4,733 research outputs found
Optical properties of an ensemble of G-centers in silicon
We addressed the carrier dynamics in so-called G-centers in silicon
(consisting of substitutional-interstitial carbon pairs interacting with
interstitial silicons) obtained via ion implantation into a
silicon-on-insulator wafer. For this point defect in silicon emitting in the
telecommunication wavelength range, we unravel the recombination dynamics by
time-resolved photoluminescence spectroscopy. More specifically, we performed
detailed photoluminescence experiments as a function of excitation energy,
incident power, irradiation fluence and temperature in order to study the
impact of radiative and non-radiative recombination channels on the spectrum,
yield and lifetime of G-centers. The sharp line emitting at 969 meV (1280
nm) and the broad asymmetric sideband developing at lower energy share the same
recombination dynamics as shown by time-resolved experiments performed
selectively on each spectral component. This feature accounts for the common
origin of the two emission bands which are unambiguously attributed to the
zero-phonon line and to the corresponding phonon sideband. In the framework of
the Huang-Rhys theory with non-perturbative calculations, we reach an
estimation of 1.60.1 \angstrom for the spatial extension of the
electronic wave function in the G-center. The radiative recombination time
measured at low temperature lies in the 6 ns-range. The estimation of both
radiative and non-radiative recombination rates as a function of temperature
further demonstrate a constant radiative lifetime. Finally, although G-centers
are shallow levels in silicon, we find a value of the Debye-Waller factor
comparable to deep levels in wide-bandgap materials. Our results point out the
potential of G-centers as a solid-state light source to be integrated into
opto-electronic devices within a common silicon platform
Anharmonic magnetic deformation of self-assembled molecular nanocapsules
High magnetic fields were used to deform spherical nanocapsules,
self-assembled from bola-amphiphilic sexithiophene molecules. At low fields the
deformation -- measured through linear birefringence -- scales quadratically
with the capsule radius and with the magnetic field strength. These data
confirm a long standing theoretical prediction (W. Helfrich, Phys. Lett. {\bf
43A}, 409 (1973)), and permits the determination of the bending rigidity of the
capsules as (2.60.8) J. At high fields, an enhanced
rigidity is found which cannot be explained within the Helfrich model. We
propose a complete form of the free energy functional that accounts for this
behaviour, and allows discussion of the formation and stability of nanocapsules
in solution.Comment: 4 pages, 3 figures, accepted in Phys. Rev. Let
A matter of culture and cost? A comparison of the employment decisions made by mothers with a lower, intermediate and higher level of education in the Netherlands.
This article is focused on financial-economic and socio-cultural factors in explaining differences in labour participation and working hours of Dutch mothers with diverging educational levels. The data used are taken from a survey held among approximately 1700 women in the Netherlands from two-parent households with children up to 12 years old. The models for participation and working hours are simultaneously estimated for different levels of education. It is found that socio-cultural factors have slightly more impact on the employment decisions of lower educated mothers compared to their higher educated counterparts, although the differences are only minor. Despite the level of education, socio-cultural factors appear to be more important in mothers' employment decisions than financial-economic factors. In addition, both factors are better predictors for mothers' decisions to participate than for their number of working hours; demographic variables are found to be the most important predictor for mothers' working hours. © The Author(s) 2011
Effect of root spacing on interpretation of blade penetration tests-full-scale physical modelling
The spatial distribution of plant roots is an important parameter when the stability of vegetated slopes is to be assessed. Previous studies in both laboratory and field conditions have shown that a penetrometer adapted with a blade-shaped tip can be used to detect roots from sudden drops in penetrometer resistance. Such drops can be related to root properties including diameter, stiffness and strength using simpleWinkler foundation models, thereby providing a field instrument for rapid quantification of root properties and distribution. While this approach has proved useful for measuring single widely-spaced roots, it has not previously been determined how the penetrometer response changes as a result of roots being in close proximity. Therefore in this study 1-g physical modelling (at 1:1 scale) was conducted to study the effect of vertical root spacing using horizontal, straight 3D-printed root analogues. Results showthatwhen roots are closely spaced, there is significant interaction between them, resulting in higher apparent root displacements to failure and an increased amount of energy being dissipated. This preliminary work shows that the interpretive models used to analyse the penetrometer trace require further development to account for root-soil-root interactions in densely rooted soil.</p
