2,277 research outputs found
Tellurium vacancy in cadmium telluride revisited: size effects in the electronic properties
The quantum states and thermodynamical properties of the Te vacancy in CdTe
are addressed by first principles calculations, including the supercell size
and quasiparticle corrections. It is shown that the 64-atoms supercell
calculation is not suitable to model the band structure of the isolated Te
vacancy. This problem can be solved with a larger 216-atoms supercell, where
the band structure of the defect seems to be a perturbation of that of the
perfect crystal. It is interesting to note that the Te-vacancy formation energy
calculated with both supercell sizes are close in energy, which is attributed
to error cancelation. We also show that the interplay between supercell size
effects and the band gap underestimation of the generalized gradient
approximation strongly influences the predicted symmetry of some charge states.Comment: 9 pages, 7 figure
Energetics and Electronic Properties of Interstitial Chlorine in CdTe
Indexación: Scopus.We acknowledge support from Chilean funding agency FONDECYT under Grants No. 1170480 (W.O.) and 1171807 (E.M-P.). Powered@NLHPC: This research was partially supported by the supercomputing infrastructure of the NLHPC (ECM-02).The role of interstitial chlorine in the electronic properties of CdTe is addressed by density functional theory calculations including hybrid functionals and large unit cells. The stability and diffusion energy barriers of the impurity are analyzed as a function of the Fermi level position in the band gap. Chlorine is found to be stable in at least five interstitial sites with rather close formation energies, suggesting that they are all probable to be found. In p-type CdTe, the most stable sites are at the center of a CdTe bond and at a split-interstitial configuration, both acting as shallow donors. Whereas in n-type CdTe, it is found at the tetrahedral site surrounded by Cd hosts, acting as a shallow acceptor. We also find that chlorine can induce a deep acceptor level in the bandgap after binding with three Cd host atoms, which can explain the experimentally observed high resistivity in Cl-doped CdTe. The energy barriers for chlorine diffusion in both p-type and n-type CdTe are also discussed. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheimhttps://onlinelibrary.wiley.com/doi/full/10.1002/pssb.20180021
Two-neutrino double electron capture on Xe based on an effective theory and the nuclear shell model
We study the two-neutrino double electron capture on Xe based on an
effective theory (ET) and large-scale shell model calculations, two modern
nuclear structure approaches that have been tested against Gamow-Teller and
double-beta decay data. In the ET, the low-energy constants are fit to electron
capture and transitions around xenon. For the nuclear shell model,
we use an interaction in a large configuration space that reproduces the
spectroscopy of nuclei in this mass region. For the dominant transition to the
Te ground state, we find half-lives y for the ET and y for the shell model. The ET uncertainty leads to
a half-life almost entirely consistent with present experimental limits and
largely within the reach of ongoing experiments. The shell model half-life
range overlaps with the ET, but extends less beyond current limits. Our
findings thus suggest that the two-neutrino double electron capture on
Xe has a good chance to be discovered by ongoing or future experiments.
In addition, we present results for the two-neutrino double electron capture to
excited states of Te.Comment: 5 pages, 2 figure
Mexican Health Sector Policy (1980—2004): Structural Adjustment and Pragmatism of Neoliberal Proposals
Objectives: To analyze continuity/discontinuity processes in health programs and policies implemented in Mexico during the 1990s and the early twenty-first century, and compare them to those of the 1980s
Coexistence of spherical states with deformed and superdeformed bands in doubly magic 40-Ca; A shell model challenge
Large scale shell model calculations, with dimensions reaching 10**9, are
carried out to describe the recently observed deformed (ND) and superdeformed
(SD) bands based on the first and second excited 0+ states of 40-Ca at 3.35-MeV
and 5.21-MeV respectively. A valence space comprising two major oscillator
shells, sd and pf, can accommodate most of the relevant degrees of freedom of
this problem. The ND band is dominated by configurations with four particles
promoted to the pf-shell (4p-4h in short). The SD band by 8p-8h configurations.
