Theory of double-resonant Raman spectra in graphene: intensity and line shape of defect-induced and two-phonon bands

We calculate the double resonant (DR) Raman spectrum of graphene, and determine the lines associated to both phonon-defect processes, and two-phonons ones. Phonon and electronic dispersions reproduce calculations based on density functional theory corrected with GW. Electron-light, -phonon, and -defect scattering matrix elements and the electronic linewidth are explicitly calculated. Defect-induced processes are simulated by considering different kind of idealized defects. For an excitation energy of $\epsilon_L=2.4$ eV, the agreement with measurements is very good and calculations reproduce: the relative intensities among phonon-defect or among two-phonon lines; the measured small widths of the D, $D'$, 2D and $2D'$ lines; the line shapes; the presence of small intensity lines in the 1800, 2000 cm$^{-1}$ range. We determine how the spectra depend on the excitation energy, on the light polarization, on the electronic linewidth, on the kind of defects and on their concentration. According to the present findings, the intensity ratio between the $2D'$ and 2D lines can be used to determine experimentally the electronic linewidth. The intensity ratio between the $D$ and $D'$ lines depends on the kind of model defect, suggesting that this ratio could possibly be used to identify the kind of defects present in actual samples. Charged impurities outside the graphene plane provide an almost undetectable contribution to the Raman signal

Economic Geology Models 1. Geochemical Exploration and Metallogenic Studies, Northern Chile

Research was initiated in 1998 on geo-chemical methods of exploration for copper porphyry deposits buried under thick, lithified piedmont gravel cover in the Atacama Desert, Chile. Early data suggest that mineralized, saline groundwater has been episodically forced up through fracture zones to the surface during earthquakes, creating geochemical anomalies above ore deposits. Follow-up research supported by the Canadian Mining Industry Research Organization (CAMIRO) examined the composition of both groundwater and surface anomalies, confirming a link between the two. Further work suggests that the geo-chemical anomalies are the surface expression of a process common to the metallogenic evolution of many deposits. Porphyry intrusion and hypo-gene mineralization are controlled by faults, and are followed by supergene enrichment in a semi-arid climate. After burial by Miocene gravels, the climate changed to hyper-arid; estimates of the onset of hyperaridity vary from mid-Miocene (11–14 Ma) to Pliocene (~3–5 Ma). Since then, saline dewatering of the basement along long-lived faults has converted the original super-gene copper oxide assemblage, formed in equilibrium with meteoric water and lacking atacamite, to one containing atacamite [Cu2Cl(OH)3], the copper mineral especially associated with northern Chile. This interpretation is supported by studies showing that the salinity of fluid inclusions in atacamite is similar to that of local groundwater and that atacamite is considerably younger than the co-existing supergene alteration. SOMMAIRE La recherche décrite ici et initiée en 1998 visait à mettre au point des méth-odes d'exploration de gisements de porphyres cuprifères enfouis sous d'épaisses couches lithifiées de graviers dans le désert d'Atacama au Chili. Des données préliminaires indiquent que des eaux souterraines salines minéralisées ont été poussées épisodiquement jusqu'à la surface, à travers des zones de fractures, à l'occasion de séismes, créant ainsi des anomalies au-dessus de gisements minéraux. Une recherche subséquente appuyée par la Canadian Mining Industry Research Organization (CAMIRO) qui a porté sur la composition de l'eau souterraine et des anomalies de surface, a permis de confirmer l'existence d'un lien entre les deux. Les résultats de travaux subséquents permettent de croire que ces anomalies géochimiques sont l'expression en surface d'un processus commun à l'évolution métallogénique de nombreux gisements. L'intrusion porphyrique et la minéralisation hypogène sont tributaires de failles, auxquelles s'est ensuite ajouté un enrichissement supergène sous climat semi-aride. Après l'enfouissement au Miocène par des graviers, le climat est devenu hyper-aride; selon les estimations le climat serait devenu hyperaride entre le Miocène moyen (11-14 Ma) et le Pliocène (~3-5 Ma). Depuis, l'assèchement des eaux salines du socle le long de failles persistantes a entraîné une conversion de l'assemblage original d'oxydes de cuivre supergène - lequel s'était formé en état d'équilibre en milieu d'eau météorique et qui était dépourvu d'atacamite - en un assemblage contenant de l'atacamite [Cu2Cl(OH)3], ce minéral de cuivre typique du Chili du nord. Cette interprétation est corroboré par des études montrant que la salinité des inclusions fluides dans l'atacamite est semblable à celle de l'eau souterraine locale et que l'atacamite est significativement plus jeune que l'altération supergène coexistante

