Environmental magnetic fingerprinting of anthropogenic and natural atmospheric deposition over southwestern Europe

Here we present an environmental magnetic study of atmospheric deposition collected by a multi-site network in Spain that covers fourteen locations representative of urban, industrial, agricultural, and natural environments across southwestern Europe. We have combined magnetic methods with scanning electron microscopy and geochemical data to characterize the magnetic mineral assemblages of particulate matter across different types of sites and phenomenological scenarios, and to unravel their environmental significance in terms of the most important anthropogenic and natural components of atmospheric deposition. Our results enable identification of two magnetite/maghemite components of anthropogenic origin, derived mostly from vehicular traffic, plus a hematite component associated with a baseline supply of north African dust, in all the studied sites regardless of their type. The ubiquitous presence of anthropogenic magnetite/maghemite particles in pristine natural envi-ronments, albeit in lower concentrations, point to their arrival from neighbouring urban areas through atmo-spheric mixing processes. Samples including particulate matter deposited during distinctively intense periods of north African dust supply are characterized by a fourth component, represented also by coarser-grained he-matite, that is likely derived from a different source area within the Sahara Desert. The concomitant increase observed in these cases in the amounts of magnetite/maghemite particles suggests strongly that part of the magnetite/maghemite load attributed to anthropogenic sources for the rest of the phenomenological scenarios is aeolian in origin. This seems to explain the overall moderate correlation observed between magnetite/maghe-mite contents and proxies for vehicular traffic, and demonstrates the need for caution when interpreting envi-ronmental magnetic proxies for magnetite/maghemite abundances in terms of anthropogenic loads. This is especially the case in southern European cities where a steady supply of north African dust occurs throughout most of the year. Our results show a good correlation between hematite abundances and geochemical proxies for north African dust, which collectively delineate broad maxima during the summer and large peaks during distinctive dust breakouts. Thus, environmental magnetic proxies of hematite abundances can be used to monitor the contribution of natural sources to atmospheric deposition.This study was funded by the Spanish Agencia Estatal de Investigación and the European Funds for Regional Development (AEI/FEDER, UE) via the DONAIRE (CGL2015-68993-R) project. XZ and DH were supported by Australian Council Discovery Project DP200100765

Recording the largest gabbro-anorthositic complex worldwide: The Kunene Complex (KC), SW Angola

ABSTRACT: The Kunene Complex (KC) represents a large Mesoproterozoic igneous body, mainly composed of anorthosites and gabbroic rocks that extends from SW Angola to NW Namibia (18000 km2, N-S trend, and ca. 350 km long and 25???50 km wide). Although the KC has been studied from a cartographic and geochemical point of view, little is known about its structure at depth below the sedimentary deposits of the Kalahari basin. Hence, we use available satellite gravity data to estimate its extent and to unravel its morphology at depth. The Bouguer anomaly map depicts a gravity gradient from the coast (+200 mGal) towards eastern Angola (-150 mGal), which is explained by the transition from a young, dense and thin basaltic oceanic crust, formed during the Mesozoic Atlantic rifting, to an old, light and thick Archaean to Proterozoic continental crust (Congo Craton), to the east. The outcropping KC interrupts the gravity trend, showing at the western, southwestern and northeastern sides, several positive and isolated gravity anomalies linked to gabbroic intrusions associated to KC (ca. 50 km wavelength and -90 mGal). In contrast, the anomalies found at the central part of the massif (50 km wavelength and < -110 mGal) correspond to the dominant anorthositic members, according to the spatial correlation of the mapping. Five 2.5D gravity profiles have been modelled to investigate the unexposed eastern boundary, reconstructing the surface crustal structure (between 0 and 15 km depth) overlaid by the thin sedimentary cover of the Kalahari basin. The gravity modelling helps us to show that the KC was emplaced in the Upper Crust and extends in depth up to ca. 6 km, showing a lobular geometry and following a large NE-SW to NNE-SSW linear trend, presumably inherited from older Palaeoproterozoic structures. The lateral continuation of the KC to the east (between 50 and 125 km) beneath the Kalahari sediments suggests an overall size of at least twice the outcropping dimension (about 42500 km2). This statement clearly influences in the economic potential of this massif, related to the prospecting of raw materials and certain types of economic mineralization (Fe-Ti oxides, metallic sulphides or platinum group minerals).info:eu-repo/semantics/publishedVersio

