CH4 and N2O dynamics in the boreal forest-mire ecotone

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Atmospheric impact of abandoned boreal organic agricultural soils depends on hydrological conditions

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Numerical calculations of effective elastic properties of two cellular structures

Young's moduli of regular two-dimensional truss-like and eye-shape-like structures are simulated by using the finite element method. The structures are the idealizations of soft polymeric materials used in the electret applications. In the simulations size of the representative smallest units are varied, which changes the dimensions of the cell-walls in the structures. A power-law expression with a quadratic as the exponential term is proposed for the effective Young's moduli of the systems as a function of the solid volume fraction. The data is divided into three regions with respect to the volume fraction; low, intermediate and high concentrations. The parameters of the proposed power-law expression in each region are later represented as a function of the structural parameters, unit-cell dimensions. The presented expression can be used to predict structure/property relationship in materials with similar cellular structures. It is observed that the structures with volume fractions of solid higher than 0.15 exhibit the importance of the cell-wall thickness contribution in the elastic properties. The cell-wall thickness is the most significant factor to predict the effective Young's modulus of regular cellular structures at high volume fractions of solid. At lower concentrations of solid, eye-like structure yields lower Young's modulus than the truss-like structure with the similar anisotropy. Comparison of the numerical results with those of experimental data of poly(propylene) show good aggreement regarding the influence of cell-wall thickness on elastic properties of thin cellular films.Comment: 7 figures and 2 table

Adolescent attachment to parents and peers in singletons and twins born with assisted and natural conception

STUDY QUESTION Does adolescent attachment to parents and peers differ between singletons and twins born with ART or natural conception (NC)? SUMMARY ANSWER Adolescent attachment anxiety with the father was higher among NC singletons than among ART and NC twins, whereas attachment avoidance with the father was higher in ART singletons than in NC singletons and NC twins. No differences were found in attachment to the mother, best friend or romantic partner. WHAT IS KNOWN ALREADY Most studies have not found differences between ART and NC singletons in parent-adolescent relationships, but twin relationships may be more at risk. No previous study has examined all four groups in the same study, or specifically looked at attachment relationships. STUDY DESIGN, SIZE, DURATION This was an 18-year, prospective and controlled longitudinal study with families of 496 ART singletons, 101 ART twin pairs, 476 NC singletons and 22 NC twin pairs. Families were recruited during the second trimester of pregnancy; the ART group was recruited from five infertility clinics in Finland and the control group was recruited from a hospital outpatient clinic during a routine visit. PARTICIPANTS/MATERIALS, SETTING, METHODS Mothers and fathers gave background information for this study during pregnancy, and during the child's first year and early school age (7-8 years). For the ART group, infertility characteristics and prenatal medical information was also obtained from the patient registry of the infertility clinics. Children (originally 50% girls) filled in electronic questionnaires related to their attachment to mother, father, best friend and romantic partner (Experiences in Close Relationships-Relationship Structures) at 17-19 years of age. MAIN RESULTS AND THE ROLE OF CHANCE Adolescent attachment anxiety to father was higher in NC singletons than in ART twins, P = 0.004 and marginally higher than in NC twins, P = 0.06. Adolescent attachment avoidance to father was higher in ART singletons than in NC singletons, P = 0.006 and marginally higher than in NC twins, P = 0.055. LIMITATIONS, REASONS FOR CAUTION The sample size was small especially in the NC twin group and there was drop-out over the 18-year time period, especially among boys and families with lower parental education level. The study only included native Finnish-speaking families. The results could differ in a more diverse population. ART singletons were younger and had fewer siblings than ART twins and NC children, and ART and NC twins had more newborn health risks than ART and NC singletons. WIDER IMPLICATIONS OF THE FINDINGS The study adds to a growing body of evidence that neither ART treatments nor being a twin places mother-child relationships or peer relationships at long-term risk. However, in our study, which was the first to examine both ART and twinhood simultaneously, we found that there may be more problems in father-adolescent relationships, but only in ART singletons and only related to attachment avoidance. Our findings suggest that men, as well as women, should receive enough support in pre- and peri-natal health care during and after infertility treatments. STUDY FUNDING/COMPETING INTEREST(S) This study was funded by Academy of Finland (grant number 2501308988), the Juho Vainio Foundation and the Finnish Cultural Foundation. The authors report no conflict of interest.Peer reviewe

Vegetation impacts ditch methane emissions from boreal forestry-drained peatlands—Moss-free ditches have an order-of-magnitude higher emissions than moss-covered ditches

Ditches of forestry-drained peatlands are an important source of methane (CH4) to the atmosphere. These CH4 emissions are currently estimated using the IPCC Tier 1 emission factor (21.7 g CH4 m(-2) y(-1)), which is based on a limited number of observations (11 study sites) and does not take into account that the emissions are affected by the condition and age of the ditches. Furthermore, the total area of different kinds of ditches remains insufficiently estimated. To constructmore advanced ditch CH4 emission factors for Finland, we measured CH4 emissions in ditches of 3 forestry-drained peatland areas (manual chamber technique) and amended this dataset with previously measured unpublished and published data from 18 study areas. In a predetermined 2type ditch classification scheme, the mean CH4 emissions (+/- standard error) were 2.6 +/- 0.8 g CH4 m(-2) y(-1) and 20.6 +/- 7.0 g CH4 m(-2) y(-1) in moss-covered and moss-free ditches, respectively. In a more detailed 4-type classification scheme, the yearly emissions were 0.6 +/- 0.3, 3.8 +/- 1.1, 8.8 +/- 3.2, and 25.1 +/- 9.7 g CH4 m(-2) y(-1) in Sphagnum-covered, Sphagnum-and vascular plant-covered, moss-free and vascular plant-covered, and plant -free ditches, respectively. Hence, we found that Tier 1 emission factor may overestimate ditch CH4 emissions through overestimation of the emissions of moss-covered ditches, irrespective of whether they harbor potentially CH4 conducing vascular plants. Based on the areal estimates and the CH4 emission factors for moss-covered and moss-free ditches, CH4 emissions of ditches of forestry-drained peatlands in Finland were 8,600 t a(-1), which is 63% lower than the current greenhouse gas inventory estimates for ditch CH4 emissions (23,200 t a(-1)). We suggest that the Tier 1 emission factor should be replaced with more advanced emission factors in the estimation of ditch CH4 emissions of boreal forestry-drained peatlands also in other countries than in Finland. Furthermore, our results suggest that the current practice in Finland to minimize ditch-network maintenance by ditch cleaning will likely decrease CH4 emissions from ditches, since old moss-covered ditches have very low emissions.Peer reviewe

CH4 and N2O dynamics in the boreal forest-mire ecotone

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