Dissolved gas separation for engineered anaerobic wastewater systems

Dissolved gases produced within engineered anaerobic processes subsequently create a fugitive emission which can have financial, environmental and health and safety implications. Whilst desorption technology has been used to control dissolved gases in the drinking water sector, there is considerably less understanding of its deployment in wastewater for which there are numerous existing and emerging challenges. This review therefore focuses on existing and proposed technological approaches to gas desorption in engineered anaerobic wastewater processes, with specific emphasis on technology compatibility and downstream gas phase management. Simplified engineered solutions such as diffused aeration and multi-tray aerators appear robust solutions for implementation into wastewater. However, these processes are characterised by a low mass transfer coefficient and require high gas to liquid ratios (G/L) to achieve reasonable separation, which suggests their suitability is limited to small scale applications, in which gas recovery is not a priority. Packed columns and membrane contactors afford process intensification through increasing interfacial area which favours large scale applications; although both will require prefiltration technology to obviate media clogging. Vacuum or steam is the preferred driving force for separation when gas recovery is sought, while sweep-gas is energetically favoured. Sweep-gas has been used for gas recovery by operating at G/L toward the equilibrium value, which somewhat constrains mass transfer. Process selection must therefore be weighted on whole life cost, but will also be dependent upon process scale, financial (e.g. incentivisation) and non-financial (e.g. carbon) instruments, which are strongly influenced by regional policy

Modelling fungal colonies and communities:challenges and opportunities

This contribution, based on a Special Interest Group session held during IMC9, focuses on physiological based models of filamentous fungal colony growth and interactions. Fungi are known to be an important component of ecosystems, in terms of colony dynamics and interactions within and between trophic levels. We outline some of the essential components necessary to develop a fungal ecology: a mechanistic model of fungal colony growth and interactions, where observed behaviour can be linked to underlying function; a model of how fungi can cooperate at larger scales; and novel techniques for both exploring quantitatively the scales at which fungi operate; and addressing the computational challenges arising from this highly detailed quantification. We also propose a novel application area for fungi which may provide alternate routes for supporting scientific study of colony behaviour. This synthesis offers new potential to explore fungal community dynamics and the impact on ecosystem functioning

Changing epidemiology of methicillin-resistant Staphylococcus aureus colonization in paediatric intensive-care units

Community-associated methicillin-resistant S. aureus (CA-MRSA) accounts for a growing proportion of hospital-onset infections, and colonization is a risk factor. This study aimed to determine changes in the prevalence of CA-MRSA colonization in paediatric intensive-care units (ICUs). A total of 495 paediatric patients colonized with MRSA from neonatal, medical, surgical, and cardiac ICUs between 2001 and 2009 were identified. Isolates were characterized by spa type, staphylococcal cassette chromosome (SCC) mec type and the presence of the genes encoding Panton–Valentine leukocidin (PVL). The proportion of patients colonized with MRSA remained stable (average 3·2%). The proportion of isolates with spa type 1, SCCmec type IV and PVL increased over time to maximums in 2009 of 36·1% (P < 0·001), 54·2% (P = 0·03) and 28·9% (P = 0·003), respectively. Antibiotic susceptibility patterns showed increasing proportions susceptible to clindamycin, gentamicin, tetracycline and trimethoprim-sulfamethoxazole (P values <0·001). In conclusion, the proportion of MRSA-colonized children in ICUs with CA-MRSA increased significantly over time

Compositional Explanation of Types and Algorithmic Debugging of Type Errors

The type systems of most typed functional programming languages are based on the Hindley-Milner type system. A practical problem with these type systems is that it is often hard to understand why a program is not type correct or a function does not have the intended type. We suggest that at the core of this problem is the difficulty of explaining why a given expression has a certain type. The type system is not defined compositionally. We propose to explain types using a variant of the Hindley-Milner type system that defines a compositional type explanation graph of principal typings. We describe how the programmer understands types by interactive navigation through the explanation graph. Furthermore, the explanation graph can be the foundation for algorithmic debugging of type errors, that is, semi-automatic localisation of the source of a type error without even having to understand the type inference steps. We implemented a prototype of a tool to explore the usefulness of the proposed methods

delta C-13 Analysis of Mars Analog Carbonates Using Evolved Gas Cavity - Ringdown Spectrometry on the 2010 Arctic Mars Analog Svalbard Expedition (AMASE)