Kinematics of Structures and Basin Evolution in the Central High Atlas: constraints from AMS and Paleomagnetic Data

[EN] From the application of the magnetic techniques (Anisotropy of Magnetic Susceptibility and paleomagnetism) it can be seen that to determine the age (and origin) of structures in the Moroccan Central High Atlas is not straightforward from geometrical features only and that similar structures can have different origins, or that the two limbs of a particular structure can have developed at different times. A classification of structures is proposed showing all these possibilities. As a general rule, many structures were initiated before compression and, with local exceptions associated with salt structures, paleo-dips were shallow at the remagnetization stage. This has allowed the restoration of structures and the characterization of the overall geometry of the atlasic basin as a narrow, steer’s head strongly subsiding basin whose geometry strongly conditioned its tectonic inversion during the Cenozoic compressional stage. As a synthesis, the Central High Atlas constitutes a good example of intra-plate chain in which different models of basin formation (continental rifting, salt tectonics, transtension) and inversion (thrust tectonics, transpression, buttressing and internal deformation…) can be tested and visualized.This work is part of the I+D+i research projects CGL2009-10840, CGL2009-8969, CGL2012-38481, CGL2016-77560-C2 (C21 and C22) and PID2019-108753GB-C2 (C21 and C22), funded by mICIN/AEI/https://doi.org/10.13039/501100011033 and by “ERDF A way of making Europe”.Peer reviewe

Riesgo de subsidencia kárstica en áreas urbanas: el caso de Zaragoza

Parte del monográfico "Riesgos geológicos externos".[EN] This paper deals with the problems generated by karst in gypsum around Zaragoza, the development of alluvial sinkholes and the concomitant risks. Sinkhole geometry depends on the mechanical behaviour of the cover overlying the evaporitic bedrock: non-cohesive soils favour the development of basin and funnel shaped dolines, whereas cohesive covers lead to the development of well-shaped collapses. Surface survey in areas prone to develop dolines is based on aerial photographs, in situ features (such as topographic depressions, stepped ground, anomalous man-made fills, wet-ground vegetation), and location of building pathologies in urban areas. In some cases, the structure and geometry of dolines can be studied in section (road cuts, for instance), where the features of natural fills allow to characterize the evolutionary patterns and sedimentation- subsidence interactions. Through dating of such fills the rate of subsidence can be estimated, and linked to possible episodes of climate variations. Doline evolution through time, either by comparison of aerial photographs taken in different years or by instrumental survey, yields the scenario of a dynamic process with subsidence rates up to 12 cm/year, where cycles of steady subsidence periods and sudden collapse are identified. In the Zaragoza area, the consequences of karst subsidence are outstanding. They dramatically increased from the 70’s, when large portions of the territory, formerly of agricultural use, turned into urban, industrial and service uses. Prevention and hazard management of karstic risks on urban and peri-urban areas must include: 1) early detection of the problem, in surface as well as underground (by means of geophysical surveys), and 2) adaptation of land use to the degree of affection by karst and the potential susceptibility. Geology, geotechnics and engineering have specific roles on risk management strategies by diminishing either the exposition to karst hazard or the vulnerability of man made structures.[ES] Este trabajo analiza, desde múltiples puntos de vista, la problemática del karst en yesos en el entorno de Zaragoza, el desarrollo de dolinas aluviales y los riesgos que éstas conllevan. La morfología de las dolinas depende del comportamiento mecánico de la cobertera situada sobre el sustrato yesífero: en coberteras sin cohesión aparecen morfologías en embudo y en cubeta, producidas por subsidencia continuada, mientras en coberteras con cohesión se producen dolinas en ventana provocadas por colapso brusco. El reconocimiento superficial de las dolinas se basa en la observación de fotografías aéreas, en el análisis visual del terreno (depresiones topográficas, escalones, áreas de vegetación o rellenos antrópicos anómalos) y en la observación y análisis de daños en áreas urbanizadas. También pueden estudiarse la geometría y la estructura interna de las dolinas en secciones del terreno donde éstas hayan quedado expuestas. Así, las características de sus rellenos naturales permiten conocer las pautas y tasas de evolución y las interacciones entre la subsidencia kárstica y los procesos sedimentarios. El estudio de la evolución temporal de las dolinas, a partir de la comparación de fotografías aéreas de distintos años o del seguimiento instrumental de las mismas, ha permitido reconocer que se trata de un proceso dinámico que llega a alcanzar velocidades de hundimiento de 12 cm/año. En dicha evolución es frecuente la ocurrencia cíclica de periodos de subsidencia lenta y eventos de hundimiento brusco. La afección causada por la subsidencia kárstica en Zaragoza es muy significativa. Ésta se incrementó a partir de los años 70 del siglo pasado, cuando buena parte del suelo agrícola que circundaba la ciudad fue destinado a uso urbano, industrial y grandes infraestructuras. La prevención y manejo del riesgo kárstico en áreas urbanas y peri-urbanas debe contemplar: (1) la detección precoz de los fenómenos tanto en superficie como en profundidad (a partir de estudios geofísicos), y (2) la adaptación del uso del suelo a su grado de afección por fenómenos kársticos y a su susceptibilidad potencial a los mismos. La geología, la geotecnia y la ingeniería desempeñan, cada una, un papel específico en la estrategia para reducir el riesgo, bien sea evitando la exposición al peligro o disminuyendo la vulnerabilidad de las construcciones.Peer reviewe

