Doppler-free Yb Spectroscopy with Fluorescence Spot Technique

We demonstrate a simple technique to measure the resonant frequency of the 398.9 nm 1S0 - 1P1 transition for the different Yb isotopes. The technique, that works by observing and aligning fluorescence spots, has enabled us to measure transition frequencies and isotope shifts with an accuracy of 60 MHz. We provide wavelength measurements for the transition that differ from previously published work. Our technique also allows for the determination of Doppler shifted transition frequencies for photoionisation experiments when the atomic beam and laser beam are not perpendicular and furthermore allows us to determine the average velocity of the atoms along the direction of atomic beam

Re II and Other Exotic Spectra in HD 65949

Powerful astronomical spectra reveal an urgent need for additional work on atomic lines, levels, and oscillator strengths. The star HD 65949 provides some excellent examples of species rarely identified in stellar spectra. For example, the Re II spectrum is well developed, with 17 lines between 3731 and 4904 [A], attributed wholly or partially to Re II. Classifications and oscillator strengths are lacking for a number of these lines. The spectrum of Os II is well identified. Of 14 lines attributed wholly or partially to Os II, only one has an entry in the VALD database. We find strong evidence that Te II is present. There are NO Te II lines in the VALD database. Ru II is clearly present, but oscillator strengths for lines in the visual are lacking. There is excellent to marginal evidence for a number of less commonly identified species, including Kr II, Nb II, Sb II, Xe II, Pr III, Ho III, Au II, and Pt II (probably Pt-198), to be present in the spectrum of HD 65949. The line Hg II at 3984 [A] is of outstanding strength, and all three lines of Multiplet 1 of Hg I are present, even though the surface temperature of HD 65949 is relatively high. Finally, we present the case of an unidentified, 24 [mA], line at 3859.63 [A], which could be the same feature seen in magnetic CP stars. It is typically blended with a putative U II line used in cosmochronology.Comment: ASOS9 Poster (Lund, Sweden, August 2007), to be published in Journal of Physics: Conference Series (JPCS), 6 pages 1 figur

Quantum transport through a DNA wire in a dissipative environment

Electronic transport through DNA wires in the presence of a strong dissipative environment is investigated. We show that new bath-induced electronic states are formed within the bandgap. These states show up in the linear conductance spectrum as a temperature dependent background and lead to a crossover from tunneling to thermal activated behavior with increasing temperature. Depending on the strength of the electron-bath coupling, the conductance at the Fermi level can show a weak exponential or even an algebraic length dependence. Our results suggest a new environmental-induced transport mechanism. This might be relevant for the understanding of molecular conduction experiments in liquid solution, like those recently performed on poly(GC) oligomers in a water buffer (B. Xu et al., Nano Lett 4, 1105 (2004)).Comment: 5 pages, 3 figure

Continuous synthesis of pyridocarbazoles and initial photophysical and bioprobe characterization

Pyridocarbazoles when ligated to transition metals yield high affinity kinase inhibitors. While batch photocyclizations enable the synthesis of these heterocycles, the non-oxidative Mallory reaction only provides modest yields and difficult to purify mixtures. We demonstrate here that a flow-based Mallory cyclization provides superior results and enables observation of a clear isobestic point. The flow method allowed us to rapidly synthesize ten pyridocarbazoles and for the first time to document their interesting photophysical attributes. Preliminary characterization reveals that these molecules might be a new class of fluorescent bioprobe

NBS monograph

From Abstract: "Comparisons with other intensity measurements in individual spectra indicate that the National Bureau of Standards spectral-line intensities may have average errors of 20 percent, but first of all they provide uniform quantitative values for the seventy chemical elements commonly determined by spectrochemists. These data are presented by element in part I, and all 39,000 observed lines are given in order of wavelength in part II.

NBS monograph

From Abstract: "Comparisons with other other intensity measurements in individual spectra indicate that the National Bureau of Standards spectral-line intensities may have average errors of 20 percent, but first of all they provide uniform quantitative values for the seventy chemical elements commonly determined by spectrochemists. These data are presented by element in part I, and all 39000 observed lines are given in order of wavelength in part II.

NBS monograph

Abstract: "These data are presented by element in part I, and all 39,000 observed lines are given in order of wavelength in Part II." From Introduction: "In the beginning, most intensity data were reported on an arbitrary scale of 10 steps, weak lines being assigned an intensity of 1, and the strongest line intensity 10.

Ab-initio study of model guanine assemblies: The role of pi-pi coupling and band transport

Several assemblies of guanine molecules are investigated by means of first-principle calculations. Such structures include stacked and hydrogen-bonded dimers, as well as vertical columns and planar ribbons, respectively, obtained by periodically replicating the dimers. Our results are in good agreement with experimental data for isolated molecules, isolated dimers, and periodic ribbons. For stacked dimers and columns, the stability is affected by the relative charge distribution of the pi orbitals in adjacent guanine molecules. pi-pi coupling in some stacked columns induces dispersive energy bands, while no dispersion is identified in the planar ribbons along the connections of hydrogen bonds. The implications for different materials comprised of guanine aggregates are discussed. The bandstructure of dispersive configurations may justify a contribution of band transport (Bloch type) in the conduction mechanism of deoxyguanosine fibres, while in DNA-like configurations band transport should be negligible.Comment: 21 pages, 6 figures, 3 tables, to be published in Phys. Rev.