7,960 research outputs found
Transient currents in a molecular photo-diode
Light-induced charge transmission through a molecular junction (molecular
diode) is studied in the framework of a HOMO-LUMO model and in using a kinetic
description. Expressions are presented for the sequential (hopping) and direct
(tunneling) transient current components together with kinetic equations
governing the time-dependent populations of the neutral and charged molecular
states which participate in the current formation. Resonant and off-resonant
charge transmission processes are analyzed in detail. It is demonstrated that
the transient currents are associated with a molecular charging process which
is initiated by photo excitation of the molecule. If the coupling of the
molecule to the electrodes is strongly asymmetric the transient currents can
significantly exceed the steady state current.Comment: 17 pages, 12 figures, accepted for publication in Chemical Physic
Can Long-Range Nuclear Properties Be Influenced By Short Range Interactions? A chiral dynamics estimate
Recent experiments and many-body calculations indicate that approximately
20\% of the nucleons in medium and heavy nuclei () are part of
short-range correlated (SRC) primarily neutron-proton () pairs. We find
that using chiral dynamics to account for the formation of pairs due to
the effects of iterated and irreducible two-pion exchange leads to values
consistent with the 20\% level. We further apply chiral dynamics to study how
these correlations influence the calculations of nuclear charge radii, that
traditionally truncate their effect, to find that they are capable of
introducing non-negligible effects.Comment: 6 pages, 0 figures. This version includes many improvement
IR optical fiber-based noncontact pyrometer for drop tube instrumentation
The design of a two color pyrometer with infrared optical fiber bundles for collection of the infrared radiation is described. The pyrometer design is engineered to facilitate its use for measurement of the temperature of small, falling samples in a microgravity materials processing experiment using a 100 meter long drop tube. Because the samples are small and move rapidly through the field of view of the pyrometer, the optical power budget of the detection system is severly limited. Strategies for overcoming this limitation are discussed
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Radiation exposure awareness from patients undergoing nuclear medicine diagnostic 99mTc-MDP bone scans and 2-deoxy-2-(18F) fluoro-D-glucose PET/computed tomography scans
INTRODUCTION: Medical imaging is on average the largest source of artificial radiation exposure worldwide. This study seeks to understand patient's awareness of radiation exposure derived from nuclear medicine diagnostic scans and assess if current information provided by leaflets is adequate.
METHODS: Single-centre cross-sectional questionnaire study applied to bone scan and FDG PET/computed tomography patients, at a nuclear medicine and PET/computed tomography department over a 15-week period in 2018. Questionnaires on dose comparators were designed in collaboration with patients, public, and experts in radiation exposure. Qualitative data were analysed using thematic analysis and quantitative data using SPSS (V. 24).
RESULTS: A total of 102 questionnaires were completed (bone scan = 50; FDG PET/computed tomography = 52). Across both groups, 33/102 (32.4%) patients reported having a reasonable understanding of nuclear medicine and 21/102 (20.6%) reported a reasonable knowledge of ionising radiations. When asked to compare the exposure dose of respective scans with common comparators 8/50 (16%) of bone scan patients and 11/52 (21.2%) FDG PET/computed tomography answered correctly. On leaflet information, 15/85 (17.6%) patients reported the leaflets do not provide enough information on radiation exposure and of these 10/15 (66.7%) commented the leaflets should incorporate more information on radiation exposure dose.
CONCLUSION: More observational and qualitative studies in collaboration with patients are warranted to evaluate patients' understanding and preferences in communication of radiation exposure from nuclear medicine imaging. This will ensure communication tools and guidelines developed to comply with ionising radiation (medical exposure) regulation 2017 are according to patients needs and preferences
Phonon self-energy and origin of anomalous neutron scattering spectra in SnTe and PbTe thermoelectrics
The anharmonic lattice dynamics of rock-salt thermoelectric compounds SnTe
and PbTe are investigated with inelastic neutron scattering (INS) and
first-principles calculations. The experiments show that, surprisingly,
although SnTe is closer to the ferroelectric instability, phonon spectra in
PbTe exhibit a more anharmonic character. This behavior is reproduced in
first-principles calculations of the temperature-dependent phonon self-energy.