GSH23.0-0.7+117, a neutral hydrogen shell in the inner Galaxy

GSH23.0-0.7+117 is a well-defined neutral hydrogen shell discovered in the VLA Galactic Plane Survey (VGPS). Only the blueshifted side of the shell was detected. The expansion velocity and systemic velocity were determined through the systematic behavior of the HI emission with velocity. The center of the shell is at (l,b,v)=(23.05,-0.77,+117 km/s). The angular radius of the shell is 6.8', or 15 pc at a distance of 7.8 kpc. The HI mass divided by the volume of the half-shell implies an average density n_H = 11 +/- 4 cm^{-3} for the medium in which the shell expanded. The estimated age of GSH23.0-0.7+117 is 1 Myr, with an upper limit of 2 Myr. The modest expansion energy of 2 * 10^{48} erg can be provided by the stellar wind of a single O4 to O8 star over the age of the shell. The 3 sigma upper limit to the 1.4 GHz continuum flux density (S_{1.4} < 248 mJy) is used to derive an upper limit to the Lyman continuum luminosity generated inside the shell. This upper limit implies a maximum of one O9 star (O8 to O9.5 taking into account the error in the distance) inside the HI shell, unless most of the incident ionizing flux leaks through the HI shell. To allow this, the shell should be fragmented on scales smaller than the beam (2.3 pc). If the stellar wind bubble is not adiabatic, or the bubble has burst (as suggested by the HI channel maps), agreement between the energy and ionization requirements is even less likely. The limit set by the non-detection in the continuum provides a significant challenge for the interpretation of GSH23.0-0.7+117 as a stellar wind bubble. A similar analysis may be applicable to other Galactic HI shells that have not been detected in the continuum.Comment: 18 pages, 6 figures. Figures 1 and 4 separately in GIF format. Accepted for publication in Astrophysical Journa

The VLA Galactic Plane Survey

The VLA Galactic Plane Survey (VGPS) is a survey of HI and 21-cm continuum emission in the Galactic plane between longitude 18 degrees 67 degr. with latitude coverage from |b| < 1.3 degr. to |b| < 2.3 degr. The survey area was observed with the Very Large Array (VLA) in 990 pointings. Short-spacing information for the HI line emission was obtained by additional observations with the Green Bank Telescope (GBT). HI spectral line images are presented with a resolution of 1 arcmin x 1 arcmin x 1.56 km/s (FWHM) and rms noise of 2 K per 0.824 km/s channel. Continuum images made from channels without HI line emission have 1 arcmin (FWHM) resolution. VGPS images are compared with images from the Canadian Galactic Plane Survey (CGPS) and the Southern Galactic Plane Survey (SGPS). In general, the agreement between these surveys is impressive, considering the differences in instrumentation and image processing techniques used for each survey. The differences between VGPS and CGPS images are small, < 6 K (rms) in channels where the mean HI brightness temperature in the field exceeds 80 K. A similar degree of consistency is found between the VGPS and SGPS. The agreement we find between arcminute resolution surveys of the Galactic plane is a crucial step towards combining these surveys into a single uniform dataset which covers 90% of the Galactic disk: the International Galactic Plane Survey (IGPS). The VGPS data will be made available on the World Wide Web through the Canadian Astronomy Data Centre (CADC).Comment: Accepted for publication in The Astronomical Journal. 41 pages, 13 figures. For information on data release, colour images etc. see http://www.ras.ucalgary.ca/VGP

MHD Turbulence as a Foreground for CMB Studies

Measurements of intensity and polarization of diffuse Galactic synchrotron emission as well as starlight polarization reveal power law spectra of fluctuations. We show that these fluctuations can arise from magnetohydrodynamic (MHD) turbulence in the Galactic disk and halo. To do so we take into account the converging geometry of lines of sight for the observations when the observer is within the turbulent volume. Assuming that the intensity of turbulence changes along the line of sight, we get a reasonable fit to the observed synchrotron data. As for the spectra of polarized starlight we get a good fit to the observations taking into account the fact that the observational sample is biased toward nearby stars.Comment: 10 pages, 6 figures, Astrophyscal J., submitte

Canopy nitrogen, carbon assimilation, and albedo in temperate and boreal forests: Functional relations and potential climate feedbacks

The availability of nitrogen represents a key constraint on carbon cycling in terrestrial ecosystems, and it is largely in this capacity that the role of N in the Earth\u27s climate system has been considered. Despite this, few studies have included continuous variation in plant N status as a driver of broad-scale carbon cycle analyses. This is partly because of uncertainties in how leaf-level physiological relationships scale to whole ecosystems and because methods for regional to continental detection of plant N concentrations have yet to be developed. Here, we show that ecosystem CO2 uptake capacity in temperate and boreal forests scales directly with whole-canopy N concentrations, mirroring a leaf-level trend that has been observed for woody plants worldwide. We further show that both CO2 uptake capacity and canopy N concentration are strongly and positively correlated with shortwave surface albedo. These results suggest that N plays an additional, and overlooked, role in the climate system via its influence on vegetation reflectivity and shortwave surface energy exchange. We also demonstrate that much of the spatial variation in canopy N can be detected by using broad-band satellite sensors, offering a means through which these findings can be applied toward improved application of coupled carbon cycle–climate models

Optical Phonons in Carbon Nanotubes: Kohn Anomalies, Peierls Distortions and Dynamic Effects

