Structural and magnetic characterization of ordered Sr2LnSbO6 (Ln=rare earth) perosvkite

The double perovskites A2LnMO6 (A = Sr2+ and Ba2+; Ln = trivalent lanthanide cation; M = pentavalent 4d or 5d transition elements) have been widely studied concerning their structure and properties [1]. If the Ln and M cations are ordered within the B-perosvkite sites the symmetry and size of the unit cell change when are compared to the ideal cubic aristotype. Woodward predicted 15 possible space groups for the ordered A2BB’O6 perovskites when the cation ordering and the octahedral tilting around the pseudo-cubic axes take place simultaneously [2]. The ordered double perovskites A2LnMO6 with only one of the two B-sites carrying magnetic moment, namely Ln, show a magnetic sublattice consisting of edge-sharing tetrahedral, which represents a frustrating magnetic geometry in three dimensions. More recently, the structure of double perovskites Sr2LnSbO6 (Ln= Dy, Ho, Gd, Y and In) has been investigated, and the monoclinic symmetry of the space group P21/n, with Ln and Sb elements ordered in the B-sites, was reported [3, 4]. We report the preparation of the whole family of double perovskites Sr2LnSbO6 (Ln = La-Lu), which crystallize with the P21/n space group, with lattice parameters p= a2a , p= a2b and p= a2c(β∼90 º), being the lattice parameter of the cubic aristotype. A progressive decreasing was observed in lattice parameters with the increasing of the atomic number of the Ln cation, according with the wellknown lanthanide contraction. pa Magnetic susceptibility measurements for this family of compounds reveal a paramagnetic behaviour in a very wide temperature range. From experimental spectroscopic data as well as from a semi-empirical estimation (Simple Overlap Model SOM [5]) of the crystal-field parameters corresponding to the point site symmetry of the magnetically active Ln, Oh, and using the wavefunctions associated with the energy levels obtained, the paramagnetic susceptibility and its evolution vstemperature is simulated according to the van Vleck formalism. The observed deviation from the Curie–Weiss behaviour at low temperature, very well reproduced in each case, reflects the splitting of the ground state of the corresponding Ln cation under the influence of the crystal field. Thus, magnetic frustration or cooperative interactions do not need to be considered to explain the mentioned low temperature deviation from the linearity of Curie-Weiss plots

Experimental results and modelling of humidity control strategies for greenhouses in continental and coastal settings in the Mediterranean region. I: Experimental results and model development

Experimental strategies for controlling humidity were compared in a greenhouse sited in Madrid, a continental site in the Mediterranean region. Small roof window apertures significantly reduced the relative humidity with only a limited increase in associated energy consumption. A simplified climate model with four energy exchange terms (heating, insolation, losses through structure, and losses through windows) and three mass exchange terms (evapotranspiration, losses through structure, and losses through windows) was validated, allowing relative humidity to be predicted with an error of < 9%

Experimental results and modelling of humidity control strategies for greenhouses in continental and coastal settings in the Mediterranean region. II: Modelling of strategies

Strategies for humidity control —with and without heating— were evaluated via simulations performed with a previously developed model (see accompanying paper, this issue, part I). With heating, the best strategy combined the use of a humidity setpoint with step control of the roof window, increasing the ventilation in line with the outside temperature. Without heating, the best strategy again combined the use of a humidity setpoint with step control of the roof window, but required ventilation to be increased in line with the inside air temperature

Application of backend database contents and structure to the design of spoken dialog services

Current development platforms for designing spoken dialog services feature different kinds of strategies to help designers build, test, and deploy their applications. In general, these platforms are made up of several assistants that handle the different design stages (e.g. definition of the dialog flow, prompt and grammar definition, database connection, or to debug and test the running of the application). In spite of all the advances in this area, in general the process of designing spoken-based dialog services is a time consuming task that needs to be accelerated. In this paper we describe a complete development platform that reduces the design time by using different types of acceleration strategies based on using information from the data model structure and database contents, as well as cumulative information obtained throughout the successive steps in the design. Thanks to these accelerations, the interaction with the platform is simplified and the design is reduced, in most cases, to simple confirmations to the “proposals” that the platform automatically provides at each stage. Different kinds of proposals are available to complete the application flow such as the possibility of selecting which information slots should be requested to the user together, predefined templates for common dialogs, the most probable actions that make up each state defined in the flow, different solutions to solve specific speech-modality problems such as the presentation of the lists of retrieved results after querying the backend database. The platform also includes accelerations for creating speech grammars and prompts, and the SQL queries for accessing the database at runtime. Finally, we will describe the setup and results obtained in a simultaneous summative, subjective and objective evaluations with different designers used to test the usability of the proposed accelerations as well as their contribution to reducing the design time and interaction

