Ion-Molecule Reactions in Unsaturated Hydrocarbons: Allene, Propyne, Diacetylene, and Vinylacetylene

Ion-molecule reactions in allene, propyne, diacetylene, and vinylacetylene (1-buten-3-yne) have been studied at near-thermal energies by the technique of ion cyclotron resonance mass spectrometry. Rate coefficients and branching ratios are reported for the reactions of C_3H^+_n (n = 1-4) with allene and propyne and for the reactions of C_4H^+_n (n = 0-5) with diacetylene and vinylacetylene. Branching ratios are also given for the reactions of C_4H^+_n, C_5H_n, and C_6H^+_n with propyne and for reactions of C_6H^+_n with diacetylene and vinylacetylene. More than 90% of the reactive channels lead to product ions having a larger carbon skeleton than the reactant ion. Evidence for ions with the same m/e ratio having differing reactivities was obtained for C_3H^+_3, C_6H^+_7, and C_7H^+_7. Ion reaction sequences in allene and propyne were followed at higher pressures (l0^(-4) torr) to investigate secondary, tertiary, and higher order processes

Investigation of prediction methods for the loads and stresses of Apollo type spacecraft parachutes. Volume 1: Loads

An analysis was conducted with the objective of upgrading and improving the loads, stress, and performance prediction methods for Apollo spacecraft parachutes. The subjects considered were: (1) methods for a new theoretical approach to the parachute opening process, (2) new experimental-analytical techniques to improve the measurement of pressures, stresses, and strains in inflight parachutes, and (3) a numerical method for analyzing the dynamical behavior of rapidly loaded pilot chute risers

An Attention-based Bidirectional LSTM Model for Continuous Cross-subject Estimation of Knee Joint Angle during Running from sEMG Signals

Running is an essential locomotion activity that plays a critical role in everyday life and exercise activities and may be impeded by joint disease and neurological impairments. Accurate and robust estimation of joint kinematics via surface electromyogram (sEMG) signals provides a human-machine interaction-based method that can be used to adequately control rehabilitation robots while performing complex movements such as running for motor function restoration in affected persons. To this end, this paper proposes a novel deep learning-based model (AM-BiLSTM) that integrates an attention mechanism (AM) and a bidirectional long short-term memory (BiLSTM) network. The proposed method was evaluated using knee joint kinematic and sEMG signals of fourteen subjects who performed running at 2 m/s speed. The proposed model’s generalizability was tested for within- and cross-subject scenarios and compared with standard LSTM and multi-layer perceptron (MLP) networks in terms of normalized root-mean-square error and correlation coefficient evaluation metrics. Based on the statistical tests, the proposed AM-BiLSTM model significantly outperformed the LSTM and MLP methods in both within- and cross-subject scenarios (p<0.05) and achieved state-of-the-art performance. © 20XX IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works

Stability of Ca-montmorillonite hydrates: A computer simulation study

Classic simulations are used to study interlayer structure, swelling curves, and stability of Ca-montmorillonite hydrates. For this purpose, NPzzT$ and MuPzzT ensembles are sampled for ground level and given burial conditions. For ground level conditions, a double layer hydrate having 15.0 A of basal spacing is the predominant state for relative vapor pressures (p/po) ranging in 0.6-1.0. A triple hydrate counting on 17.9 A of interlaminar distance was also found stable for p/po=1.0. For low vapor pressures, the system may produce a less hydrated but still double layer state with 13.5 A or even a single layer hydrate with 12.2 A of interlaminar distance. This depends on the established initial conditions. On the other hand, the effect of burial conditions is two sided. It was found that it enhances dehydration for all vapor pressures except for saturation, where swelling is promoted.Comment: 8 pages, 9 figure

Effect of seasonal diet composition changes on the characteristics of the gastrointestinal tract contents of the Eurasian beaver (Castor fiber).

