5,549 research outputs found
Organosolv pretreatment of Sitka spruce wood: conversion of hemicelluloses to ethyl glycosides
A range of organosolv pretreatments, using ethanol:water mixtures with dilute sulphuric acid, were applied to Sitka spruce sawdust with the aim of generating useful co-products as well as improving saccharification yield. The most efficient of the pretreatment conditions, resulting in subsequent saccharification yields of up to 86%, converted a large part of the hemicellulose sugars to their ethyl glycosides as identified by GC/MS. These conditions also reduced conversion of pentoses to furfural, the ethyl glycosides being more stable to dehydration than the parent pentoses. Through comparison with the behaviour of model compounds under the same reaction conditions it was shown that the anomeric composition of the products was consistent with a predominant transglycosylation reaction mechanism, rather than hydrolysis followed by glycosylation. The ethyl glycosides have potential as intermediates in the sustainable production of high-value chemicals
Isolation of high quality lignin as a by-product from ammonia percolation pretreatment of poplar wood
A two-step process combining percolation-mode ammonia pretreatment of poplar sawdust with mild organosolv purification of the extracted lignin produced high quality, high purity lignin in up to 31% yield and 50% recovery. The uncondensed fraction of the isolated lignin was up to 34%, close to that the native lignin (40%). Less lignin was recovered after pretreatment in batch mode, apparently due to condensation during the longer residence time of the solubilised lignin at elevated temperature. The lignin recovery was directly correlated with its molecular weight and its nitrogen content. Low nitrogen incorporation, observed at high ammonia concentration, may be explained by limited homolytic cleavage of -O-4 bonds. Ammonia concentrations from 15% to 25% (w/w) gave similar results in terms of lignin structure, yield and recovery
External Validity: A Survey-Experiment Approach
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/68477/2/10.1177_014616727400100102.pd
Discovery of a Radio-loud/Radio-quiet Binary Quasar
We report the discovery of a small separation quasar pair (z=0.586, O=18.4,
19.2, sep. = 2.3 arcsec) associated with the radio source FIRST
J164311.3+315618 (S_1400 = 120 mJy). The spectrum of the brighter quasar (A)
has a much stronger narrow emission-line spectrum than the other (B), and also
stronger Balmer lines relative to the continuum. The continuum ratio of the
spectra is flat in the blue at about 2.1, but falls to 1.5 at longer
wavelengths. A K' image shows two unresolved sources with a flux ratio of 1.3.
The different colors appear to result from the contribution of the host galaxy
of B, which is evident from Ca II and high-order Balmer absorption lines
indicative of a substantial young stellar population. New 3.6 cm VLA
observations show that the compact radio source is coincident with quasar A (B
is only marginally detected). We rule out the lensing hypothesis because the
optical flux ratio is A/B = 1.2 to 2, while the radio flux ratio is A/B > 40,
and conclude that this system is a binary. Moreover, the radio-loud quasar is a
compact steep spectrum source. FIRST J164311.3+315618A, B is the lowest
redshift and smallest separation binary quasar yet identified.Comment: 8 pages, 3 figures, to appear in Astrophysical Journal Letter
Recommended from our members
Assessment of Vessel Density on Non-Contrast Computed Tomography to Detect Basilar Artery Occlusion
Introduction: Basilar artery occlusion (BAO) may be clinically occult due to variable and non-specific symptomatology. We evaluated the qualitative and quantitative determination of a hyperdense basilar artery (HDBA) on non-contrast computed tomography (NCCT) brain for the diagnosis of BAO.Methods: We conducted a case control study of patients with confirmed acute BAO vs a control group of suspected acute stroke patients without BAO. Two EM attending physicians, one third-year EM resident, and one medical student performed qualitative and quantitative assessments for the presence of a HDBA on axial NCCT images. Our primary outcome measures were sensitivity and specificity for BAO. Our secondary outcomes were inter-rater and intra-rater reliability of the qualitative and quantitative assessments.Results: We included 60 BAO and 65 control patients in our analysis. Qualitative assessment of the hyperdense basilar artery sign was poorly sensitive (54%–72%) and specific (55%–89%). Quantitative measurement improved the specificity of hyperdense basilar artery assessment for diagnosing BAO, with a threshold of 61.0–63.8 Hounsfield units demonstrating relatively high specificity of 85%–94%. There was moderate inter-rater agreement for the qualitative assessment of HDBA (Fleiss’ kappa statistic 0.508, 95% confidence interval: 0.435–0.581). Agreement improved for quantitative assessments, but still fell in the moderate range (Shrout-Fleiss intraclass correlation coefficient: 0.635). Intra-rater reliability for the quantitative assessments of the two attending physician reviewers demonstrated substantial consistency.Conclusion: Our results highlight the importance of carefully examining basilar artery density when interpreting the NCCT of patients with altered consciousness or other signs and symptoms concerning for an acute basilar artery occlusion. If the Hounsfield unit density of the basilar artery exceeds 61 Hounsfield units, BAO should be highly suspected
