207 research outputs found
Optical Properties of (SrMnO3)n/(LaMnO3)2n superlattices: an insulator-to-metal transition observed in the absence of disorder
We measure the optical conductivity of (SrMnO3)n/(LaMnO3)2n superlattices
(SL) for n=1,3,5, and 8 and 10 < T < 400 K. Data show a T-dependent insulator
to metal transition (IMT) for n \leq 3, driven by the softening of a polaronic
mid-infrared band. At n = 5 that softening is incomplete, while at the
largest-period n=8 compound the MIR band is independent of T and the SL remains
insulating. One can thus first observe the IMT in a manganite system in the
absence of the disorder due to chemical doping. Unsuccessful reconstruction of
the SL optical properties from those of the original bulk materials suggests
that (SrMnO3)n/(LaMnO3)2n heterostructures give rise to a novel electronic
state.Comment: Published Online in Nano Letters, November 8, 2010;
http://pubs.acs.org/doi/abs/10.1021/nl1022628; 5 pages, 3 figure
Effect of Mn substitution by Ga on the optical properties of a metallic manganite
In a metallic manganite like La(2/3)Sr(1/3)MnO(3), the substitution of Mn(+3)
by Ga(+3) dilutes the ferromagnetic order and locally cancels the Jahn-Teller
distortion, without heavily affecting the crystal structure. One can thus
follow the changes in the charge dynamics induced by Ga, until the
ferro-metallic manganite is turned into an insulator. Here this phenomenon is
studied in detail through the infrared reflectivity of five samples of
La(2/3)Sr(1/3)Mn(1-x)Ga(x)O(3), with x increasing from 0 to 0.30 and for 50 < T
< 320 K. A simple model which links the measured optical parameters to the
magnetization M(x, T) well describes the behavior of the plasma frequency, the
scattering rate, and the mid-infrared absorption along the metal-to-insulator
transition.Comment: 8 pages including 7 figure
Charge density waves enhance the electronic noise of manganites
The transport and noise properties of Pr_{0.7}Ca_{0.3}MnO_{3} epitaxial thin
films in the temperature range from room temperature to 160 K are reported. It
is shown that both the broadband 1/f noise properties and the dependence of
resistance on electric field are consistent with the idea of a collective
electrical transport, as in the classical model of sliding charge density
waves. On the other hand, the observations cannot be reconciled with standard
models of charge ordering and charge melting. Methodologically, it is proposed
to consider noise-spectra analysis as a unique tool for the identification of
the transport mechanism in such highly correlated systems. On the basis of the
results, the electrical transport is envisaged as one of the most effective
ways to understand the nature of the insulating, charge-modulated ground states
in manganites.Comment: 6 two-column pages, 5 figure
Critical currents of MgB2 thin films depositedin situby sputtering
We have measured the temperature and magnetic field dependencies of the critical current density J(c)(H,T) in MgB2 thin films, in situ deposited by sputtering. Three-dimensional point like normal core pinning was evidenced by measurements of the magnetic dependence of the pinning forces independently from the superconducting and structural quality of the investigated films. The analysis of the experimental data in terms of the collective pinning model has pointed out the presence of a crossover magnetic field from a single vortex to a small vortex bundle pinning regime. A DeltaT(c) pinning mechanism, i.e., a pinning associated with spatial fluctuations of the transition temperature, has been evidenced by the temperature dependence of this crossover field, in agreement with previous observations performed on MgB2 bulk materials
Multiple double-exchange mechanism by Mn-doping in manganite compounds
Double-exchange mechanisms in REAEMnO manganites (where
RE is a trivalent rare-earth ion and AE is a divalent alkali-earth ion) relies
on the strong exchange interaction between two Mn and Mn ions
through interfiling oxygen 2p states. Nevertheless, the role of RE and AE ions
has ever been considered "silent" with respect to the DE conducting mechanisms.
Here we show that a new path for DE-mechanism is indeed possible by partially
replacing the RE-AE elements by Mn-ions, in La-deficient
LaMnO thin films. X-ray absorption spectroscopy demonstrated
the relevant presence of Mn ions, which is unambiguously proved to be
substituted at La-site by Resonant Inelastic X-ray Scattering. Mn is
proved to be directly correlated to the enhanced magneto-transport properties
because of an additional hopping mechanism trough interfiling Mn-ions,
theoretically confirmed by calculations within the effective single band model.
The very idea to use Mn both as a doping element and an ions
electronically involved in the conduction mechanism, has never been foreseen,
revealing a new phenomena in transport properties of manganites. More
important, such a strategy might be also pursed in other strongly correlated
materials.Comment: 6 pages, 5 figure
Evolution of magnetic phases and orbital occupation in (SrMnO3)n/(LaMnO3)2n superlattices
The magnetic and electronic modifications induced at the interfaces in
(SrMnO)/(LaMnO) superlattices have been investigated
by linear and circular magnetic dichroism in the Mn L x-ray absorption
spectra. Together with theoretical calculations, our data demonstrate that the
charge redistribution across interfaces favors in-plane ferromagnetic (FM)
order and orbital occupation, in agreement with the
average strain. Far from interfaces, inside LaMnO, electron localization
and local strain favor antiferromagnetism (AFM) and
orbital occupation. For the high density of interfacial planes ultimately
leads to dominant FM order forcing the residual AFM phase to be in-plane too,
while for the FM layers are separated by AFM regions having
out-of-plane spin orientation.Comment: accepted for publication as a Rapid Communication in Physical Review
W-F substitutions in apomyoglobin increase the local flexibility of the N-terminal region causing amyloid aggregation: A H/D exchange study.
Myoglobin is an α-helical globular protein containing two highly conserved tryptophanyl residues at positions 7 and 14 in the N-terminal region. The simultaneous substitution of the two residues impairs the productive folding of the protein making the polypeptide chain highly prone to aggregate forming amyloid fibrils at physiological pH and room temperature. The role played by tryptophanyl residues in driving the productive folding process was investigated by providing structural details at low resolution of compact intermediate of three mutated apomyoglobins, i.e., W7F, W14F and the amyloid forming mutant W7FW14F. In particular, we followed the hydrogen/deuterium exchange rate of protein segments using proteolysis with pepsin followed by mass spectrometry analysis. The results revealed significant differences in the N-terminal region, consisting in an alteration of the physico-chemical properties of the 7-11 segment for W7F and in an increase of local flexibility of the 12-29 segment for W14F. In the double trypthophanyl substituted mutant, these effects are additive and impair the formation of native-like contacts and favour inter-chain interactions leading to protein aggregation and amyloid formation at physiological pH
Twin digital short period seismic Array Experiment at Stromboli Volcano
Two small arrays composed by short period (1 Hz) digital seismic
stations, with an aperture of approximately 400 meters, were set up at
Stromboli volcano (one at semaforo Labronzo, the other at Ginostra-
Timpone del Fuoco) with the purpose of the spatial location of the high
frequency source of the explosion quakes.
About 75 explosion-quakes were recorded at both arrays, and
constitute the available data base.
We have planned to apply the zero-lag cross-correlation technique to
the whole data set in order to obtain back-azimuth and apparent
slowness of the coherent seismic phases. A preliminary analysis for
both arrays show that the predominant back-azimuth for the first phase
is oriented in the direction of , but not strictly coincident to, the crater
area. Moreover some back-scattered arrivals are quite evident in the
seismogram.INGV - Osservatorio VesuvianoUnpublishedope
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