Caledonian and Pre-Caledonian orogenic events in Shetland, Scotland:evidence from garnet Lu-Hf and Sm-Nd geochronology

Garnet Lu-Hf and Sm-Nd ages from the Shetland Caledonides provide evidence of a pollorogenic history as follows: 1) c. 1050 Ma Grenvillian reworking of Neoarchaean basement; 2) c. 910 Ma Renlandian metamorphism of the Westing Group; 3) c. 622-606 Ma metamorphism of the Walls Metamorphic Series but of uncertain significance because the eastern margin of Laurentia is thought to have been in extension at that time; 4) Grampian I ophiolite obduction at c. 491 Ma followed by crustal thickening and metamorphism between c. 485 and c. 466 Ma; 5) Grampian II metamorphism between c. 458 and c. 442 Ma that appears to have been focused in areas here pre-existing foliations ere gentle-inclined and thus may have been relatively easily reworked; 6) Scandian metamorphism at c. 430 Ma, although the paucity of these ages suggests that much of Shetland did not attain temperatures for garnet growth. There is no significant difference in the timing of Caledonian orogenic events either side of the Walls Boundary Fault, although this need not preclude linkage with the Great Glen Fault. However, the incompatibility of Ediacaran events either side of the Walls Boundary Fault may indicate significant lateral displacement and requires further investigation

Geochemistry of the Late Holocene rocks from the Tolbachik volcanic field, Kamchatka: Quantitative modelling of subduction-related open magmatic systems

We present new major and trace element, high-precision Sr-Nd-Pb (double spike), and Oisotope data for the whole range of rocks from the Holocene Tolbachik volcanic field in the Central Kamchatka Depression (CKD). The Tolbachik rocks range from high-Mg basalts to low-Mg basaltic trachyandesites. The rocks considered in this paper represent mostly Late Holocene eruptions (using tephrochronological dating), including historic ones in 1941, 1975-1976 and 2012-2013. Major compositional features of the Tolbachik volcanic rocks include the prolonged predominance of one erupted magma type, close association of middle-K primitive and high-K evolved rocks, large variations in incompatible element abundances and ratios but narrow range in isotopic composition. We quantify the conditions of the Tolbachik magma origin and evolution and revise previously proposed models. We conclude that all Tolbachik rocks are genetically related by crystal fractionation of medium-K primary magmas with only a small range in trace element and isotope composition. The primary Tolbachik magmas contain ~14 wt% MgO and ~4% wt% H2O and originated by partial melting (~6%) of moderately depleted mantle peridotite with Indian-MORB-type isotopic composition at temperature of ~1250oC and pressure of ~2 GPa. The melting of the mantle wedge was triggered by slab-derived hydrous melts formed at ~2.8 GPa and ~725oC from a mixture of sediments and MORB- and Meiji- type altered oceanic crust. The primary magmas experienced a complex open-system evolution termed Recharge-Evacuation-Fractional Crystallization (REFC). First the original primary magmas underwent open-system crystal fractionation combined with periodic recharge of the magma chamber with more primitive magma, followed by mixing of both magma types, further fractionation and finally eruption. Evolved high-K basalts, which predominate in the Tolbachik field, and basaltic trachyandesites erupted in 2012-2013 approach steady-state REFC liquid compositions at different eruption or replenishment rates. Intermediate rocks, including high-K, high-Mg basalts, are formed by mixing of the evolved and primitive magmas. Evolution of Tolbachik magmas is associated with large fractionation between incompatible trace elements (e.g., Rb/Ba, La/Nb, Ba/Th) and is strongly controlled by the relative difference in partitioning between crystal and liquid phases. The Tolbachik volcanic field shows that open-system scenarios provide more plausible and precise descriptions of long-lived arc magmatic systems than simpler, but often geologically unrealistic, closed-system models

A new upper Paleogene to Neogene stratigraphy for Sarawak and Labuan in northwestern Borneo:Paleogeography of the eastern Sundaland margin

The Miri Zone in Sarawak contains thick Paleogene to Neogene sedimentary successions that extend offshore into the Sarawak Basin (Balingian and Central Luconia Provinces) and Sabah Basin. Exploration offshore has shown the Sarawak Basin in the South China Sea contains major hydrocarbon reservoirs. The sediments on land are age equivalents of the offshore successions and can be used to provide insights into their sedimentological and stratigraphic relations. However, because the rocks are found in mountainous regions covered by dense rainforest much of the stratigraphy in the Miri Zone is poorly known, as are timings and causes of major unconformities in the region that are essential for understanding the tectonic history, basin development, and sedimentary pathways. In this study we integrate fieldwork, U–Pb zircon dating, biostratigraphy, and light and heavy mineral analyses to present a revised stratigraphy for the region as well as paleogeographic maps, including major paleo-river systems for the main sedimentary basins. Rocks studied include parts of the Cretaceous to Eocene deep marine Rajang Group, fluvial to marginal marine sediments of the Oligocene to Early Miocene Tatau, Buan, Nyalau and Setap Shale Formations, and the Miocene sediments which are assigned to the Balingian, Begrih and Liang Formations in the Mukah-Balingian province, and the Belait Formation on Labuan. There is still much debate about the timings or even existence of some important unconformities offshore, such as the Middle Miocene Unconformity (MMU) and Deep Regional Unconformity (DRU). We propose to avoid the ambiguous time-based terminology that has been used for different events by different authors. Instead, our results from the on-land stratigraphy show two main unconformities in northern Sarawak; one at c. 37 Ma (Rajang Unconformity), marking the change from deep marine to fluvial – marginal marine sedimentation, and another one at c. 17 Ma (Nyalau Unconformity) which is related to widespread uplift in Borneo and changing river systems

