Do arsenic levels in rice pose a health risk to the UK population?

Consumption of rice and rice products can be a significant exposure pathway to inorganic arsenic (iAs), which is a group 1 carcinogen to humans. The UK follows the current European Commission regulations so that iAs concentrations must be  0.1 mg kg-1 were selected for As speciation using HPLC-ICP-MS. Based on the average concentration of iAs of our samples, we calculated values for the Lifetime Cancer Risk (LCR), Target Hazard Quotient (THQ) and Margin of Exposure (MoE). We found a statistically significant difference between organically and non-organically grown rice. We also found that brown rice contained a significantly higher concentration of iAs compared to white or wild rice. Notably, 28 rice samples exceeded the iAs maximum limit stipulated by the EU (0.1 mg kg-1) with an average iAs concentration of 0.13 mg kg-1; therefore consumption of these rice types could be riskier for infants than adults. Based on the MoE, it was found that infants up to 1 year must be restricted to a maximum of 20 g per day for the 28 rice types to avoid carcinogenic risks. We believe that consumers could be better informed whether the marketed product is fit for infants and young children, via appropriate product labelling containing information about iAs concentration

A quantitative evaluation of metallic conduction in conjugated polymers

As the periodicity in crystalline materials creates the optimal condition for electronic delocalization, one might expect that in partially crystalline conjugated polymers delocalization is impeded by intergrain transport. However, for the best conducting polymers this presumption fails. Delocalization is obstructed by interchain rather than intergrain charge transfer and we propose a model of weakly coupled disordered chains to describe the physics near the metal-insulator transition. Our quantitative calculations match the outcome of recent broad-band optical experiments and provide a consistent explanation of metallic conduction in polymers.Comment: 4 pages incl. 3 figure

Surface melting of the vortex lattice

We discuss the effect of an (ab)-surface on the melting transition of the pancake-vortex lattice in a layered superconductor within a density functional theory approach. Both discontinuous and continuous surface melting are predicted for this system, although the latter scenario occupies the major part of the low-field phase diagram. The formation of a quasi-liquid layer below the bulk melting temperature inhibits the appearance of a superheated solid phase, yielding an asymmetric hysteretic behavior which has been seen in experiments.Comment: 4 pages, 3 figure

Surface Melting of the Vortex Lattice in Layered Superconductors: Density Functional Theory

We study the effects of an $ab$-surface on the vortex-solid to vortex-liquid transition in layered superconductors in the limit of vanishing inter-layer Josephson coupling. We derive the interaction between pancake vortices in a semi-infinite sample and adapt the density functional theory of freezing to this system. We obtain an effective one-component order-parameter theory which can be used to describe the effects of the surface on vortex-lattice melting. Due to the absence of protecting layers in the neighbourhood of the surface, the vortex lattice formed near the surface is more susceptible to thermal fluctuations. Depending on the value of the magnetic field, we predict either a continuous or a discontinuous surface melting transition. For intermediate values of the magnetic field, the surface melts continuously, assisting the formation of the liquid phase and suppressing hysteresis above the melting transition, a prediction consistent with experimental results. For very low and very high magnetic fields, the surface melts discontinuously. The two different surface melting scenarios are separated by two surface multicritical points, which we locate on the melting line.Comment: 16 pages, 12 figure