The goal of the study was to compare chemical and physical parameters of the content of various gastrointestinal (GI) tract segments of adult beavers and to relate the obtained results to seasonal changes in the composition of natural diet. The study was conducted on 36 adult beavers originated from the natural environment that were captured in winter, summer and autumn. The obtained results demonstrated that pH, redox potential (Eh), dry matter (DM), short-chain fatty acids (SCFA) and distribution of food particles varied along the beaver GI tract during the year. The lowest value of pH was observed in stomach whereas the highest in the small intestine and cecum. The reverse pattern of changes was found for the value of redox potential. The research indicated that anaerobic conditions were predominant in the cecum and so contributed to development of microbial population. Also, the increase in the SCFA contents in the cecum and colon indicated that beavers belong both to hindgut fermenters as well as to the mixed moderate type animals. In summary, the obtained results indicated that seasonal changes in the diet composition affected physical and chemical parameters as well as microbial activity of the GI tract of beaver

Dynamics of Inflationary Universes with Positive Spatial Curvature

If the spatial curvature of the universe is positive, then the curvature term will always dominate at early enough times in a slow-rolling inflationary epoch. This enhances inflationary effects and hence puts limits on the possible number of e-foldings that can have occurred, independently of what happened before inflation began and in particular without regard for what may have happened in the Planck era. We use a simple multi-stage model to examine this limit as a function of the present density parameter $\Omega_0$ and the epoch when inflation ends.Comment: 9 Pages RevTex4. Revised and update

Disease associated polymorphisms within the conserved ECR1 enhancer differentially regulate the tissue specific activity of the cannabinoid‐1 receptor gene promoter; implications for cannabinoid pharmacogenetics

EH was funded by Medical Research Scotland (PhD-719-2013) and GW Pharmaceuticals. AMcE was funded by BBSRC project grant (BB/N017544/1). PB and DW are funded by the Scottish Government Rural and Environment Science and Analytical Services Division to the Rowett Institute. The authors declare no conflicts of interest.Peer reviewedPublisher PD

On the period ratio P₁/2P₂ in the oscillations of coronal loops

&lt;p&gt;Aims. With strong evidence of fast and slow magnetoacoustic modes arising in the solar atmosphere there is scope for improved determinations of coronal parameters through coronal seismology. Of particular interest is the ratio P&lt;sub&gt;1&lt;/sub&gt;/2P&lt;sub&gt;2&lt;/sub&gt;between the period P&lt;sub&gt;1&lt;/sub&gt; of the fundamental mode and the period P&lt;sub&gt;2&lt;/sub&gt; of its first harmonic; in an homogeneous medium this ratio is one, but in a more complex configuration it is shifted to lower values.&lt;/p&gt; &lt;p&gt;Methods. We consider analytically the effects on the different magnetohydrodynamic modes of structuring and stratification, pointing out that transverse or longitudinal structuring or gravitational stratification modifies the ratio P&lt;sub&gt;1&lt;/sub&gt;/2P&lt;sub&gt;2&lt;/sub&gt;.&lt;/p&gt; &lt;p&gt;Results. The deviations caused by gravity and structure are studied for the fast and slow modes. Structure along the loop is found to be the dominant effect.&lt;/p&gt; &lt;p&gt;Conclusions. The departure of P&lt;sub&gt;1&lt;/sub&gt;/2P&lt;sub&gt;2&lt;/sub&gt; from unity can be used as a seismological tool in the corona. We apply our technique to the observations by Verwichte et al. (2004), deducing the density scale height in a coronal loop.&lt;/p&gt

Molecular analysis of type 3 fimbrial genes from Escherichia coli, Klebsiella and Citrobacter species

Background: Catheter-associated urinary tract infection (CAUTI) is the most common nosocomial infection in the United States and is caused by a range of uropathogens. Biofilm formation by uropathogens that cause CAUTI is often mediated by cell surface structures such as fimbriae. In this study, we characterised the genes encoding type 3 fimbriae from CAUTI strains of Escherichia coli, Klebsiella pneumoniae, Klebsiella oxytoca, Citrobacter koseri and Citrobacter freundii