We present a detailed study of the vibrational properties of Single Wall Carbon Nanotubes (SWNTs). The phonon dispersions of SWNTs are strongly shaped by the effects of electron-phonon coupling. We analyze the separate contributions of curvature and confinement. Confinement plays a major role in modifying SWNT phonons and is often more relevant than curvature. Due to their one-dimensional character, metallic tubes are expected to undergo Peierls distortions (PD) at T=0K. At finite temperature, PD are no longer present, but phonons with atomic displacements similar to those of the PD are affected by strong Kohn anomalies (KA). We investigate by Density Functional Theory (DFT) KA and PD in metallic SWNTs with diameters up to 3 nm, in the electronic temperature range from 4K to 3000 K. We then derive a set of simple formulas accounting for all the DFT results. Finally, we prove that the static approach, commonly used for the evaluation of phonon frequencies in solids, fails because of the SWNTs reduced dimensionality. The correct description of KA in metallic SWNTs can be obtained only by using a dynamical approach, beyond the adiabatic Born-Oppenheimer approximation, by taking into account non-adiabatic contributions. Dynamic effects induce significant changes in the occurrence and shape of Kohn anomalies. We show that the SWNT Raman G peak can only be interpreted considering the combined dynamic, curvature and confinement effects. We assign the G+ and G- peaks of metallic SWNTs to TO (circumferential) and LO (axial) modes, respectively, the opposite of semiconducting SWNTs.Comment: 24 pages, 21 figures, submitted to Phys. Rev.

Wavelet-based bracketing, time–frequency beta burst detection: new insights in Parkinson's disease

Studies have shown that beta band activity is not tonically elevated but comprises exaggerated phasic bursts of varying durations and magnitudes, for Parkinson’s disease (PD) patients. Current methods for detecting beta bursts target a single frequency peak in beta band, potentially ignoring bursts in the wider beta band. In this study, we propose a new robust framework for beta burst identification across wide frequency ranges. Chronic local field potential at-rest recordings were obtained from seven PD patients implanted with Medtronic SenSight™ deep brain stimulation (DBS) electrodes. The proposed method uses wavelet decomposition to compute the time–frequency spectrum and identifies bursts spanning multiple frequency bins by thresholding, offering an additional burst measure, ∆f, that captures the width of a burst in the frequency domain. Analysis included calculating burst duration, magnitude, and ∆f and evaluating the distribution and likelihood of bursts between the low beta (13–20 Hz) and high beta (21–35 Hz). Finally, the results of the analysis were correlated to motor impairment (MDS-UPDRS III) med off scores. We found that low beta bursts with longer durations and larger width in the frequency domain (∆f) were positively correlated, while high beta bursts with longer durations and larger ∆f were negatively correlated with motor impairment. The proposed method, finding clear differences between bursting behavior in high and low beta bands, has clearly demonstrated the importance of considering wide frequency bands for beta burst behavior with implications for closed-loop DBS paradigms

Reply to Fisher: Nitrogen–albedo relationship in forests remains robust and thought-provoking

Fisher’s primary concerns have overlooked important methodological aspects of our study, whereas other concerns are consistent with our own presentation of the findings. We did not exclude photosynthetically active radiation (PAR) wavelengths, as Fisher states

Increased Finger-Tapping Related Cerebellar Activation in Cervical Dystonia, Enhanced by Transcranial Stimulation: An Indicator of Compensation?

Background: Cervical dystonia is a movement disorder causing abnormal postures and movements of the head. While the exact pathophysiology of cervical dystonia has not yet been fully elucidated, a growing body of evidence points to the cerebellum as an important node.Methods: Here, we examined the impact of cerebellar interference by transcranial magnetic stimulation on finger-tapping related brain activation and neurophysiological measures of cortical excitability and inhibition in cervical dystonia and controls. Bilateral continuous theta-burst stimulation was used to modulate cerebellar cortical excitability in 16 patients and matched healthy controls. In a functional magnetic resonance imaging arm, data were acquired during simple finger tapping before and after cerebellar stimulation. In a neurophysiological arm, assessment comprised motor-evoked potentials amplitude and cortical silent period duration. Theta-burst stimulation over the dorsal premotor cortex and sham stimulation (neurophysiological arm only) served as control conditions.Results: At baseline, finger tapping was associated with increased activation in the ipsilateral cerebellum in patients compared to controls. Following cerebellar theta-burst stimulation, this pattern was even more pronounced, along with an additional movement-related activation in the contralateral somatosensory region and angular gyrus. Baseline motor-evoked potential amplitudes were higher and cortical silent period duration shorter in patients compared to controls. After cerebellar theta-burst stimulation, cortical silent period duration increased significantly in dystonia patients.Conclusion: We conclude that in cervical dystonia, finger movements—though clinically non-dystonic—are associated with increased activation of the lateral cerebellum, possibly pointing to general motor disorganization, which remains subclinical in most body regions. Enhancement of this activation together with an increase of silent period duration by cerebellar continuous theta-burst stimulation may indicate predominant disinhibitory effects on Purkinje cells, eventually resulting in an inhibition of cerebello-thalamocortical circuits