Spanish Expressive Voices: corpus for emotion research in Spanish

A new emotional multimedia database has been recorded and aligned. The database comprises speech and video recordings of one actor and one actress simulating a neutral state and the Big Six emotions: happiness, sadness, anger, surprise, fear and disgust. Due to a careful design and its size (more than 100 minutes per emotion), the recorded database allows comprehensive studies on emotional speech synthesis, prosodic modelling, speech conversion, far-field speech recognition and speech and video-based emotion identification. The database has been automatically labelled for prosodic purposes (5% was manually revised). The whole database has been validated thorough objective and perceptual tests, achieving a validation score as high as 89%

Desarrollo de un Robot-Guía con Integración de un Sistema de Diálogo y Expresión de Emociones: Proyecto ROBINT

Este artículo presenta la incorporación de un sistema de diálogo hablado a un robot autónomo, concebido como elemento interactivo en un museo de ciencias capaz de realizar visitas guiadas y establecer diálogos sencillos con los visitantes del mismo. Para hacer más atractivo su funcionamiento, se ha dotado al robot de rasgos (como expresividad gestual o síntesis de voz con emociones) que humanizan sus intervenciones. El reconocedor de voz es un subsistema independiente del locutor (permite reconocer el habla de cualquier persona), que incorpora medidas de confianza para mejorar las prestaciones del reconocimiento, puesto que se logra un filtrado muy importante de habla parásita. En cuanto al sistema de comprensión, hace uso de un sistema de aprendizaje basado en reglas, lo que le permite inferir información explícita de un conjunto de ejemplos, sin que sea necesario generar previamente una gramática o un conjunto de reglas que guíen al módulo de comprensión. Estos subsistemas se han evaluado previamente en una tarea de control por voz de un equipo HIFI, empleando nuestro robot como elemento de interfaz, obteniendo valores de 95,9% de palabras correctamente reconocidas y 92,8% de conceptos reconocidos. En cuanto al sistema de conversión de texto a voz, se ha implementado un conjunto de modificaciones segmentales y prosódicas sobre una voz neutra, que conducen a la generación de emociones en la voz sintetizada por el robot, tales como alegría, enfado, tristeza o sorpresa. La fiabilidad de estas emociones se ha medido con varios experimentos perceptuales que arrojan resultados de identificación superiores al 70% para la mayoría de las emociones, (87% en tristeza, 79,1% en sorpresa)

Speech to sign language translation system for Spanish

This paper describes the development of and the first experiments in a Spanish to sign language translation system in a real domain. The developed system focuses on the sentences spoken by an official when assisting people applying for, or renewing their Identity Card. The system translates official explanations into Spanish Sign Language (LSE: Lengua de Signos Espan¿ola) for Deaf people. The translation system is made up of a speech recognizer (for decoding the spoken utterance into a word sequence), a natural language translator (for converting a word sequence into a sequence of signs belonging to the sign language), and a 3D avatar animation module (for playing back the hand movements). Two proposals for natural language translation have been evaluated: a rule-based translation module (that computes sign confidence measures from the word confidence measures obtained in the speech recognition module) and a statistical translation module (in this case, parallel corpora were used for training the statistical model). The best configuration reported 31.6% SER (Sign Error Rate) and 0.5780 BLEU (BiLingual Evaluation Understudy). The paper also describes the eSIGN 3D avatar animation module (considering the sign confidence), and the limitations found when implementing a strategy for reducing the delay between the spoken utterance and the sign sequence animation

Automatic Understanding of ATC Speech: Study of Prospectives and Field Experiments for Several Controller Positions

Although there has been a lot of interest in recognizing and understanding air traffic control (ATC) speech, none of the published works have obtained detailed field data results. We have developed a system able to identify the language spoken and recognize and understand sentences in both Spanish and English. We also present field results for several in-tower controller positions. To the best of our knowledge, this is the first time that field ATC speech (not simulated) is captured, processed, and analyzed. The use of stochastic grammars allows variations in the standard phraseology that appear in field data. The robust understanding algorithm developed has 95% concept accuracy from ATC text input. It also allows changes in the presentation order of the concepts and the correction of errors created by the speech recognition engine improving it by 17% and 25%, respectively, absolute in the percentage of fully correctly understood sentences for English and Spanish in relation to the percentages of fully correctly recognized sentences. The analysis of errors due to the spontaneity of the speech and its comparison to read speech is also carried out. A 96% word accuracy for read speech is reduced to 86% word accuracy for field ATC data for Spanish for the "clearances" task confirming that field data is needed to estimate the performance of a system. A literature review and a critical discussion on the possibilities of speech recognition and understanding technology applied to ATC speech are also given

