1,265 research outputs found
Influence of phase purity on photoluminescence properties of strontium oxynitride phosphor doped with Eu2+ ions
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Synthesis of iso-C-nucleoside analogues from 1-(methyl 2-O-benzyl-4,6-O- benzylidene-3-deoxy-α-D-altropyranosid-3-yl)but-3-yn-2-ones
1-(Methyl 2-O-benzyl-4,6-O-benzylidene-3-deoxy-α-D-altropyranosid-3- yl)but-3-yn-2-one (3a) reacted with 3-amino-1H-1,2,4-triazole and 5-aminopyrazole-4-carboxylic acid derivatives in the presence of base to furnish the triazolo[1,5-a]pyrimidine (5) and the pyrazolo[1,5-a]pyrimidines (8a-d), respectively. Treatment of 1-(methyl 2-O-benzyl-4,6-O-benzylidene-3-deoxy- α-D-altropyranosid-3-yl)-4-phenyl-but-3-yn-2-one (3b) with cyanacetamide, 2-cyano-N-(4-methoxyphenyl)acetamide und N-aryl-3-oxo-butyramides afforded the substituted nicotinonitriles (11a-d). Furthermore, reaction of 3b with 2-benzimidazolyl-acetonitrile yielded the benz[4,5]imidazo[1,2-a]pyridine-4- carbonitrile (13). Deprotection of 8d in two steps afforded the 2-amino-N-benzyl-5-(methyl 3-deoxy-α-D-altropyranosid-3-yl-methyl) pyrazolo[1,5-a]pyrimidine-3-carboxamide (10). Compounds 5 and 11d were treated with AcOH/H2O to furnish the 5-(methyl 2-O-benzyl-3-deoxy-α-D- altropyranosid-3-yl-methyl)[1,2,4]triazolo[1,5-a]pyrimidine (6) and the 3-acetyl-1,2-dihydro-1-(4-methoxyphenyl)-6-(methyl 2-O-benzyl-3-deoxy-α-D- altropyranosid-3-yl-methyl)-4-phenylpyridin-2-one (12), respectively
Simulative Analysis of a New Type Wide Range Estimator of Protection Criterion Values
In the paper a new adaptive estimator of protection criterion values insensitive to wide range power system frequency changes is proposed and analysed. Its operation is based on a coarse calculation of signal frequency and appropriate correction of used orthogonal filters frequency responses as well as adaptation of chosen parameters of the measurement algorithm. The main features of the new method has been compared with standard criterion values estimators both theoretically and by simulations. The proposed estimators assure good accuracy of measurement within the frequency range from 5 to 95 Hz
3D freeform surfaces from planar sketches using neural networks
A novel intelligent approach into 3D freeform surface reconstruction from planar sketches is proposed. A multilayer perceptron (MLP) neural network is employed to induce 3D freeform surfaces from planar freehand curves. Planar curves were used to represent the boundaries of a freeform surface patch. The curves were varied iteratively and sampled to produce training data to train and test the neural network. The obtained results demonstrate that the network successfully learned the inverse-projection map and correctly inferred the respective surfaces from fresh curves
Potential control under thin aqueous layers using a Kelvin Probe
Kelvin Probes can be modified to control as well as monitor potential. The design and operation of two different Kelvin Probe Potentiostats (KPPs) are described in this paper. One approach uses a permanent magnet and double coil to oscillate the needle at a fixed frequency, an AC backing potential, and software analysis and control schemes. This technique can also control the distance between the tip and sample, thereby tracking the topography of the sample. Both KPPs were used to make measurements on Type 304L stainless steel under thin layers of electrolyte. Cathodic polarization curves exhibited a limiting current density associated with oxygen reduction. The limiting current density varied with solution layer thickness over a finite range of thickness. Anodic polarization curves on 304L in a thin layer of chloride solution resulted in pitting corrosion. The breakdown potential did not vary with solution layer thickness. However, the thin layer was observed to increase in volume remarkably during pit growth owing to the absorption of water from the high humidity environment into the layer with ionic strength increased by the pit dissolution. The open circuit potential (OCP) and solution layer thickness were monitored during drying out of a thin electrolyte layer. Pitting corrosion initiated, as indicated by a sharp drop in the OCP, as the solution thinned and increased in concentration.This work was supported in part by the Office of Science and Technology and International (OST&I), Office of Civilian Radioactive Waste Management (OCRWM), US Department of Energy (DOE). The work is carried out as part of the DOE Multi-University Corrosion Cooperative under Cooperative Agreement DE-FC28-04RW12252
Strontium oxynitride phosphor doped with Eu2+ ions : phase purity/optical properties relationship
Enhanced exchange and reduced magnetization of Gd in an Fe/Gd/Fe trilayer
5 pĂĄginas, 6 figuras.-- PACS number(s): 75.70.âi, 75.47.De, 75.60.EjThe exchange interaction of Gd adjacent to Fe has been characterized by transport measurements on a double spin valve with a Fe/Gd/Fe trilayer as the middle layer. Our measurements show that the ferromagnetism of the Gd is enhanced by the presence of the Fe, and it remains ferromagnetic over its Curie temperature up to a thickness no smaller than 1 nm adjacent to the Fe. This thickness is more than double what has been reported before. Additionally, the saturation magnetization of the thin Gd layer sandwiched in Fe was found to be half of its bulk value. This reduced magnetization does not seem to be related to the proximity of Fe but rather to the incomplete saturation of Gd even for very high fields.This work was partially supported by Project Nos.
MAT2008-02770/NAN and MAT2009-08771 from the SpanishMinisterio
deCiencia e InnovaciÂŽon. M. Romerawas funded
through the FPU Fellowship No. AP2007-00464.Peer reviewe
Autonomous on-board data processing and instrument calibration software for the SO/PHI
The extension of on-board data processing capabilities is an attractive
option to reduce telemetry for scientific instruments on deep space missions.
The challenges that this presents, however, require a comprehensive software
system, which operates on the limited resources a data processing unit in space
allows. We implemented such a system for the Polarimetric and Helioseismic
Imager (PHI) on-board the Solar Orbiter (SO) spacecraft. It ensures autonomous
operation to handle long command-response times, easy changing of the processes
after new lessons have been learned and meticulous book-keeping of all
operations to ensure scientific accuracy. This contribution presents the
requirements and main aspects of the software implementation, followed by an
example of a task implemented in the software frame, and results from running
it on SO/PHI. The presented example shows that the different parts of the
software framework work well together, and that the system processes data as we
expect. The flexibility of the framework makes it possible to use it as a
baseline for future applications with similar needs and limitations as SO/PHI.Comment: Conference: SPIE Astronomical Telescopes + Instrumentatio, Software
and Cyberinfrastructure for Astronomy
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