Cr segregation and impact fracture in a martensitic stainless steel

The fracture surfaces of a 10.5 wt.% Cr martensitic stainless steel broken in Charpy tests have been investigated through X-ray photoelectron spectroscopy (XPS). The specimens have been examined in two different conditions: as-quenched and heat treated for 10 h at 700°C. The trends of Fe/Cr ratio vs. test temperature are similar to the sigmoidal curves of absorbed energy and, after both ductile and quasi-cleavage brittle fractures, such ratio is always significantly lower than the nominal value of the steel chemical composition. Cr segregation does not occur on a macroscopic scale but takes place in microscopic zones which represent weaker spots in the steel matrix and a preferred path for moving cracks. Small area (diameter 300 μm) XPS measurements evidenced a higher density of such microscopic zones in the inner part of probes; this is explained by the different diffusion length of Cr atoms in the external and inner parts during quenching from austenitic field which has been calculated through FEM simulations. No significant differences of Cr concentration were observed in fracture surfaces of probes with and without heat treatment. The results highlight how Cr segregation plays a role not only in the intergranular mode of fracture but also in the quasi-cleavage and ductile ones

Otites externes nécrosantes: Apport de l’imagerie isotopique

Objective : the Necrotizing (malignant) External Otitis is a very serious, potentially lethal affection. It touches exclusively a debilitated population, where from the necessity of a premature and reliable diagnosis for a beam of cliniquo-biological, radiological and isotopic arguments. Its care as well as its treatment are heavy and require a better definition of themoment of cure. The purpose of our work is to specify the place of the isotopic explorations in the care of the NEO.Materials and methods : we report a retrospective study bringing together 29 patients hospitalized for suspicion of necrotizing external otitis of period going from 2003 till 2009.Résultats : the Middle Age of our population is 64.2 years, with a clear male prevalence. The majority of our patients are diabetics (90% of the cases) with a cardiac and hypertensive Co-morbidity among 19 patients. All our patients consulted, within 47 average days. An assessment of imagery was carried out, comprising a scanner for 16 of our patients. It wasnormal in 4 cases and had shown lesions of osteitis in 12 cases. The osseous scintigraphy marked in MDP-Tc99 was carried out among 24 patients, within 9.69 average day. It was positive for all our patients, objectifying an osseous hyperfixation. All our patients received an adapted treatment. After amendment of the clinico-biological signs, a scintigraphy in Ga67 was practiced for 16 patients within 74 average days. It confirmed the cure among 12 patients, at which one decided to stop the antibiotic therapy. In the other cases, it objectified an osseous hyperfixation translating the persistence of the active infectious process, from where prolongation of the treatment.Conclusion : it comes out from our work that the imagery is essential to confirm the diagnosis and to specify the extent of the osteitis. Indeed, the scanner and the MRI offer an excellent resolution and evaluate the extension of the infection perfectly. However, because of their poor sensitivity, they have little interest to the early phase of the diagnosis and for the therapeutic follow-up. The osseous scintigraphy has the advantage of an excellent sensitivity, approximately 100% in particular at the early stage, but is not specific. The tomographic techniques (SPECT) and the quantification improve however its specificity. The scintigraphy with gallium 67 seems quite as sensitive as and more specific than the osseousscintigraphy, especially if it is quantified, and appears essential with the therapeutic follow-up. Its standardization would have an excellent predictive value of cure, allowing the stop of the antibiotic therapyKeywords : Necrotizing External Otitis, scintigraphy with gallium, the osseous scintigraphy

A Simplified Parametric Study on Occupant Comfort Conditions in Base Isolated Buildings under Wind Loading

Vibrations in buildings can cause occupant discomfort in the form of annoyance, headache, or sickness. While occupant comfort is considered in international standards regarding the design of high rise buildings against wind loading, it is neglected in the design of buildings with seismic protective base isolation systems. Nevertheless, due to their low flexibility, base isolated buildings can be prone to wind-induced vibrations, which makes occupant discomfort a potentially significant serviceability limit state. This paper presents a study on occupant comfort conditions in wind-excited base isolated buildings. A numerical simplified parametric procedure is proposed in order to evaluate the return period of wind events causing human discomfort. A parametric investigation is then presented to evaluate the effects of salient parameters on comfort conditions. The procedure is based on (i) the nonlinear dynamic analysis of the structure modeled as a single-degree-of-freedom oscillator with hysteretic base isolators, (ii) the digital generation of time histories of turbulent wind velocity, and (iii) comfort evaluations based on international standards. Results demonstrate that discomfort conditions can occur a few times in a year, depending upon the wind-exposure of the site, what suggests considering this serviceability limit state in the design of base isolated buildings

