMB polarization experiments that will be challenged by complex foregrounds in their quest for B-modes detection.Comment: 13 Pages, 15 figures, 4 tables. Submitted to A&

Evolutionary stasis of the pseudoautosomal boundary in strepsirrhine primates

Sex chromosomes are typically comprised of a non-recombining region and a recombining pseudoautosomal region. Accurately quantifying the relative size of these regions is critical for sex-chromosome biology both from a functional and evolutionary perspective. The evolution of the pseudoautosomal boundary (PAB) is well documented in haplorrhines (apes and monkeys) but not in strepsirrhines (lemurs and lorises). Here, we studied the PAB of seven species representing the main strepsirrhine lineages by sequencing a male and a female genome in each species and using sex differences in coverage to identify the PAB. We found that during primate evolution, the PAB has remained unchanged in strepsirrhines whereas several recombination suppression events moved the PAB and shortened the pseudoautosomal region in haplorrhines. Strepsirrhines are well known to have much lower sexual dimorphism than haplorrhines. We suggest that mutations with antagonistic effects between males and females have driven recombination suppression and PAB evolution in haplorrhines

Travelling in time with networks: revealing present day hybridization versus ancestral polymorphism between two species of brown algae, Fucus vesiculosus and F. spiralis

Background: Hybridization or divergence between sympatric sister species provides a natural laboratory to study speciation processes. The shared polymorphism in sister species may either be ancestral or derive from hybridization, and the accuracy of analytic methods used thus far to derive convincing evidence for the occurrence of present day hybridization is largely debated. Results: Here we propose the application of network analysis to test for the occurrence of present day hybridization between the two species of brown algae Fucus spiralis and F. vesiculosus. Individual-centered networks were analyzed on the basis of microsatellite genotypes from North Africa to the Pacific American coast, through the North Atlantic. Two genetic distances integrating different time steps were used, the Rozenfeld (RD; based on alleles divergence) and the Shared Allele (SAD; based on alleles identity) distances. A diagnostic level of genotype divergence and clustering of individuals from each species was obtained through RD while screening for exchanges through putative hybridization was facilitated using SAD. Intermediate individuals linking both clusters on the RD network were those sampled at the limits of the sympatric zone in Northwest Iberia. Conclusion: These results suggesting rare hybridization were confirmed by simulation of hybrids and F2 with directed backcrosses. Comparison with the Bayesian method STRUCTURE confirmed the usefulness of both approaches and emphasized the reliability of network analysis to unravel and study hybridization

Rapid De Novo Evolution of X Chromosome Dosage Compensation in Silene latifolia, a Plant with Young Sex Chromosomes

Evidence for dosage compensation in Silene latifolia, a plant with 10-million-year-old sex chromosomes, reveals that dosage compensation can evolve rapidly in young XY systems and is not an animal-specific phenomenon

Status of QUBIC, the Q&U Bolometer for Cosmology

The Q&U Bolometric Interferometer for Cosmology (QUBIC) is a novel kind of polarimeter optimized for the measurement of the B-mode polarization of the Cosmic Microwave Back-ground (CMB), which is one of the major challenges of observational cosmology. The signal is expected to be of the order of a few tens of nK, prone to instrumental systematic effects and polluted by various astrophysical foregrounds which can only be controlled through multichroic observations. QUBIC is designed to address these observational issues with a novel approach that combines the advantages of interferometry in terms of control of instrumental systematics with those of bolometric detectors in terms of wide-band, background-limited sensitivity.Comment: Contribution to the 2022 Cosmology session of the 33rd Rencontres de Blois. arXiv admin note: substantial text overlap with arXiv:2203.0894