Organosolv pretreatment of Sitka spruce wood: conversion of hemicelluloses to ethyl glycosides

A range of organosolv pretreatments, using ethanol:water mixtures with dilute sulphuric acid, were applied to Sitka spruce sawdust with the aim of generating useful co-products as well as improving saccharification yield. The most efficient of the pretreatment conditions, resulting in subsequent saccharification yields of up to 86%, converted a large part of the hemicellulose sugars to their ethyl glycosides as identified by GC/MS. These conditions also reduced conversion of pentoses to furfural, the ethyl glycosides being more stable to dehydration than the parent pentoses. Through comparison with the behaviour of model compounds under the same reaction conditions it was shown that the anomeric composition of the products was consistent with a predominant transglycosylation reaction mechanism, rather than hydrolysis followed by glycosylation. The ethyl glycosides have potential as intermediates in the sustainable production of high-value chemicals

Isolation of high quality lignin as a by-product from ammonia percolation pretreatment of poplar wood

A two-step process combining percolation-mode ammonia pretreatment of poplar sawdust with mild organosolv purification of the extracted lignin produced high quality, high purity lignin in up to 31% yield and 50% recovery. The uncondensed fraction of the isolated lignin was up to 34%, close to that the native lignin (40%). Less lignin was recovered after pretreatment in batch mode, apparently due to condensation during the longer residence time of the solubilised lignin at elevated temperature. The lignin recovery was directly correlated with its molecular weight and its nitrogen content. Low nitrogen incorporation, observed at high ammonia concentration, may be explained by limited homolytic cleavage of -O-4 bonds. Ammonia concentrations from 15% to 25% (w/w) gave similar results in terms of lignin structure, yield and recovery

External Validity: A Survey-Experiment Approach

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/68477/2/10.1177_014616727400100102.pd

Discovery of a Radio-loud/Radio-quiet Binary Quasar

We report the discovery of a small separation quasar pair (z=0.586, O=18.4, 19.2, sep. = 2.3 arcsec) associated with the radio source FIRST J164311.3+315618 (S_1400 = 120 mJy). The spectrum of the brighter quasar (A) has a much stronger narrow emission-line spectrum than the other (B), and also stronger Balmer lines relative to the continuum. The continuum ratio of the spectra is flat in the blue at about 2.1, but falls to 1.5 at longer wavelengths. A K' image shows two unresolved sources with a flux ratio of 1.3. The different colors appear to result from the contribution of the host galaxy of B, which is evident from Ca II and high-order Balmer absorption lines indicative of a substantial young stellar population. New 3.6 cm VLA observations show that the compact radio source is coincident with quasar A (B is only marginally detected). We rule out the lensing hypothesis because the optical flux ratio is A/B = 1.2 to 2, while the radio flux ratio is A/B > 40, and conclude that this system is a binary. Moreover, the radio-loud quasar is a compact steep spectrum source. FIRST J164311.3+315618A, B is the lowest redshift and smallest separation binary quasar yet identified.Comment: 8 pages, 3 figures, to appear in Astrophysical Journal Letter

Integrated assessment of oyster reef ecosystem services: Quantifying denitrification rates and nutrient fluxes

Fluxes of N2-N (denitrification), dissolved ammonium, nitrate plus nitrite, and dissolved oxygen were determined at teh 350 acre oyster restoration project at Harris Creek, Maryland. The ex situ incubation approach involved adding oyster communities to embedded trays for ~1 mo incubating the trays under dark and light conditions for 1-2 hour time courses for gas and solute sampling, adn determination of the rates of gas and solute exchange for 136 individual reef tray incubations. Reef exchange rates were compared to rates of sediment water exchange in core incubations throughout Harris Creek and in reef-adjacent environments

A response to “Likelihood ratio as weight of evidence: a closer look” by Lund and Iyer

Recently, Lund and Iyer (L&I) raised an argument regarding the use of likelihood ratios in court. In our view, their argument is based on a lack of understanding of the paradigm. L&I argue that the decision maker should not accept the expert’s likelihood ratio without further consideration. This is agreed by all parties. In normal practice, there is often considerable and proper exploration in court of the basis for any probabilistic statement. We conclude that L&I argue against a practice that does not exist and which no one advocates. Further we conclude that the most informative summary of evidential weight is the likelihood ratio. We state that this is the summary that should be presented to a court in every scientific assessment of evidential weight with supporting information about how it was constructed and on what it was based

Measurement of mutual inductance from frequency dependence of impedance of AC coupled circuit using digital dual-phase lock-in amplifier

We present a simple method to determine the mutual inductance $M$ between two coils in a coupled AC circuit by using a digital dual-phase lock-in amplifier. The frequency dependence of the real and imaginary parts is measured as the coupling constant is changed. The mutual inductance $M$ decreases as the distance $d$ between the centers of coils is increased. We show that the coupling constant is proportional to $d^{-n}$ with an exponent $n$ ($\approx$ 3). This coupling is similar to that of two magnetic moments coupled through a dipole-dipole interaction.Comment: 9 pages, 10 figures, Fig.1 is corrected, figures in png files, short version is published in Am. J. Phys. 76, (2008) 12