Comparison of new <i>in situ </i>root-reinforcement measuring devices to existing techniques
Mechanical root-reinforcement is difficult to quantify. Existing in-situ methods are cumbersome, while modelling requires parameters which are difficult to acquire. In this paper, two new in-situ measurement devices are introduced ('cork screw' and 'pin vane') and their performance is compared to field vane and laboratory direct shear strength measurements in fallow and rooted soil. Both new methods show a close correlation with field vane readings in fallow soil. Tests in reinforced soil show that both new methods can be installed without significant root disturbance. The simplicity of both new methods allows for practical in-situ use and both can be used to study soil stress-strain behaviour, thus addressing some major limitations in existing methodologies for characterising rooted soil.</p
Anisotropic and strong negative magneto-resistance in the three-dimensional topological insulator Bi2Se3
We report on high-field angle-dependent magneto-transport measurements on
epitaxial thin films of Bi2Se3, a three-dimensional topological insulator. At
low temperature, we observe quantum oscillations that demonstrate the
simultaneous presence of bulk and surface carriers. The magneto- resistance of
Bi2Se3 is found to be highly anisotropic. In the presence of a parallel
electric and magnetic field, we observe a strong negative longitudinal
magneto-resistance that has been consid- ered as a smoking-gun for the presence
of chiral fermions in a certain class of semi-metals due to the so-called axial
anomaly. Its observation in a three-dimensional topological insulator implies
that the axial anomaly may be in fact a far more generic phenomenon than
originally thought.Comment: 6 pages, 4 figure
Collisional and thermal ionization of sodium Rydberg atoms I. Experiment for nS and nD atoms with n=8-20
Collisional and thermal ionization of sodium nS and nD Rydberg atoms with
n=8-20 has been studied. The experiments were performed using a two-step pulsed
laser excitation in an effusive atomic beam at atom density of about 2 10^{10}
cm^{-3}. Molecular and atomic ions from associative, Penning, and thermal
ionization processes were detected. It has been found that the atomic ions were
created mainly due to photoionization of Rydberg atoms by photons of blackbody
radiation at the ambient temperature of 300K. Blackbody ionization rates and
effective lifetimes of Rydberg states of interest were determined. The
molecular ions were found to be from associative ionization in Na(nL)+Na(3S)
collisions. Rate constants of associative ionization have been measured using
an original method based on relative measurements of Na_{2}^{+} and Na^{+} ion
signals.Comment: 23 pages, 10 figure
Stability of Colloidal Quasicrystals
Freezing of charge-stabilized colloidal suspensions and relative stabilities
of crystals and quasicrystals are studied using thermodynamic perturbation
theory. Macroion interactions are modelled by effective pair potentials
combining electrostatic repulsion with polymer-depletion or van der Waals
attraction. Comparing free energies -- counterion terms included -- for
elementary crystals and rational approximants to icosahedral quasicrystals,
parameters are identified for which one-component quasicrystals are stabilized
by a compromise between packing entropy and cohesive energy.Comment: 6 pages, 4 figure
Study of the Negative Magneto-Resistance of Single Proton-Implanted Lithium-Doped ZnO Microwires
The magneto-transport properties of single proton-implanted ZnO and of
Li(7\%)-doped ZnO microwires have been studied. The as-grown microwires were
highly insulating and not magnetic. After proton implantation the Li(7\%) doped
ZnO microwires showed a non monotonous behavior of the negative
magneto-resistance (MR) at temperature above 150 K. This is in contrast to the
monotonous NMR observed below 50 K for proton-implanted ZnO. The observed
difference in the transport properties of the wires is related to the amount of
stable Zn vacancies created at the near surface region by the proton
implantation and Li doping. The magnetic field dependence of the resistance
might be explained by the formation of a magnetic/non magnetic heterostructure
in the wire after proton implantation.Comment: 6 pages with 5 figure
- âŠ