The ground state of 40-Ca is strongly correlated, but the closed shell still
amounts to 65%. The energies of the bands are very well reproduced by the
calculations. The out-band transitions connecting the SD band with other states
are very small and depend on the details of the mixing among the different
np-nh configurations, in spite of that, the calculation describes them
reasonably. For the in-band transition probabilities along the SD band, we
predict a fairly constant transition quadrupole moment Q_0(t)~170 e fm**2 up to
J=10, that decreases toward the higher spins. We submit also that the J=8
states of the deformed and superdeformed band are maximally mixed.Comment: 12 pages, 9 figure
Electric field and exciton structure in CdSe nanocrystals
Quantum Stark effect in semiconductor nanocrystals is theoretically
investigated, using the effective mass formalism within a
Baldereschi-Lipari Hamiltonian model for the hole states. General expressions
are reported for the hole eigenfunctions at zero electric field. Electron and
hole single particle energies as functions of the electric field
() are reported. Stark shift and binding energy of the
excitonic levels are obtained by full diagonalization of the correlated
electron-hole Hamiltonian in presence of the external field. Particularly, the
structure of the lower excitonic states and their symmetry properties in CdSe
nanocrystals are studied. It is found that the dependence of the exciton
binding energy upon the applied field is strongly reduced for small quantum dot
radius. Optical selection rules for absorption and luminescence are obtained.
The electric-field induced quenching of the optical spectra as a function of
is studied in terms of the exciton dipole matrix element. It
is predicted that photoluminescence spectra present anomalous field dependence
of the emission lines. These results agree in magnitude with experimental
observation and with the main features of photoluminescence experiments in
nanostructures.Comment: 9 pages, 7 figures, 1 tabl
Getting ahead of the arms race: hothousing the coevolution of VirusTotal with a Packer
Malware detection is in a coevolutionary arms race where the attackers and defenders are constantly seeking advantage. This arms race is asymmetric: detection is harder and more expensive than evasion. White hats must be conservative to avoid false positives when searching for malicious behaviour. We seek to redress this imbalance. Most of the time, black hats need only make incremental changes to evade them. On occasion, white hats make a disruptive move and find a new technique that forces black hats to work harder. Examples include system calls, signatures and machine learning. We present a method, called Hothouse, that combines simulation and search to accelerate the white hat’s ability to counter the black hat’s incremental moves, thereby forcing black hats to perform disruptive moves more often. To realise Hothouse, we evolve EEE, an entropy-based polymorphic packer for Windows executables. Playing the role of a black hat, EEE uses evolutionary computation to disrupt the creation of malware signatures. We enter EEE into the detection arms race with VirusTotal, the most prominent cloud service for running anti-virus tools on software. During our 6 month study, we continually improved EEE in response to VirusTotal, eventually learning a packer that produces packed malware whose evasiveness goes from an initial 51.8% median to 19.6%. We report both how well VirusTotal learns to detect EEE-packed binaries and how well VirusTotal forgets in order to reduce false positives. VirusTotal’s tools learn and forget fast, actually in about 3 days. We also show where VirusTotal focuses its detection efforts, by analysing EEE’s variants
Ant colony optimization for object-oriented unit test generation
Generating useful unit tests for object-oriented programs is difficult for traditional optimization methods. One not only needs to identify values to be used as inputs, but also synthesize a program which creates the required state in the program under test. Many existing Automated Test Generation (ATG) approaches combine search with performance-enhancing heuristics. We present Tiered Ant Colony Optimization (Taco) for generating unit tests for object-oriented programs. The algorithm is formed of three Tiers of ACO, each of which tackles a distinct task: goal prioritization, test program synthesis, and data generation for the synthesised program. Test program synthesis allows the creation of complex objects, and exploration of program state, which is the breakthrough that has allowed the successful application of ACO to object-oriented test generation. Taco brings the mature search ecosystem of ACO to bear on ATG for complex object-oriented programs, providing a viable alternative to current approaches. To demonstrate the effectiveness of Taco, we have developed a proof-of-concept tool which successfully generated tests for an average of 54% of the methods in 170 Java classes, a result competitive with industry standard Randoop
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