CARATTERIZZAZIONE MICROCHIMICA DELL’ INTERFACCIA FIBRA-MATRICE NEL COMPOSITO TI6AL4V-SICf

Il materiale composito costituito da una matrice Ti6Al4V, rinforzato con fibre lunghe di SiC (tipo SCS-6), è stato caratterizzato sia allo stato di fabbricazione che dopo trattamenti termici in vuoto. Attraverso la microanalisi EDS e la spettroscopia di fotoemissione (XPS) e Auger (AES), è stata determinata la concentrazione dei principali elementi, operando su sezioni metallografiche. Le analisi sono state eseguite in varie posizioni: tra le interfaccie di fibra, nel rivestimento in carbonio e nella matrice. I dati sperimentali nella zona di reazione sono stati discussi e confrontati con andamenti teorici

Recycling of multilayer packaging waste with switchable anionic surfactants

Switchable Anionic Surfactants (SAS) were used for delaminating flexible packaging waste composed of various plastic layers and aluminium, thereby promoting the recycling of such waste streams from a circular economy perspective. The delamination protocol was optimized on de-pulped food and beverage cartons containing low-density polyethylene (LDPE) and aluminium, varying the carboxylic acid and its counterion constituting the SAS (C8[sbnd]C18 carboxylic acids as the anionic part; inorganic bases and primary, secondary and tertiary amines as the cationic one) their molar ratio (carboxylic acid: base molar ratio from 1:1 to 1:3), SAS concentration (0.15, 0.3 and 0.5 wt%), time (0.5–3 h) and material weight in input (1–10 wt%). High-quality LDPE and aluminium were separated and recovered by using a diluted solution of a surfactant based on lauric acid and triethanolamine (C12-TEA), with performances not achievable with other anionic or cationic surfactants available on the market. The C12-TEA solution was then applied to a large variety of multilayer waste materials composed of polypropylene and aluminium, polyolefins/polyethylene terephthalate/aluminium, giving a material separation dependant on the structure and composition of the material in input. At the end of the process, lauric acid was recovered from the aqueous solution used for washing the separated materials by tuning its water solubility with CO2

Charge transport mechanisms of black diamond at cryogenic temperatures

Black diamond is an emerging material for solar applications. The femtosecond laser surface treatment of pristine transparent diamond allows the solar absorptance to be increased to values greater than 90% from semi-transparency conditions. In addition, the defects introduced by fs-laser treatment strongly increase the diamond surface electrical conductivity and a very-low activation energy is observed at room temperature. In this work, the investigation of electronic transport mechanisms of a fs-laser nanotextured diamond surface is reported. The charge transport was studied down to cryogenic temperatures, in the 30–300 K range. The samples show an activation energy of a few tens of meV in the highest temperature interval and for T < 50 K, the activation energy diminishes to a few meV. Moreover, thanks to fast cycles of measurement, we noticed that the black-diamond samples also seem to show a behavior close to ferromagnetic materials, suggesting electron spin influence over the transport properties. The mentioned properties open a new perspective in designing novel diamond-based biosensors and a deep knowledge of the charge-carrier transport in black diamond becomes fundamental

Analisi microchimica mediante SPEM di una superlega di Nichel dopo prove di creep

Lo scopo di questo lavoro è mostrare le potenzialità delle analisi micro-chimiche di superficie, in particolare laspettroscopia Scanning PhotoEmission Microscopy (SPEM) ad alta risoluzione, nello studio dei fenomeni diffusiviche hanno luogo fra le fasi g e g’ nelle superleghe di Ni a seguito del creep. Si riportano le analisi condotte su unasuperlega monocristallina, CM186LC, prima e dopo prove di creep alle temperature di 800 e 900 °C.Le misure di fotoemissione ai raggi X (XPS) ad elevata risoluzione spaziale sono state effettuate presso labeam-line ESCA-microscopy del sincrotrone Elettra di Trieste, in cui è stato utilizzato lo SPEM, che opera inmodalità sia di immagine che di spettroscopia puntuale, producendo una microsonda a raggi X di diametroinferiore a 50 nm. L’alta risoluzione permette di esaminare separatamente la composizione chimica della faserinforzante g’ e della matrice g caratterizzanti la superlega. In questo modo è possibile studiare la partizionedegli elementi di lega tra le fasi nel materiale vergine e la sua evoluzione dopo le prove di creep