The 2010 Arctic Mars Analog Svalbard Expedition (AMASE) investigated two distinct geologic settings on Svalbard, using instrumentation and techniques in development for future Mars missions, such as the Mars Science Laboratory (MSL), ExoMars, and Mars Sample Return (MSR). The Sample Analysis at Mars (SAM) instrument suite, which will fly on MSL, was developed at Goddard Space Flight Center (GSFC), together with several partners. SAM consists of a quadrupole mass spectrometer (QMS), a gas chromatograph CGC), and a tunable laser spectrometer (TLS), which all analyze gases created by evolved gas analysis (EGA). The two sites studied represent "biotic" and "abiotic" analogs; the "biotic" site being the Knorringfjell fossil methane seep, and the "abiotic" site being the basaltic Sigurdfjell vent complex. The data presented here represent experiments to measure the carbon isotopic composition of carbonates from these two analogs using evolved gas analysis coupled with a commercial cavity ringdown CO2 isotopic analyzer (Picarro) as a proxy for the TLS on SAM

Visible, Near-Infrared, and Mid-Infrared Spectral Characterization of Hawaiian Fumarolic Alteration Near Kilauea's December 1974 Flow: Implications for Spectral Discrimination of Alteration Environments on Mars

The December 1974 flow in the SW rift zone at Kilauea Volcano, Hawaii, has been established as a Mars analog due to its physical, chemical, and morphological properties, as well as its interaction with the outgassing plume from the primary Kilauea caldera. We focus on a solfatara site that consists of hydrothermally altered basalt and alteration products deposited in and around a passively degassing volcanic vent situated directly adjacent to the December 1974 flow on its northwest side. Reflectance spectra are acquired in the visible/near-infrared (VNIR) region and emission spectra in the mid-infrared (MIR) range to better understand the spectral properties of hydrothermally altered materials. The VNIR signatures are consistent with silica, Fe-oxides, and sulfates (Ca, Fe). Primarily silica-dominated spectral signatures are observed in the MIR and changes in spectral features between samples appear to be driven by grain size effects in this wavelength range. The nature of the sample coating and the thermal emission signatures exhibit variations that may be correlated with distance from the vent. Chemical analyses indicate that most surfaces are characterized by silica-rich material, Fe-oxides, and sulfates (Ca, Fe). The silica and Fe-oxide-dominated MIR/VNIR spectral signatures exhibited by the hydrothermally altered material in this study are distinct from the sulfate-dominated spectral signatures exhibited by previously studied low-temperature aqueous acid-sulfate weathered basaltic glass. This likely reflects a difference in open vs. closed system weathering, where mobile cations are removed from the altered surfaces in the fumarolic setting. This work provides a unique infrared spectral library that includes martian analog materials that were altered in an active terrestrial solfatara (hydrothermal) setting. Hydrothermal environments are of particular interest as they potentially indicate habitable conditions. Key constraints on the habitability and astrobiological potential of ancient aqueous environments are provided through detection and interpretation of secondary mineral assemblages; thus, spectral detection of fumarolic alteration assemblages observed from this study on Mars would suggest a region that could have hosted a habitable environment

Hybrid membrane distillation reverse electrodialysis configuration for water and energy recovery from human urine: an opportunity for off-grid decentralised sanitation

The integration of membrane distillation with reverse electrodialysis has been investigated as a sustainable sanitation solution to provide clean water and electrical power from urine and waste heat. Reverse electrodialysis was integrated to provide the partial remixing of the concentrate (urine) and diluate (permeate) produced from the membrane distillation of urine. Broadly comparable power densities to those of a model salt solution (sodium chloride) were determined during evaluation of the individual and combined contribution of the various monovalent and multivalent inorganic and organic salt constituents in urine. Power densities were improved through raising feed-side temperature and increasing concentration in the concentrate, without observation of limiting behaviour imposed by non-ideal salt and water transport. A further unique contribution of this application is the limited volume of salt concentrate available, which demanded brine recycling to maximise energy recovery analogous to a battery, operating in a ‘state of charge’. During recycle, around 47% of the Gibbs free energy was recoverable with up to 80% of the energy extractable before the concentration difference between the two solutions was halfway towards equilibrium which implies that energy recovery can be optimised with limited effect on permeate quality. This study has provided the first successful demonstration of an integrated MD-RED system for energy recovery from a limited resource, and evidences that the recovered power is sufficient to operate a range of low current fluid pumping technologies that could help deliver off-grid sanitation and clean water recovery at single household scale

A Universal Model of Global Civil Unrest

Civil unrest is a powerful form of collective human dynamics, which has led to major transitions of societies in modern history. The study of collective human dynamics, including collective aggression, has been the focus of much discussion in the context of modeling and identification of universal patterns of behavior. In contrast, the possibility that civil unrest activities, across countries and over long time periods, are governed by universal mechanisms has not been explored. Here, we analyze records of civil unrest of 170 countries during the period 1919-2008. We demonstrate that the distributions of the number of unrest events per year are robustly reproduced by a nonlinear, spatially extended dynamical model, which reflects the spread of civil disorder between geographic regions connected through social and communication networks. The results also expose the similarity between global social instability and the dynamics of natural hazards and epidemics.Comment: 8 pages, 3 figure