Precambrian olistoliths masquerading as sills from Death Valley, California

Olistolith production and magmatism are processes commonly associated with extensional tectonic settings, such as rift basins. We present a cautionary exemplar from one such Precambrian basin, in which we reinterpret metabasite bodies, previously documented as sills, to be olistoliths. We nevertheless demonstrate that, on the basis of field observation alone, the previous but erroneous sill interpretation is parsimonious. Indeed, it is only by using isotopic age and compositional analysis that the true identities of these metabasite olistoliths are revealed. We present new data from metabasites and metasedimentary strata of the Kingston Peak Formation (Cryogenian) and Crystal Spring Formation (Mesoproterozoic) of Death Valley, USA. These include field observations, U?Pb apatite ages, U?Pb zircon ages (detrital and igneous) and whole-rock geochemistry. These data also provide a new maximum age for the base of the Pahrump Group and suggest that the Crystal Spring Diabase was more tholeiitic than previously thought. Similar sill/olistolith misinterpretations may have occurred elsewhere, potentially producing erroneous age and tectonic-setting interpretations of surrounding strata. This is particularly relevant in Precambrian rocks, where fossil age constraints are rare. This is illustrated herein using a potential example from the Neoproterozoic literature of the Lufilian belt, Africa. We caution others against Precambrian olistoliths masquerading as sills.publishersversionPeer reviewe

Arc crust formation of Lesser Antilles revealed by crustal xenoliths from Petit St. Vincent

The Lesser Antilles volcanic arc is known for its magmatic diversity and unusually abundant plutonic xenoliths. Xenoliths from Petit St. Vincent (Grenadines archipelago) are particularly interesting because of their textural and petrogenetic range. Here we combine petrographic observations, Electron Backscatter Diffraction (EBSD) analysis, major and trace element chemistry of xenoliths and lavas, and geochemical and thermal modelling to explore the construction of arc crust beneath Petit St. Vincent. Petit St. Vincent xenoliths are dominated by calcic plagioclase, clinopyroxene and amphibole, and can be divided into two main categories, igneous and meta-igneous. Igneous xenoliths typically have cumulate textures; meta-igneous xenoliths range texturally from those that preserve vestiges of primary magmatic fabrics to intensely deformed varieties characterised by grain-size reduction and foliation development. Meta-igneous xenoliths also contain the most calcic plagioclase (An98-100)

First evidence of Renlandian (c. 950–940 Ma) orogeny in mainland Scotland:Implications for the status of the Moine Supergroup and circum-North Atlantic correlations

Central problems in the interpretation of the Neoproterozoic geology of the North Atlantic region arise from uncertainties in the ages of, and tectonic drivers for, Tonian orogenic events recorded in eastern Laurentia and northern Baltica. The identification and interpretation of these events is often problematic because most rock units that record Tonian orogenesis were strongly reworked at amphibolite facies during the Ordovician-Silurian Caledonian orogeny. Lu-Hf and Sm-Nd geochronology and metamorphic modelling carried out on large (>1 cm) garnets from the Meadie Pelite in the Moine Nappe of the northern Scottish Caledonides indicate prograde metamorphism between 950 and 940 Ma at pressures of 6–7 kbar and temperatures of 600 °C. This represents the first evidence for c. 950 Ma Tonian (Renlandian) metamorphism in mainland Scotland and significantly extends its geographic extent along the palaeo-Laurentian margin. The Meadie Pelite is believed to be part of the Morar Group within the Moine Supergroup. If this is correct: 1) the Morar Group was deposited between 980 ± 4 Ma (age of the youngest detrital zircon; Peters, 2001, youngest published zircon date is 947 ± 189 (Friend et al., 2003)) and c. 950 Ma (age of regional metamorphism reported here), 2) an orogenic unconformity must separate the Morar Group from the 883 ± 35 Ma (Cawood et al., 2004) Glenfinnan and Loch Eil groups, and 3) the term ‘Moine Supergroup’ may no longer be appropriate. The Morar Group is broadly correlative with similar aged metasedimentary successions in Shetland, East Greenland, Svalbard, Ellesmere Island and northern Baltica. All these successions were deposited after c. 1030 Ma, contain detritus from the Grenville orogen, and were later deformed and metamorphosed at 950–910 Ma during accretionary Renlandian orogenesis along an active plate margin developed around this part of Rodinia