Chiral spin-order in some purported Kitaev spin-liquid compounds

We examine recent magnetic torque measurements in two compounds, $\gamma$-Li$_2$IrO$_3$ and RuCl$_3$, which have been discussed as possible realizations of the Kitaev model. The analysis of the reported discontinuity in torque, as an external magnetic field is rotated across the $c-$axis in both crystals, suggests that they have a translationally-invariant chiral spin-order of the from $\ne 0$ in the ground state and persisting over a very wide range of magnetic field and temperature. An extra-ordinary $|B|B^2$ dependence of the torque for small fields, beside the usual $B^2$ part, is predicted due to the chiral spin-order, and found to be consistent with experiments upon further analysis of the data. Other experiments such as inelastic scattering and thermal Hall effect and several questions raised by the discovery of chiral spin-order, including its topological consequences are discussed.Comment: Clearer figures of the experimental data provided. Also clearer exposition and comment on related recent wor

Single reconstructed Fermi surface pocket in an underdoped single layer cuprate superconductor

The observation of a reconstructed Fermi surface via quantum oscillations in hole-doped cuprates opened a path towards identifying broken symmetry states in the pseudogap regime. However, such an identification has remained inconclusive due to the multi-frequency quantum oscillation spectra and complications accounting for bilayer effects in most studies. We overcome these impediments with high resolution measurements on the structurally simpler cuprate HgBa2CuO4+d (Hg1201), which features one CuO2 plane per unit cell. We find only a single oscillatory component with no signatures of magnetic breakdown tunneling to additional orbits. Therefore, the Fermi surface comprises a single quasi-two-dimensional pocket. Quantitative modeling of these results indicates that biaxial charge-density-wave within each CuO2 plane is responsible for the reconstruction, and rules out criss-crossed charge stripes between layers as a viable alternative in Hg1201. Lastly, we determine that the characteristic gap between reconstructed pockets is a significant fraction of the pseudogap energy

A solar powered handheld plasma source for microbial decontamination applications

A fully portable atmospheric pressure air plasma system is reported to be suitable for the microbial decontamination of both surfaces and liquids. The device operates in quiescent air, and includes an integrated battery which is charged from a solar cell and weighs less than 750 g, making it highly amenable for a wide variety of applications beyond the laboratory. Using particle imaging velocimetry to visualise air flows around the device, the geometric configuration of the plasma generating electrodes was enhanced to induce a gas flow on the order of 0.5 m s-1 directed towards a sample placed downstream, thus improving the transport of plasma generated reactive species to the sample. The microbial decontamination efficiency of the system was assessed using potable water samples inoculated with common waterborne organisms Escherichia coli and Pseudomonas fluorescens. The reduction in the number of microorganisms was found to be in the range of 2-8 log and was strongly dependent on the plasma generation conditions

Atmospheric pressure plasma and depositions of antibacterial coatings

Healthcare-associated infections (HCAI) are complications of healthcare that result in elevated patient morbidity and mortality. HCAI present a huge financial burden for patients, hospitals and insurers due to extended hospitalisation and associated care. According to the estimations, in the US alone, HCAI affects approximately 2 million patients annually, of whom approximately 90.000 patients die, with an estimated annual cost estimated to range from 28 billion to 45 billion US$. [1] European Union is facing the similar situation, the European Centre for Disease Prevention and control (ECDC) advice that approximately 4.1 million acute care patients acquire a HCAI annually, with 37.000 deaths directly attributed to HCAI. With increasing prevalence of HCAI across European countries and threatening development of antimicrobial resistance to widely used antibiotics, there is a recognised need for novel approach in battle against this healthcare burden [2]. One of the approaches involves a development and fabrication of materials with antimicrobial properties. Usually, these are coatings with integrated antibacterial agent that is responsible for the elimination of microorganisms that come into contact with active surface. There is a variety of different antibacterial compounds integrated in such coatings, such as different antibiotics, chemical compounds, peptides. Recently, metal nanoparticles (NPs) have been increasingly used in designing coatings with antibacterial properties due to their large surface-to-volume ration, physiochemical properties and biological multi-target mechanism of actions. Besides all beneficial properties of NPs their emergence of cytotoxicity is limiting their practical applications in human body. [3-4] To overcome this drawback it is important to design a new class of antibacterial coatings with firmly embedded NPs that allows controlled release of antimicrobial agent into the microenvironment. Atmospheric pressure plasma technology has shown a big promise as an alternative and cost-efficient method for deposition of coatings with antibacterial properties. This contribution explores the potential of plasma-assisted approach for fabrication of antibacterial coatings, containing different metal NPs on medical textiles. Plasma-assisted deposition of coatings was carried out with so-called ˝sandwich technique˝, where nanoparticles were embedded between two layers in order to tailor the desirable ion release and to prolong antibacterial effect of fabrics. Antibacterial effects of different nano-coatings were tested against G+ and G- bacterial species, Staphylococcus aureus and Escherichia coli, respectively. Besides antibacterial properties, potential cytotoxic effects were also studied. The study demonstrates that atmospheric pressure plasma can be an efficient technique for deposition of antibacterial coatings containing metal NPs. Medical textiles with plasma-assisted nano-coatings showed effective antibacterial properties. The choice of proper metal antimicrobial agent and optimal concentration of NPs should be considered in regards to potential cytotoxic effects when these materials would be used in medical environments.info:eu-repo/semantics/publishedVersio