Integrated assessment of oyster reef ecosystem services: Quantifying denitrification rates and nutrient fluxes
Fluxes of N2-N (denitrification), dissolved ammonium, nitrate plus nitrite, and dissolved oxygen were determined at teh 350 acre oyster restoration project at Harris Creek, Maryland. The ex situ incubation approach involved adding oyster communities to embedded trays for ~1 mo incubating the trays under dark and light conditions for 1-2 hour time courses for gas and solute sampling, adn determination of the rates of gas and solute exchange for 136 individual reef tray incubations. Reef exchange rates were compared to rates of sediment water exchange in core incubations throughout Harris Creek and in reef-adjacent environments
A response to “Likelihood ratio as weight of evidence: a closer look” by Lund and Iyer
Recently, Lund and Iyer (L&I) raised an argument regarding the use of likelihood ratios in court. In our view, their argument is based on a lack of understanding of the paradigm. L&I argue that the decision maker should not accept the expert’s likelihood ratio without further consideration. This is agreed by all parties. In normal practice, there is often considerable and proper exploration in court of the basis for any probabilistic statement. We conclude that L&I argue against a practice that does not exist and which no one advocates. Further we conclude that the most informative summary of evidential weight is the likelihood ratio. We state that this is the summary that should be presented to a court in every scientific assessment of evidential weight with supporting information about how it was constructed and on what it was based
Comparison of methods for determining biogeochemical fluxes from a restored oyster reef
Oyster reef restoration can significantly increase benthic denitrification rates. Methods applied to measure nutrient fluxes and denitrification from oyster reefs in previous studies include incubations of sediment cores collected adjacent to oyster clumps, benthic chambers filled with intact reef segments that have undergone in situ equilibration and ex situ incubation, and cores with single oysters. However, fluxes of nutrients vary by orders of magnitude among oyster reefs and methods. This study compares two methods of measuring nutrient and metabolic fluxes on restored oyster reefs: incubations including intact segments of oyster reef and incubations containing oyster clumps without underlying sediments. Fluxes of oxygen (O-2), dissolved inorganic carbon (DIC), ammonium (NH4+), combined nitrate and nitrite (NO2/3-), di-nitrogen (N-2), and soluble reactive phosphorus (SRP) were determined in June and August in Harris Creek, a tributary of the Chesapeake Bay, Maryland, USA. Regression of fluxes measured from clumps alone against those measured from intact reef segments showed significant positive relationships for O-2, DIC, NH4+, and SRP (R-2 = 0.920, 0.61, 0.26, and 0.52, respectively). Regression of clump fluxes against the oyster tissue biomass indicates significant positive relationships for O-2 and NH4+, marginally significant and positive relationships for DIC and N-2, and no significant relationship for NO2/3- or SRP. Although these results demonstrate that the incubation of oyster clumps without underlying sediments does not accurately represent biogeochemical fluxes measured from the whole oyster and sediment community, this work supports the need to understand the balance between the metabolism of oysters and local sediments to correctly estimate biogeochemical rates
Measurement of mutual inductance from frequency dependence of impedance of AC coupled circuit using digital dual-phase lock-in amplifier
We present a simple method to determine the mutual inductance between two
coils in a coupled AC circuit by using a digital dual-phase lock-in amplifier.
The frequency dependence of the real and imaginary parts is measured as the
coupling constant is changed. The mutual inductance decreases as the
distance between the centers of coils is increased. We show that the
coupling constant is proportional to with an exponent (
3). This coupling is similar to that of two magnetic moments coupled through a
dipole-dipole interaction.Comment: 9 pages, 10 figures, Fig.1 is corrected, figures in png files, short
version is published in Am. J. Phys. 76, (2008) 12
- …