Our simulations reveal how the nesting of phonon dispersions induces prominent
features in the self-energy, which account for the measured INS spectra and
their temperature dependence. We establish that the phase-space for
three-phonon scattering processes, rather than just the proximity to the
lattice instability, is the mechanism determining the complex spectrum of the
transverse-optical ferroelectric mode
Scalar conservation laws with nonconstant coefficients with application to particle size segregation in granular flow
Granular materials will segregate by particle size when subjected to shear,
as occurs, for example, in avalanches. The evolution of a bidisperse mixture of
particles can be modeled by a nonlinear first order partial differential
equation, provided the shear (or velocity) is a known function of position.
While avalanche-driven shear is approximately uniform in depth, boundary-driven
shear typically creates a shear band with a nonlinear velocity profile. In this
paper, we measure a velocity profile from experimental data and solve initial
value problems that mimic the segregation observed in the experiment, thereby
verifying the value of the continuum model. To simplify the analysis, we
consider only one-dimensional configurations, in which a layer of small
particles is placed above a layer of large particles within an annular shear
cell and is sheared for arbitrarily long times. We fit the measured velocity
profile to both an exponential function of depth and a piecewise linear
function which separates the shear band from the rest of the material. Each
solution of the initial value problem is non-standard, involving curved
characteristics in the exponential case, and a material interface with a jump
in characteristic speed in the piecewise linear case
Time resolved in situ spectroscopy during formation of the GaP Si 100 heterointerface
Though III V Si 100 heterointerfaces are essential for future epitaxial high performance devices, their atomic structure is an open historical question. Benchmarking of transient optical in situ spectroscopy during chemical vapor deposition to chemical analysis by X ray photoelectron spectroscopy enables us to distinguish between formation of surfaces and of the heterointerface. A terrace related optical anisotropy signal evolves during pulsed GaP nucleation on single domain Si 100 surfaces. This dielectric anisotropy agrees well with the one calculated for buried GaP Si 100 interfaces from differently thick GaP epilayers. X ray photoelectron spectroscopy reveals a chemically shifted contribution of the P and Si emission lines, which quantitatively corresponds to one monolayer and establishes simultaneously with the nucleation related optical in situ signal. We attribute that contribution to the existence of Si P bonds at the buried heterointerface. During further pulsing and annealing in phosphorus ambient, dielectric anisotropies known from atomically well ordered GaP 100 surfaces super impose the nucleation related optical in situ spectra. Figure Presente
Phonon density of states and heat capacity of La_(3−x)Te_4
The phonon density of states (DOS) of La_(3−x)Te_4 compounds (x=0.0,0.18,0.32) was measured at 300, 520, and 780 K, using inelastic neutron scattering. A significant stiffening of the phonon DOS and a large broadening of features were observed upon introduction of vacancies on La sites (increasing x). Heat-capacity measurements were performed at temperatures 1.85 ≤ T ≤ 1200 K and were analyzed to quantify the contributions of phonons and electrons. The Debye temperature and the electronic coefficient of heat capacity determined from these measurements are consistent with the neutron-scattering results, and with previously reported first-principles calculations. Our results indicate that La vacancies in La_(3−x)Te_4 strongly scatter phonons and this source of scattering appears to be independent of temperature. The stiffening of the phonon DOS induced by the introduction of vacancies is explained in terms of the electronic structure and the change in bonding character. The temperature dependence of the phonon DOS is captured satisfactorily by the quasiharmonic approximation
Systems, interactions and macrotheory
A significant proportion of early HCI research was guided by one very clear vision: that the existing theory base in psychology and cognitive science could be developed to yield engineering tools for use in the interdisciplinary context of HCI design. While interface technologies and heuristic methods for behavioral evaluation have rapidly advanced in both capability and breadth of application, progress toward deeper theory has been modest, and some now believe it to be unnecessary. A case is presented for developing new forms of theory, based around generic “systems of interactors.” An overlapping, layered structure of macro- and microtheories could then serve an explanatory role, and could also bind together contributions from the different disciplines. Novel routes to formalizing and applying such theories provide a host of interesting and tractable problems for future basic research in HCI
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