Structural transformations and disordering in zirconolite (CaZrTi2O7) at high pressure

There is interest in identifying novel materials for use in radioactive waste applications and studying their behavior under high pressure conditions. The mineral zirconolite (CaZrTi2O7) exists naturally in trace amounts in diamond-bearing deep-seated metamorphic/igneous environments, and it is also identified as a potential ceramic phase for radionuclide sequestration. However, it has been shown to undergo radiation-induced metamictization resulting in amorphous forms. In this study we probed the high pressure structural properties of this pyrochlore-like structure to study its phase transformations and possible amorphization behavior. Combined synchrotron X-ray diffraction and Raman spectroscopy studies reveal a series of high pressure phase transformations. Starting from the ambient pressure monoclinic structure, an intermediate phase with P21/m symmetry is produced above 15.6 GPa via a first order transformation resulting in a wide coexistence range. Upon compression to above 56 GPa a disordered metastable phase III with a cotunnite-related structure appears that is recoverable to ambient conditions. We examine the similarity between the zirconolite behavior and the structural evolution of analogous pyrochlore systems under pressure.<br/

Unravelling the Potamonautes lirrangensis (Rathbun, 1904) species complex (Potamoidea: Potamonautidae), with the description of two new species

The taxonomic status of the widely distributed freshwater crab Potamonautes lirrangensis (Rathbun, 1904) sensu lato is revised because morphological and molecular evidence indicates that this taxon is a complex comprising more than one species. Four taxa are now recognized: Potamonautes lirrangensis (Rathbun, 1904) s. str. and P. kisangani sp. nov. from the Middle Congo River in Central Africa, P. amosae sp. nov. from the drainages of Lakes Kivu and Tanganyika, and P. orbitospinus (Cunnington, 1907) from Lake Malawi which had been previously synonymised with P. lirrangensis s. lat. Diagnoses, illustrations and distribution maps are provided for each of these taxa and they are compared to similar species from Central and Southern Africa

Reply to comment on the paper by Davies et al. “Resolving MISS conceptions and misconceptions: A geological approach to sedimentary surface textures generated by microbial and abiotic processes”

We thank Noffke (2017) for her comment and for providing an opportunity to clarify our classification of “sedimentary surface textures”. We accord great credit to Dr. Noffke and other dedicated researchers whose detailed work has brought microbially induced sedimentary structures (MISS) to the widespread attention of geoscientists. However, we stand by our assertion that attributing structures observed in practical field and laboratory studies to processes of formation is much more problematic than Noffke (2017) indicates. Indeed, points in the Comment confirm the need for a classification system that categorises the degree of certainty attributed to a given interpretation. We stress that our paper was not designed as a critique of previous studies of MISS but rather was designed to encourage a reasonable assessment of uncertainty in assigning sedimentary surface textures to physical processes or to MISS

Resolving MISS conceptions and misconceptions: A geological approach to sedimentary surface textures generated by microbial and abiotic processes

The rock record contains a rich variety of sedimentary surface textures on siliciclastic sandstone, siltstone and mudstone bedding planes. In recent years, an increasing number of these textures have been attributed to surficial microbial mats at the time of deposition, resulting in their classification as microbially induced sedimentary structures, or MISS. Research into MISS has developed at a rapid rate, resulting in a number of misconceptions in the literature. Here, we attempt to rectify these MISS misunderstandings. The first part of this paper surveys the stratigraphic and environmental range of reported MISS, revealing that contrary to popular belief there are more reported MISS-bearing rock units of Phanerozoic than Precambrian age. Furthermore, MISS exhibit a pan-environmental and almost continuous record since the Archean. Claims for the stratigraphic restriction of MISS to intervals prior to the evolution of grazing organisms or after mass extinction events, as well as claims for the environmental restriction of MISS, appear to result from sampling bias. In the second part of the paper we suggest that raised awareness of MISS has come at the cost of a decreasing appreciation of abiotic processes that may create morphologically similar features. By introducing the umbrella term ‘sedimentary surface textures’, of which MISS are one subset, we suggest a practical methodology for classifying such structures in the geological record. We illustrate how elucidating the formative mechanisms of ancient sedimentary surface textures usually requires consideration of a suite of sedimentological evidence from surrounding strata. Resultant interpretations, microbial or non-microbial, should be couched within a reasonable degree of uncertainty. This approach recognizes that morphological similarity alone does not constitute scientific proof of a common origin, and reinstates a passive descriptive terminology for sedimentary surface textures that cannot be achieved with the current MISS lexicon. It is hoped that this new terminology will reduce the number of overly sensational and misleading claims of MISS occurrence, and permit the means to practically separate initial observation from interpretation. Furthermore, this methodology offers a scientific approach that appreciates the low likelihood of conclusively identifying microbial structures from visual appearance alone, informing the search for true MISS in Earth's geological record and potentially on other planetary bodies such as Mars

