Use of acrylic sheet molds for elastomeric products

Molds constructed of acrylic sheet are more easily machined than metal, are transparent to ensure complete filling during injection, and have smooth surfaces free of contamination. Technique eliminates flashing on molded parts and mold release agents

86 GHz SiO maser survey of late-type stars in the Inner Galaxy. IV. SiO emission and infrared data for sources in the Scutum and Sagittarius-Carina arms, 20 deg < l < 50 deg

We present an 86 GHz SiO (v = 1, J = 2 ---> 1) maser search toward late-type stars located within |b|<0.5 deg and 20 deg < l < 50 deg. This search is an extension at longer longitudes of a previously published work. We selected 135 stars from the MSX catalog using color and flux criteria and detected 92 (86 new detections). The detection rate is 68%, the same as in our previous study. The last few decades have seen the publication of several catalogs of point sources detected in infrared surveys (MSX, 2MASS, DENIS, ISOGAL, WISE, GLIMPSE, AKARI, and MIPSGAL). We searched each catalog for data on the 444 targets of our earlier survey and for the 135 in the survey reported here. We confirm that, as anticipated, most of our targets have colors typical of oxygen-rich asymptotic giant branch (AGB) stars. Only one target star may have already left the AGB. Ten stars have colors typical of carbon-rich stars, meaning a contamination of our sample with carbon stars <=1.7%.Comment: 13 pages, 6 Figures, A&A accepte

Evaluation of equilibrium moisture content in ligno-cellulosic residues of olive culture

The use of ligno-cellulosic residuals from agriculture as means for renewable energy production is well known; nonetheless significant problems still exist on development of bioenergy value chains. Moisture content and hygroscopicity are among these problems. Higher moisture content of the biomass means lower calorific value and higher perishability, hence storage difficulties. For this reason it is important to evaluate how the moisture content of the material varies while it is stored and how the calorific value of the feedstock is affected by it. The purpose of this study is to determine the variation of moisture content and its influence on lower calorific value (LCV) of four types of solid residual biomass: oven dried chipped olive tree trimmings, milled olive pomace; oven dried olive tree trimmings and fresh olive tree trimmings. Moisture content of the samples is calculated by means of thermogravimetric analysis (TGA) according to standard CEN/TS 14774-2:2004, while the LCVs are calculated by means of a calorimeter, following standard UNI EN 14918:2010. All the biomass samples were left to reach equilibrium moisture content (EMC) in a temperature and humidity controlled environment. Two different phases were analyzed with respect to moisture uptake rates: 1) fast moisture uptake rate phase (first four hours of exposure) and 2) slow moisture uptake rate, (the days following the first four hours of exposure). Samples experiencing fast moisture uptake rate, during the first four hours of exposure, were kept in a monitored ambient at T=22 \ub1 1oC and RH=59 \ub1 2%, while samples exposed to slow moisture uptake rate were kept in a climatic chamber at three different set of temperature and humidity controlled environment simulating the climatic conditions in different periods of the year in Enna province: 10oC - 80% RH (winter), 15oC - 70% RH (spring/autumn) and 20oC - 55% RH, (summer). The results obtained show that the olive pruning chips (0.425 mm to 1.00 mm and 1.00 mm to 2.00 mm particle size ranges) stored in a heap in a controlled climatic chamber require approximately 20 days to reach EMC. Depending on the particle size range EMCs reach the values of 6.2 and 7.5% by weight in the "summer" condition, 14.3% and 16.9% in "spring/autumn" condition, 24.1% and 28.2% in "winter" condition. Moisture is absorbed gradually over time and results show that in the first four hours, the dry sample exposed to ambient condition (T=22 \ub1 1 oC and RH=59 \ub1 2%) reaches a moisture content between 0.75 and 0.96% of its weight; the LCV at equilibrium is evaluated between 18, 576 J\u2022odg-1 and 18, 793 J\u2022odg-1, the higher value related to the bigger particle size range examined. Pomace heap under the same experimental set up and time period, reaches an equilibrium moisture content of 8.5% and 9.7% (summer conditions), 19.2% and 22.0% (spring/autumn condition) and between 30.9% and 34.1% (winter condition). Olive pomace accumulates moisture relatively faster than olive trimmings as dry sample recovers about 1.61% to 1.97% of moisture in the first four hours of exposure. The LCV at equilibrium is determined between 20, 145 J\u2022odg-1 and 20, 436 J\u2022odg-1. Pruning dried samples reach an EMC equal to 6.1% in approximately 25 days, with a LCV equal to18, 921 J\u2022odg-1 \ub1 1.9%. Heaps of fresh prunings reach an EMC of 8.2% in approximately 20 days; LCV of the feedstock is 19, 356 J\u2022odg-1\ub1 1.6%.\ua92006-2014 Asian Research Publishing Network (ARPN). All rights reserved