Quantum limit transport and destruction of the Weyl nodes in TaAs

Weyl fermions are a new ingredient for correlated states of electronic matter. A key difficulty has been that real materials also contain non-Weyl quasiparticles, and disentangling the experimental signatures has proven challenging. We use magnetic fields up to 95 tesla to drive the Weyl semimetal TaAs far into its quantum limit (QL), where only the purely chiral 0th Landau levels (LLs) of the Weyl fermions are occupied. We find the electrical resistivity to be nearly independent of magnetic field up to 50 tesla: unusual for conventional metals but consistent with the chiral anomaly for Weyl fermions. Above 50 tesla we observe a two-order-of-magnitude increase in resistivity, indicating that a gap opens in the chiral LLs. Above 80 tesla we observe strong ultrasonic attenuation below 2 kelvin, suggesting a mesoscopically-textured state of matter. These results point the way to inducing new correlated states of matter in the QL of Weyl semimetals

Plasma-laser assisted synthesis of nanoparticles for antibacterial coatings

The “green synthesis” of colloidal nanoparticles and their application for the antibacterial coatings is based on the plasma-laser assisted ablation in liquids. Nanoparticles are synthesized through the process of laser ablation of target in water, which enables additional advantages in comparison with the other standard wet chemical synthesis, such as simplicity and complete utilization of materials. Furthermore, these nanoparticles are used and tested for antibacterial coatings on polymers, where they are grafted or imbedded through atmospheric pressure plasma assisted processes. The advantages of different coatings made from those nanoparticles are presented as well.Plasmatexinfo:eu-repo/semantics/publishedVersio

Controlling magnetic order and quantum disorder in molecule-based magnets.

We investigate the structural and magnetic properties of two molecule-based magnets synthesized from the same starting components. Their different structural motifs promote contrasting exchange pathways and consequently lead to markedly different magnetic ground states. Through examination of their structural and magnetic properties we show that [Cu(pyz)(H 2 O)(gly) 2 ](ClO 4 ) 2 may be considered a quasi-one-dimensional quantum Heisenberg antiferromagnet whereas the related compound [Cu(pyz)(gly)](ClO 4 ) , which is formed from dimers of antiferromagnetically interacting Cu 2+ spins, remains disordered down to at least 0.03 K in zero field but shows a field-temperature phase diagram reminiscent of that seen in materials showing a Bose-Einstein condensation of magnons

Controlling magnetic order and quantum disorder in molecule-based magnets

We investigate the structural and magnetic properties of two molecule-based magnets synthesized from the same starting components. Their different structural motifs promote contrasting exchange pathways and consequently lead to markedly different magnetic ground states. Through examination of their structural and magnetic properties we show that [Cu(pyz)(H2O)(gly)2](ClO4)2 may be considered a quasi-one-dimensional quantum Heisenberg antiferromagnet whereas the related compound [Cu(pyz)(gly)](ClO4), which is formed from dimers of antiferromagnetically interacting Cu2+ spins, remains disordered down to at least 0.03 K in zero field but shows a field-temperature phase diagram reminiscent of that seen in materials showing a Bose-Einstein condensation of magnons

Tin telluride: a weakly co-elastic metal

We report resonant ultrasound spectroscopy (RUS), dilatometry/magnetostriction, magnetotransport, magnetization, specific heat, and $^{119}$Sn M\"ossbauer spectroscopy measurements on SnTe and Sn$_{0.995}$Cr$_{0.005}$Te. Hall measurements at $T=77$ K indicate that our Bridgman-grown single crystals have a $p$-type carrier concentration of $3.4 \times 10^{19}$ cm$^{-3}$ and that our Cr-doped crystals have an $n$-type concentration of $5.8 \times 10^{22}$ cm$^{-3}$. Although our SnTe crystals are diamagnetic over the temperature range $2\, \text{K} \leq T \leq 1100\, \text{K}$, the Cr-doped crystals are room temperature ferromagnets with a Curie temperature of 294 K. For each sample type, three-terminal capacitive dilatometry measurements detect a subtle 0.5 micron distortion at $T_c \approx 85$ K. Whereas our RUS measurements on SnTe show elastic hardening near the structural transition, pointing to co-elastic behavior, similar measurements on Sn$_{0.995}$Cr$_{0.005}$Te show a pronounced softening, pointing to ferroelastic behavior. Effective Debye temperature, $\theta_D$, values of SnTe obtained from $^{119}$Sn M\"ossbauer studies show a hardening of phonons in the range 60--115K ($\theta_D$ = 162K) as compared with the 100--300K range ($\theta_D$ = 150K). In addition, a precursor softening extending over approximately 100 K anticipates this collapse at the critical temperature, and quantitative analysis over three decades of its reduced modulus finds $\Delta C_{44}/C_{44}=A|(T-T_0)/T_0|^{-\kappa}$ with $\kappa = 0.50 \pm 0.02$, a value indicating a three-dimensional softening of phonon branches at a temperature $T_0 \sim 75$ K, considerably below $T_c$. We suggest that the differences in these two types of elastic behaviors lie in the absence of elastic domain wall motion in the one case and their nucleation in the other