Structure of the Central High Atlas (Morocco): constraints from Potential Field Data and 3D Models

[EN] From a 3-D reconstruction based on serial cross-sections, structural observations, and potential field geophysical data we characterize the major structural frame of the Moroccan Central High Atlas. Its overall structure shows two fold-and-thrust systems (each one showing particular features) at the northern and southern borders of the chain, resulting from the inversion of the Mesozoic basin. Five more zones can be distinguished in the inner part of the chain, according to their structural features, ranging from basement-involved structures in the westernmost sector to completely detached structures in the eastern part. Most compressional structures show an ENE-WSW (atlasic) trend, also pinpointed by the orientation of pressure-solution and slaty cleavage associated with the compressional stage. Large-scale faults of crustal or lithospheric reach can be inferred from the aeromagnetic maps, that show that the gabbro intrusions (some of them showing sigmoidal shape) are aligned in an E-W direction, oblique to the main trend. The overall compressional structure is controlled by a main, low-angle, South-verging thrust involving both the Mesozoic cover and the Paleozoic basement thrusting over the southern foreland of the chain. Branching on this surface there is a series of back-thrusts and faults, some of them resulting from re-activation of extensional structures.This research was financed by projects CGL2016-77560-C2 (C21 and C22) and PID2019-108753GB-C2 (C21 and C22), funded by MICIN/AEI/10.13039/501100011033 and by “ERDF A way of making Europe”.Peer reviewe

Unraveling the geometry of the New England oroclines (eastern Australia): Constraints from magnetic fabrics

