171 research outputs found

    Superconducting fluctuations in organic molecular metals enhanced by Mott criticality

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    Unconventional superconductivity typically occurs in materials in which a small change of a parameter such as bandwidth or doping leads to antiferromagnetic or Mott insulating phases. As such competing phases are approached, the properties of the superconductor often become increasingly exotic. For example, in organic superconductors and underdoped high-TcT_\mathrm{c} cuprate superconductors a fluctuating superconducting state persists to temperatures significantly above TcT_\mathrm{c}. By studying alloys of quasi-two-dimensional organic molecular metals in the Îş\kappa-(BEDT-TTF)2_2X family, we reveal how the Nernst effect, a sensitive probe of superconducting phase fluctuations, evolves in the regime of extreme Mott criticality. We find strong evidence that, as the phase diagram is traversed through superconductivity towards the Mott state, the temperature scale for superconducting fluctuations increases dramatically, eventually approaching the temperature at which quasiparticles become identifiable at all.Comment: 19 pages, 4 figures, 1 tabl

    Mott transition, antiferromagnetism, and unconventional superconductivity in layered organic superconductors

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    The phase diagram of the layered organic superconductor Îş\kappa-(ET)2_{2}Cu[N(CN)2_{2}]Cl has been accurately measured from a combination of 1^{1}H NMR and AC susceptibility techniques under helium gas pressure. The domains of stability of antiferromagnetic and superconducting long-range orders in the pressure {\it vs} temperature plane have been determined. Both phases overlap through a first-order boundary that separates two regions of inhomogeneous phase coexistence. The boundary curve is found to merge with another first order line related to the metal-insulator transition in the paramagnetic region. This transition is found to evolve into a crossover regime above a critical point at higher temperature. The whole phase diagram features a point-like region where metallic, insulating, antiferromagnetic and non s-wave superconducting phases all meet.Comment: 4 pages, 6 figures, Revte

    Evaluation and design of multispecies cropping systems with perennials: are current methods applicable?

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    The existing methods are applicable to multispecies cropping systems with perennials. However, the particular features of these cropping systems highlight the drawbacks of each of them. Therefore, combining these approaches, where and when it is possible, should be preferred. Whatever the method, evaluation of the new systems requires new indicators development, to account for the multiple productions with very different timescales and serving varying objectives. Development of simple and effective sets of indicators adapted to these systems is a powerful tool to boost the design realm, for practitioners and researchers alike

    Aperiodic quantum oscillations of particle-hole asymmetric Dirac cones

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    We report experimental measurements and theoretical analysis of Shubnikov-de Haas (SdH) oscillations in a Dirac cone system: the a-(BEDT-TTF)2I3 organic metal under hydrostatic pressure. The measured SdH oscillations reveal anomalies at high magnetic fields B where the 1/B oscillations periodicity is lost above 7 T. We interpret these unusual results within a theoretical model that takes into account intrinsic distortions of the a-(BEDT-TTF)2I3 Dirac cones such as a parabolic particle-hole asymmetric correction. Others possible causes, such as a cone tilting or a Zeeman effect, are carefully ruled out. The observations are consistent among a-(BEDT-TTF)2I3 samples with different Fermi levels

    Evaluation and design of multispecies cropping systems with perennials: are current methods applicable?

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    The shock Hugoniot of hydroxy-terminated polybutadiene

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    The response of polymers to shock loading is becoming of increasing importance, both as binder systems in plastic-bonded explosives (PBXs) and as structural materials in their own right. In this paper, we report on the shock Hugoniot of hydroxy-terminated polybutadiene (HTPB), which is commonly used as a binder system in PBXs, but whose shock response has yet to be presented in the open literature. Results indicate that the shock velocity --- particle velocity relationship is linear, similar to some but not all polymer-based materials

    A set of moment tensor potentials for zirconium with increasing complexity

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    Machine learning force fields (MLFFs) are an increasingly popular choice for atomistic simulations due to their high fidelity and improvable nature. Here, we propose a hybrid small-cell approach that combines attributes of both offline and active learning to systematically expand a quantum mechanical (QM) database while constructing MLFFs with increasing model complexity. Our MLFFs employ the moment tensor potential formalism. During this process, we quantitatively assessed structural properties, elastic properties, dimer potential energies, melting temperatures, phase stability, point defect formation energies, point defect migration energies, free surface energies, and generalized stacking fault (GSF) energies of Zr as predicted by our MLFFs. Unsurprisingly, model complexity has a positive correlation with prediction accuracy. We also find that the MLFFs wee able to predict the properties of out-of-sample configurations without directly including these specific configurations in the training dataset. Additionally, we generated 100 MLFFs of high complexity (1513 parameters each) that reached different local optima during training. Their predictions cluster around the benchmark DFT values, but subtle physical features such as the location of local minima on the GSFE surface are washed out by statistical noise

    Haut parleur tout aimant guidé sur joint ferrofluide : caractérisation dynamique du guidage

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    Une étude expérimentale sur le comportement visqueux de ferrofluides, au sein d'une goutte insérée entre deux plans parallèles, en condition de cisaillement oscillatoire et sous champ magnétique homogène et stationnaire, permet d'alimenter un modèle pour les pertes d'un haut-parleur tout aimant guidé sur joint ferrofluide. Ces joints sont localisés dans les zones de fort gradient de champs magnétique. Le modèle de perte, fonction du volume, de la viscosité et de la saturation magnétique du ferrofluide, est alors validé par confrontation avec une expérience
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