Quantitative analysis of mixed niobium-titanium carbonitride solubility in HSLA steels based on atom probe tomography and electrical resistivity measurements

Solubility of mixed niobium-titanium carbonitrides in commercially relevant High Strength Low-Alloy (HSLA) steel was investigated by combined use of electrical re sistivity measurements and APT after interrupted quenching from soaking temperatures between 950 and 1250 C. Increasing electrical resistivity of the bulk material towards higher soaking temperatures was proportional to the nominal niobium addition which was varied between 0.002 and 0.022e0.043e0.085 wt.-%. Correlative APT analysis of the solutes in the steel matrix showed good agreement with electrical resistivity. Investigating numerous precipitate particles, APT also derived a precise composition for mixed niobium titanium-carbonitrides which constitute the steel microstructure after casting/before soaking. The scavenging of microalloy elements by insoluble titanium nitrides was cor rected by means of combined APT analysis of such precipitate and a quantitative image analysis for the estimation of the total volume fraction of titanium nitrides. For the first time, solute and precipitate composition together were used for solubility calculations of such mixed carbonitrides to derive an experimental solubility product. This was compared to solubility products of well-established simple carbides and nitrides and theoretical calculations of the solubility of multicomponent carbonitrides. The large discrepancy between experimentally derived and modelled solubility emphasizes the ne cessity of a robust methodology for the quantification of microalloy precipitation in HSLA steels

Tracing Microalloy Precipitation in Nb-Ti HSLA Steel during Austenite Conditioning

The microalloying with niobium (Nb) and titanium (Ti) is standardly applied in low carbon steel high-strength low-alloy (HSLA) steels and enables austenite conditioning during thermo-mechanical controlled processing (TMCP), which results in pronounced grain refinement in the finished steel. In that respect, it is important to better understand the precipitation kinetics as well as the precipitation sequence in a typical Nb-Ti-microalloyed steel. Various characterization methods were utilized in this study for tracing microalloy precipitation after simulating different austenite TMCP conditions in a Gleeble thermo-mechanical simulator. Atom probe tomography (APT), scanning transmission electron microscopy in a focused ion beam equipped scanning electron microscope (STEM-on-FIB), and electrical resistivity measurements provided complementary information on the precipitation status and were correlated with each other. It was demonstrated that accurate electrical resistivity measurements of the bulk steel could monitor the general consumption of solute microalloys (Nb) during hot working and were further complemented by APT measurements of the steel matrix. Precipitates that had formed during cooling or isothermal holding could be distinguished from strain-induced precipitates by corroborating STEM measurements with APT results, because APT specifically allowed obtaining detailed information about the chemical composition of precipitates as well as the elemental distribution. The current paper highlights the complementarity of these methods and shows first results within the framework of a larger study on strain-induced precipitation

Effect of quenching strategy and Nb-Mo sdditions on phase transformations and quenchability of high-strength boron steels

The application of direct quenching after hot rolling of plates is being employed in the production of ultra-high-strength hot rolled plates. When heavy gauge plates are produced, the complexity involve in achieving high cooling rates in the plate core is increased and the formation of undesirable soft phases within martensite is common. In the current paper, both direct quenching and conventional quenching (DQ and CQ) processing routes were reproduced by dilatometry tests and continuous cooling transformation (CCT) diagrams were built for four different high-strength boron steels. The results indicate that the addition of Mo and Nb-Mo suppresses the ferritic region and considerably shifts the CCT diagram to lower transformation temperatures. The combination of DQ strategy and the Mo-alloying concept provides the best option to ensure hardenability and the formation of a fully martensitic microstructure, and to avoid the presence of soft phases in the center of thick plates

Effect of carbon content on the microstructure and mechanical properties of NbC-Ni based cermets

The aim of this work was to correlate the overall carbon content in NbC-Ni, NbC-Ni-VC and NbC-Ni-Mo starting powders with the resulting microstructure, hardness, and fracture toughness of Ni-bonded NbC cermets. A series of NbC-Ni, NbC-Ni-VC and NbC-Ni-Mo cermets with different carbon content were prepared by conventional liquid phase sintering for 1 h at 1420 degrees C in vacuum. Microstructural analysis of the fully densified cermets was performed by electron probe microanalysis (EPMA) to assess the effect of carbon and VC or Mo additions on the NbC grain growth and morphology. A decreased carbon content in the starting powder mixtures resulted in increased dissolution of Nb, V, and Mo in the Ni binder and a decreased C/Nb ratio in the NbC based carbide phase. The Vickers hardness (HV30) and Palmqvist indentation toughness were found to decrease significantly with an increasing carbon content in the Mo-free cermets, whereas an antagonistic correlation between hardness and toughness was obtained as a function of the Mo-content in Mo-modified NbC cermets. To obtain optimized mechanical properties, methods to control the total carbon content of NbC-Ni mixtures were proposed and the prepared cermets were investigated in detail