Correlation between clinical parameters characterising peri-implant and periodontal health : a practice-based research in Spain in a series of patients with implants installed 4-5 years ago

Objectives: To explore peri-implant health (and relation with periodontal status) 4-5 years after implant insertion. Study D esign: A practice-based dental research network multicentre study was performed in 11 Spanish centres. The first patient/month with implant insertion in 2004 was considered. Per patient four teeth (one per quadrant) showing the highest bone loss in the 2004 panoramic X-ray were selected for periodontal status assessment. Bone losses in implants were calculated as the differences between 2004 and 2009 bone levels in radiographs. Results: A total of 117 patients were included. Of the 408 teeth considered, 73 (17.9%) were lost in 2009 (losing risk: >50% for bone losses ?7mm). A total of 295 implants were reviewed. Eight of 117 (6.8%) patients had lost implants (13 of 295 implants installed; 4.4%). Implant loss rate (quadrant status) was 1.4% (edentulous), 3.6% (preserved teeth), and 11.1% (lost teeth) (p=0.037). The percentage of implant loss significantly (p<0.001) increased when the medial/distal bone loss was ?3 mm. The highest (p?0.001) pocket depths were found in teeth with ?5mm and implants with ?3mm bone losses, with similar mean values (?4mm), associated with higher rates of plaque index and bleeding by probing. Conclusions: The significant bi-directional relation between plaque and bone loss, and between each of these two parameters/signs and pocket depths or bleeding (both in teeth and implants, and between them) together with the higher percentage of implants lost when the bone loss of the associated teeth was ?3 mm suggest that the patient?s periodontal status is a critical issue in predicting implant health/lesion

Gαi2+ vomeronasal neurons govern the initial outcome of an acute social competition

Pheromone detection by the vomeronasal organ (VNO) mediates important social behaviors across different species, including aggression and sexual behavior. However, the relationship between vomeronasal function and social hierarchy has not been analyzed reliably. We evaluated the role of pheromone detection by receptors expressed in the apical layer of the VNO such as vomeronasal type 1 receptors (V1R) in dominance behavior by using a conditional knockout mouse for G protein subunit Gαi2, which is essential for V1R signaling. We used the tube test as a model to analyze the within-a-cage hierarchy in male mice, but also as a paradigm of novel territorial competition in animals from different cages. In absence of prior social experience, Gαi2 deletion promotes winning a novel social competition with an unfamiliar control mouse but had no effect on an established hierarchy in cages with mixed genotypes, both Gαi2−/− and controls. To further dissect social behavior of Gαi2−/− mice, we performed a 3-chamber sociability assay and found that mutants had a slightly altered social investigation. Finally, gene expression analysis in the medial prefrontal cortex (mPFC) for a subset of genes previously linked to social status revealed no differences between group-housed Gαi2−/− and controls. Our results reveal a direct influence of pheromone detection on territorial dominance, indicating that olfactory communication involving apical VNO receptors like V1R is important for the outcome of an initial social competition between two unfamiliar male mice, whereas final social status acquired within a cage remains unaffected. These results support the idea that previous social context is relevant for the development of social hierarchy of a group. Overall, our data identify two context-dependent forms of dominance, acute and chronic, and that pheromone signaling through V1R receptors is involved in the first stages of a social competition but in the long term is not predictive for high social ranks on a hierarchy.Fil: Pallé, Anna. Consejo Superior de Investigaciones Científicas; EspañaFil: Montero, Marta. Consejo Superior de Investigaciones Científicas; EspañaFil: Fernendez, Silvia. Consejo Superior de Investigaciones Científicas; EspañaFil: Tezanos, Patricia. Consejo Superior de Investigaciones Científicas; EspañaFil: De las Heras, Juan. Consejo Superior de Investigaciones Científicas; EspañaFil: Luskey, Valerie. Consejo Superior de Investigaciones Científicas; EspañaFil: Birnbaumer, Lutz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Investigaciones Biomédicas. Universidad de Buenos Aires. Facultad de Medicina. Instituto de Investigaciones Biomédicas; ArgentinaFil: Zufall, Frank. Universitat Saarland; AlemaniaFil: Chamero, Pablo. Centre National de la Recherche Scientifique; FranciaFil: Trejo, José Luis. Consejo Superior de Investigaciones Científicas; Españ