10 research outputs found
Novel Thermal Decarbonylative Dimerization of 1,2,3,4,5,6-Hexahydrobenzo[1,2;4,5]dicyclobutene-3,6-dione
No full text2-[Tris(pyridin-2-yl)methyl]pyridinium trans-bis(acetonitrile)tetrachloridoruthenate(III) acetonitrile monosolvate
No full textThe asymmetric unit of the title compound, [(C5H4N)3C(C5H5N)][RuCl4(CH3CN)2]·CH3CN, contains one 2-[tris(pyridin-2-yl)methyl]pyridinium cation, one trans-bis(acetonitrile)tetrachloridoruthenate(III) anion and one acetonitrile solvent molecule. The RuIII ion is coordinated by four Cl− anions in the equatorial plane and by two acetonitrile ligands in the axial positions, forming a distorted octahedral geometry. The cation, the monoprotonated species of tetrakis(pyridin-2-yl)methane, forms an intramolecular N—H...N hydrogen bond between the pyridinium ring and one of the pyridine rings. The complex anions are linked to each other via C—H...Cl hydrogen bonds, forming an undulating sheet parallel to the ac plane. A C—H...N hydrogen bond between the cation and the anion is also observed. The solvate acetonitrile molecule forms C—H...N and C—H...Cl hydrogen bonds, respectively, with the cation and the anion
Remarkable Heteroatom Dependence of the Spin Multiplicity in the Ground State of 9,9‘-( m
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Synthesis and Properties of a 1,3-Thiazole Extended p-Terphenoquinone. A New sp2 Nitrogen Atom-Containing Terquinone Derivative
No full textInduced circular dichroism spectra of 2-(2,4,6-cycloheptatrien-1-ylidene)-4-cyclopentene-1,3-dione included in?-cyclodextrin
No full textEndotoxin adsorption: Direct hemoperfusion with the polymyxin B-immobilized fiber column (PMX)
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