On the suitability of thermogravimetric balances for the study of biomass pyrolysis

In fixed-bed pyrolysis reactors, the stacking of sample particles often leads to higher yields of solid pyrolysis products (chars) than are obtained from other types of reactors. This phenomenon is particularly emphasised in thermogravimetric (TG) balances, which unlike many fixed-bed reactors, do not sweep gas through the stationary bed of pyrolysing sample. Gas is swept through the sample bed to reduce the residence time of tar vapours in close proximity to chars, which affects the extent to which these vapours will condense onto the surface of chars and repolymerise, thus increasing char yield. Depth of the sample bed affects this residence time, and thus affects char yield. In this work, the sensitivity of typical analyses of biomass thermogravimetry to variations in bed depth have been assessed. Results of these analyses, including product distributions, proximate compositions, and kinetic predictions, carried out on microcrystalline cellulose and birch wood hydrochar samples produced at temperatures ranging from 160 to 280 °C, have been shown to be sensitive to variations in bed depth, and it has been demonstrated that this sensitivity is amplified at higher heating rates and temperatures. Thus, when a single sample mass is used for any of these typical TG analyses, as is common in published literature, the results are not fundamental properties of the material tested but rather a product of the exact experimental design employed. Future work is needed to identify reactor and experimental design guidelines to minimise this sensitivity in fixed-bed reactors

Explanatory Supplement of the ISOGAL-DENIS Point Source Catalogue

We present version 1.0 of the ISOGAL-DENIS Point Source Catalogue (PSC), containing more than 100,000 point sources detected at 7 and/or 15 micron in the ISOGAL survey of the inner Galaxy with the ISOCAM instrument on board the Infrared Space Observatory (ISO). These sources are cross-identified, wherever possible, with near-infrared (0.8-2.2 micron) data from the DENIS survey. The overall surface covered by the ISOGAL survey is about 16 square degrees, mostly (95%) distributed near the Galactic plane (|b| < 1 deg), where the source extraction can become confusion limited and perturbed by the high background emission. Therefore, special care has been taken aimed at limiting the photometric error to ~0.2 magnitude down to a sensitivity limit of typically 10 mJy. The present paper gives a complete description of the entries and the information which can be found in this catalogue, as well as a detailed discussion of the data processing and the quality checks which have been completed. The catalogue is available via the VizieR Service at the Centre de Donn\'ees Astronomiques de Strasbourg (CDS, http://vizier.u-strasbg.fr/viz-bin/VizieR/) and also via the server at the Institut d'Astrophysique de Paris (http://www-isogal.iap.fr/). A more complete version of this paper, including a detailed description of the data processing, is available in electronic form through the ADS service.Comment: 21 pages, 7 figures. A&A in press. Full length version with 32 figures and detailed description of the data processing is available here: http://www-isogal.iap.fr/Publications/ExplSupplFull.ps.g

Recovery of metals and valuable chemicals from waste electric and electronic materials: a critical review of existing technologies

The growing development of technology has increased the amount of waste generated by electrical and electronic equipment (WEEE) every year. WEEE contains valuable metals and hazardous materials which, if not properly recovered, may drastically contribute to the depletion of natural resources while posing threat to the environment. The recent escalation of geopolitical tensions has fueled a growing spike in commodity and energy prices. In today's world, the recycling technologies have already evolved from primitive methods to more sophisticated techniques such as automatic disassembly, chemical leaching, electrolysis and so on. It is mandatory that researchers will develop novel technologies to tackle the complexity of WEEE treatment and material recovery. This analysis critically reviews the accomplishments in the field of e-waste recycling and further assesses the principles of recycling, separation, and optimized parameters of different technologies. The application of conventional techniques like pyrometallurgy and chemical leaching (non-cyanide, reduced wastewater) results in an active recovery of various materials. Compared to cyanide and strong acid leading, thiourea and thiosulphate have achieved significant advancements in environmental protection. Additionally, novel technologies like bio-metallurgy cryo-milling, siderophores and supercritical extraction technology also resulted in enhanced recovery efficiencies for base and precious metals, along with metal recovery techniques using recyclable lixiviates. However, the application of these technologies is restricted due to the heterogeneous nature of WEEE. Therefore, this review focuses on the deficiencies of each of them and further discusses the interpretation of future urgent developments in the WEEE recycling sector