X-Ray Flashes in Recurrent Novae: M31N 2008-12a and the Implications of the Swift Non-detection

Models of nova outbursts suggest that an X-ray flash should occur just after hydrogen ignition. However, this X-ray flash has never been observationally confirmed. We present four theoretical light curves of the X-ray flash for two very massive white dwarfs (WDs) of 1.380 and 1.385 M_sun and for two recurrence periods of 0.5 and 1 years. The duration of the X-ray flash is shorter for a more massive WD and for a longer recurrence period. The shortest duration of 14 hours (0.6 days) among the four cases is obtained for the 1.385 M_sun WD with one year recurrence period. In general, a nova explosion is relatively weak for a very short recurrence period, which results in a rather slow evolution toward the optical peak. This slow timescale and the predictability of very short recurrence period novae give us a chance to observe X-ray flashes of recurrent novae. In this context, we report the first attempt, using the Swift observatory, to detect an X-ray flash of the recurrent nova M31N 2008-12a (0.5 or 1 year recurrence period), which resulted in the non-detection of X-ray emission during the period of 8 days before the optical detection. We discuss the impact of these observations on nova outburst theory. The X-ray flash is one of the last frontiers of nova studies and its detection is essentially important to understand the pre-optical-maximum phase. We encourage further observations.Comment: 12 pages, including 9 figures and 3 tables. To appear in the Astrophysical Journa

Englacial architecture and age-depth constraints across the West Antarctic Ice Sheet

he englacial stratigraphic architecture of internal reflection horizons (IRHs) as imaged by ice‐penetrating radar (IPR) across ice sheets reflects the cumulative effects of surface mass balance, basal melt, and ice flow. IRHs, considered isochrones, have typically been traced in interior, slow‐flowing regions. Here, we identify three distinctive IRHs spanning the Institute and Möller catchments that cover 50% of West Antarctica's Weddell Sea Sector and are characterized by a complex system of ice stream tributaries. We place age constraints on IRHs through their intersections with previous geophysical surveys tied to Byrd Ice Core and by age‐depth modeling. We further show where the oldest ice likely exists within the region and that Holocene ice‐dynamic changes were limited to the catchment's lower reaches. The traced IRHs from this study have clear potential to nucleate a wider continental‐scale IRH database for validating ice sheet models

The American English version of the Juvenile Arthritis Multidimensional Assessment Report (JAMAR)

The Juvenile Arthritis Multidimensional Assessment Report (JAMAR) is a new parent/patient-reported outcome measure that enables a thorough assessment of the disease status in children with juvenile idiopathic arthritis (JIA). We report the results of the cross-cultural adaptation and validation of the parent and patient versions of the JAMAR in the American English language. The reading comprehension of the questionnaire was tested in 10 JIA parents and patients. Each participating centre was asked to collect demographic, clinical data and the JAMAR in 100 consecutive JIA patients or all consecutive patients seen in a 6-month period and to administer the JAMAR to 100 healthy children and their parents. The statistical validation phase explored descriptive statistics and the psychometric issues of the JAMAR: the 3 Likert assumptions, floor/ceiling effects, internal consistency, Cronbach\u2019s alpha, interscale correlations, test\u2013retest reliability, and construct validity (convergent and discriminant validity). A total of 315 JIA patients (5.1% systemic, 31.1% oligoarticular, 34% RF negative polyarthritis, 29.8% other categories) and 98 healthy children, were enrolled in three centres. The JAMAR components discriminated well healthy subjects from JIA patients. All JAMAR components revealed good psychometric performances. In conclusion, the American English version of the JAMAR is a valid tool for the assessment of children with JIA and is suitable for use both in routine clinical practice and clinical research