Stereochemical properties of the OH molecule in combined electric and magnetic fields: analytic results

The stereochemical properties of the ultracold ground state OH molecule in the presence of electric and magnetic fields are currently of considerable interest. For example, relevant quantities such as molecular alignment and orientation, calculated numerically by using large basis sets, have lately appeared in the literature. In this work, based on our recent exact solution to an effective eight-dimensional matrix Hamiltonian for the molecular ground state, we present analytic expressions for the stereochemical properties of OH. Our results require the solution of algebraic equations only, agree well with the aforementioned fully numerical calculations, provide compact expressions for simple field geometries, allow ready access to relatively unexplored parameter space, and yield straightforwardly higher moments of the molecular axis distribution.Comment: 8 pages, 9 figure

Power in the Multinational Corporation in Industry Equilibrium

Recent theories of the multinational corporation introduce the property rights model of the firm and examine whether to integrate our outsource firm activities locally or to a foreign country. This paper focus instead on the internal organization of the multinational corporation by examining the power allocation between headquarters and subsidiaries. We provide a framework to analyse the interaction between the decision to serve the local market by exporting or FDI, market acces and the optimal mode of organization of the multinational corporation. We find that subsidiary managers are given most autonomy in their decision how to run the firm at intermediate levels of local competition. We then provide comparative statics for changes in fixed FDI entry costs and trade costs, information technology, the number of local competitors, and in the size of the local market

Equilibrium relationships for non-equilibrium chemical dependencies

In contrast to common opinion, it is shown that equilibrium constants determine the time-dependent behavior of particular ratios of concentrations for any system of reversible first-order reactions. Indeed, some special ratios actually coincide with the equilibrium constant at any moment in time. This is established for batch reactors, and similar relations hold for steady-state plug-flow reactors, replacing astronomic time by residence time. Such relationships can be termed time invariants of chemical kinetics

3D discrete element modeling of concrete: study of the rolling resistance effects on the macroscopic constitutive behavior

The Discrete Element Method (DEM) is appropriate for modeling granular materials [14] but also cohesive materials as concrete when submitted to a severe loading such an impact leading to fractures or fragmentation in the continuum [1, 5, 6, 8]. Contrarily to granular materials, the macroscopic constitutive behavior of a cohesive material is not directly linked to contact interactions between the rigid Discrete Elements (DE) and interaction laws are then defined between DE surrounding each DE. Spherical DE are used because the contact detection is easy to implement and the computation time is reduced in comparison with the use of 3D DE with a more complex shape. The element size is variable and the assembly is disordered to prevent preferential cleavage planes. The purpose of this paper is to highlight the influence of DE rotations on the macroscopic non-linear quasi-static behavior of concrete. Classically, the interactions between DE are modeled by spring-like interactions based on displacements and rotation velocities of DE are only controlled by tangential forces perpendicular to the line linking the two sphere centroids. The disadvantage of this modeling with only spring-like interactions based on displacements is that excessive rolling occurs under shear, therefore the macroscopic behavior of concrete is too brittle. To overcome this problem a non linear Moment Transfer Law (MTL) is introduced to add a rolling resistance to elements. This solution has no influence on the calculation cost and allows a more accurate macroscopic representation of concrete behavior. The identification process of material parameters is given and simulations of tests performed on concrete samples are shown

Test of the fluctuation theorem for stochastic entropy production in a nonequilibrium steady state

We derive a simple closed analytical expression for the total entropy production along a single stochastic trajectory of a Brownian particle diffusing on a periodic potential under an external constant force. By numerical simulations we compute the probability distribution functions of the entropy and satisfactorily test many of the predictions based on Seifert's integral fluctuation theorem. The results presented for this simple model clearly illustrate the practical features and implications derived from such a result of nonequilibrium statistical mechanics.Comment: Accepted in Phys. Rev.

A Discrete Geometric Optimal Control Framework for Systems with Symmetries

This paper studies the optimal motion control of mechanical systems through a discrete geometric approach. At the core of our formulation is a discrete Lagrange-d’Alembert- Pontryagin variational principle, from which are derived discrete equations of motion that serve as constraints in our optimization framework. We apply this discrete mechanical approach to holonomic systems with symmetries and, as a result, geometric structure and motion invariants are preserved. We illustrate our method by computing optimal trajectories for a simple model of an air vehicle flying through a digital terrain elevation map, and point out some of the numerical benefits that ensue