The southern New England Orogen (NEO) in eastern Australia is characterized by tight curvatures(oroclines), but the exact geometry of the oroclines and their kinematic evolution are controversial. Here we present new data on the anisotropy ofmagnetic susceptibility (AMS), which provide a petrofabric proxy for the finite strain associated with the oroclines.We focus on a series of preoroclinal Devonian-Carboniferous fore-arc basin rocks, which are aligned parallel to the oroclinal structure, and by examining structural domains, we test whether or not the magnetic fabric is consistent with the strain axes. AMS data show a first-order consistency with the shape of the oroclines, characterized, in most of structural domains, by subparallelism between magnetic lineations, “structural axis” and bedding. With the exception of the Gresford and west Hastings domains, our results are relatively consistent with the existence of the Manning and Nambucca (Hastings) Oroclines. Reconstruction of magnetic lineations to a prerotation (i.e., pre–late Carboniferous) stage, considering available paleomagnetic results, yields a consistent and rather rectilinear NE-SW predeformation fore-arc basin. This supports the validity of AMS as a strain proxy in complex orogens, such as the NEO. In the Hastings Block, magnetic lineations are suborthogonal to bedding, possibly indicating a different deformational historywith respect to the rest of the NEO

Magnetic fabrics in the Western Central-Pyrenees: An overview

[EN] In the Western Central-Pyrenees numerous investigations during the past years have yielded an exceptional high density of localities (more than 700 sites) where the AMS and rock magnetic properties have been determined. This unique AMS dataset helps in understanding the orogenic evolution of the Pyrenees and its foreland basins. Processes related to AMS development in different structural units permit to identify: (i) an early recording of strain related to the transtensional or transpressional stages during the Early Triassic and Early Cretaceous, (ii) a moderate shortening related to the fold-and-thrust belt and foreland basin evolution during the Cretaceous–Tertiary orogenic stage, and (iii) a relatively strong deformation that produced cleavage related to the emplacement of basement thrusts in the Axial Zone during the Middle–Late Eocene. The main achievement of this contribution is the integration in cross-section and map-view of magnetic fabrics (orientation and parameters) in the western Central-Pyrenees, which allow constraining the processes affecting magnetic fabrics at the orogen scale. AMS results indicate: (i) a dominant bedding-controlled foliation, very sensitive to subtle layer parallel shortening (LPS) processes, especially in the foreland basins; (ii) magnetic lineations parallel to fold axes or strike of thrusts outside the cleavage front that can be deflected by vertical-axis rotations in particular areas; and (iii) an overall decrease of the definition of AMS fabrics (magnetic lineation or the anisotropy of the ellipsoid) associated with incipient cleavage and intersection lineation fabrics in the internal zones of the orogen. Therefore, AMS is a sensitive indicator to delineate the strain patterns at the orogen-scale, in particular, in those areas undergoing a modest degree of deformation.This study has been financed by the research projects CGL2006-05817 (PIRIMAG), CGL2009-08969 (BASINMAG), BTE2002-04168-C03-01, CGL2009-14214 and CGL2006-02289 (Pmag3Drest), CGL2006-02514 (Spanish Ministry of Science and Innovation and FEDER funds), UZ2012-CIE-11 (University of Zaragoza) and the financial support from the E27 Geotransfer and E72 Aquifer research groups (Government of Aragon).Peer reviewe

Subsurface Geophysics and Geology (GEOFSU

[EN] The geophysics line at the IGME began in 1927 as a Geophysics Sectiondedicated to subsurface exploration. During all this time, it has been developed in order to support and give expert service in all IGME’s activities both as a geological service and public research institution, as well as a research and development work itself. On the other hand, in recent years the IGME has promoted a line of research aimed at the characterization and 3D modeling of geological structures and formations, the development of dedicated software and the evolution and sophistication of computer equipment. The new scenario of incorporation of the IGME to the CSIC as a national reference center in the field of Earth Sciences has allowed the establishment of the GEOFSUB Research Group (Subsurface Geophysics and Geology). It is constituted by 21 members who had been collaborating regularly of the IGME former scientific-technic areas Geophysics and remote sensing (Área de Geofísica y Teledetección) and Subsurface geology and 3D geological modelling (Área de Geología del Subsuelo y Modelización Geológica 3D). Our main differentiating element is our extensive knowledge of geophysical and geological techniques, which allows us to characterize the subsoil in an optimal waPeer reviewe