Molybdenum alloying in high-performance flat-rolled steel grades

Considerable progress in developing flat-rolled steel grades has been made by the Chinese steel industry over the recent two decades. The increasing demand for high-performance products to be used in infrastructural projects as well as in production of consumer and capital goods has been driving this development until today. The installation of state-of-the-art steel making and rolling facilities has provided the possibility of processing the most advanced steel grades. The production of high-performance steel grades relies on specific alloying elements of which molybdenum is one of the most powerful. China is nearly self-sufficient in molybdenum supplies. This paper highlights the potential and advantages of molybdenum alloying over the entire range of flat-rolled steel products. Specific aspects of steel property improvement with respect to particular applications are indicated

Fatigue performance of laser welds in heavy-gage press hardening steels

This work investigates and compares the fatigue performance of laser-welded joints of two press hardening steels: a standard 22MnB5 and a variant modified by a combination of niobium and molybdenum (NbMo) alloying. The results indicate that joint geometry aspects, superposed to an intrusion-generated damage mechanism, were prevalent in causing a poor fatigue life in the case of peak stress values greater than 11% of the base metal's ultimate strength being around 1450 MPa. As identical process procedures were employed, the tests allowed investigating the influence of the alloy design on fatigue performance. The results of geometrical analysis and fatigue tests indicated that the NbMo modified alloy performed better than the standard 22MnB5 steel. The results also suggest that, if extremely tight quality limits are used in the manufacturing procedures, laser-welded joints of press hardened steels could offer a very favorable fatigue performance being considerably better than that of conventional and high strength structural steels

Property Optimization in As-Quenched Martensitic Steel by Molybdenum and Niobium Alloying

Niobium microalloying is the backbone of modern low-carbon high strength low alloy (HSLA) steel metallurgy, providing a favorable combination of strength and toughness by pronounced microstructural refinement. Molybdenum alloying is established in medium-carbon quenching and tempering of steel by delivering high hardenability and good tempering resistance. Recent developments of ultra-high strength steel grades, such as fully martensitic steel, can be optimized by using beneficial metallurgical effects of niobium and molybdenum. The paper details the metallurgical principles of both elements in such steel and the achievable improvement of properties. Particularly, the underlying mechanisms of improving toughness and reducing the sensitivity towards hydrogen embrittlement by a suitable combination of molybdenum and niobium alloying will be discussed

Effects of niobium alloying on microstructure, toughness and wear resistance of austempered ductile iron

© 2019 Elsevier B.V. Austempered ductile iron (ADI) is a heat-treated nodular iron variant that has for a given strength level much higher elongation than conventional iron with spheroidized graphite. This paper considers the effect of niobium addition on the graphite microstructure, bainite microstructure, bainite transformation process and properties such as hardness and impact toughness under given heat-treatment conditions. The resulting properties are significant with regard to the wear resistance of the material. The effects of niobium addition on the graphite morphology can be understood based on a detailed precipitation analysis of the niobium precipitation behavior in the liquid phase. Niobium influences the temperature and kinetics of pearlite as well as bainite transformation. Furthermore, niobium refines the bainite microstructure generated during austempering treatment. It was found that niobium addition in the range of 0.2–0.5 wt percent allows obtaining an optimum combination of hardness, impact toughness and wear resistance.status: Published onlin

Guest editorial: Molybdenum alloying: more than hardenability

status: Published onlin

Metallurgical Effects of Niobium and Molybdenum on Heat-Affected Zone Toughness in Low-Carbon Steel

Modern weldable high strength steel grades are typically based on low-carbon alloy concepts using microalloying for obtaining a good strength-toughness balance. Such steel grades having a yield strength in the range of 420 to 690 MPa are very commonly used in pipelines, heavy vehicles, shipbuilding and general structural applications. Thermomechanical processing during hot rolling combined with accelerated cooling is an established means of producing such steel grades. Considering the alloying concepts, the use of niobium and molybdenum, and in selected cases boron, is very efficient to achieve high strength and good toughness. However, all targeted applications of such high strength steels involve extensive welding. Thus, heat affected zone properties are of particular importance. The present paper investigates the effects of Nb, Mo and Ti on the heat affected zone properties. Variations of the Mn and Si contents are considered as well. Additionally, the influence of post-weld heat treatment in the coarse-grained heat-affected zone (HAZ) is considered. In this approach, HAZ subzones were generated using laboratory weld cycle simulations in combination with systematic variation of alloying elements to scrutinize and interpret their specific effects. The results indicate that Mo and Nb, when alloyed in the typical range, provide excellent HAZ toughness and guarantee sufficiently low ductile-to-brittle transition temperature. An alloy combination of Nb, Mo and Ti improves performance under hot deformation conditions and toughness after post-weld heat treatment