How Do They Know It Is a Parallelogram? Analysing Geometric Discourse at Van Hiele Level 3

In this article, we introduce Sfard\u27s discursive framework and use it to investigate prospective teachers\u27 geometric discourse in the context of quadrilaterals. In particular, we focus on describing and analysing two participants\u27 use of mathematical words and substantiation routines related to parallelograms and their properties at van Hiele level 3 thinking. Our findings suggest that a single van Hiele level of thinking encompasses a range of complexity of reasoning and differences in discourse and thus a deeper investigation of students\u27 mathematical thinking within assigned van Hiele levels is warranted

Synthesis of Some Organic Conductive Materials

The primary goal in conducting the experimental work involved in the formulating of this thesis was to synthesize some organic conducting compounds by utilizing the highly electronegative 7,7,8,8-tetracyanoquinodimethan complexed with some completely conjugated benzologs of the quinolizinium ion. The history is divided into three parts, the first part describing the electronic properties of organic conducting polymers, the second part dealing with anion-radical derivatives and complexes of 7,7,8,8-tetracyanoquinodimethan, the third part describing some benzologs of the quinolizinium ion. 1. Electronic Properties of Organic Conducting Polymers One of the most important problems of present-day chemistry is the creation of new substances and materials possessing a series of valuable properties. Particularly great prospects have been opened in the synthesis and study of organic compounds possessing extensively delocalized electrons because of the presence in them of highly conjugated double bonds or the formation of charge transfer complexes. Although in recent years the study of semi conductive properties of organic compounds has made much progress, most of the exact mechanisms involved in the electronic conducting processes are at the present time either not known at all or else poorly understood. Generally, the semi conductive polymers can be classified as follows: (a) covalent organic polymers, (b) charge-transfer complexes, (c) metal organic polymers, (d) H-bonded polymers, and (e) mixed polymers, for example, charge transfer complexes between covalent polymers and low molecular weight donor or acceptor molecules. The main efforts of synthetic chemists working in this field have been devoted to obtaining stable polymers of low resistance. As a working hypothesis, Pohl proposed the idea of eka- and rubi- conjugation. Rubi-conjugation was defined as a type of structure in which various molecular defects and quantum mechanical effects exist which produce a limited, or broken sequence of electronic delocalization. Such conjugation was to be avoided if strong electronic conduction was desired. In eka-conjugation, molecular defects were absent or suppressed, and full interlinking of the chain atom pi orbitals occurred. Long-range electron orbital delocalization was then possible

Awareness, interest, and preferences of primary care providers in using point-of-care cancer screening technology

Well-developed point-of-care (POC) cancer screening tools have the potential to provide better cancer care to patients in both developed and developing countries. However, new medical technology will not be adopted by medical providers unless it addresses a population’s existing needs and end-users’ preferences. The goals of our study were to assess primary care providers’ level of awareness, interest, and preferences in using POC cancer screening technology in their practice and to provide guidelines to biomedical engineers for future POC technology development. A total of 350 primary care providers completed a one-time self-administered online survey, which took approximately 10 minutes to complete. A $50 Amazon gift card was given as an honorarium for the first 100 respondents to encourage participation. The description of POC cancer screening technology was provided in the beginning of the survey to ensure all participants had a basic understanding of what constitutes POC technology. More than half of the participants (57%) stated that they heard of the term “POC technology” for the first time when they took the survey. However, almost all of the participants (97%) stated they were either “very interested” (68%) or “somewhat interested” (29%) in using POC cancer screening technology in their practice. Demographic characteristics such as the length of being in the practice of medicine, the percentage of patients on Medicaid, and the average number of patients per day were not shown to be associated with the level of interest in using POC. These data show that there is a great interest in POC cancer screening technology utilization among this population of primary care providers and vast room for future investigations to further understand the interest and preferences in using POC cancer technology in practice. Ensuring that the benefits of new technology outweigh the costs will maximize the likelihood it will be used by medical providers and patients

A randomized trial of selenium supplementation and risk of type-2 diabetes, as assessed by plasma adiponectin

Background: Evidence that selenium affects the risk of type-2 diabetes is conflicting, with observational studies and a few randomized trials showing both lower and higher risk linked to the level of selenium intake and status. We investigated the effect of selenium supplementation on the risk of type-2 diabetes in a population of relatively low selenium status as part of the UK PRECISE (PREvention of Cancer by Intervention with SElenium) pilot study. Plasma adiponectin concentration, a recognised independent predictor of type-2 diabetes risk and known to be correlated with circulating selenoprotein P, was the biomarker chosen. Methods: In a randomized, double-blind, placebo-controlled trial, five hundred and one elderly volunteers were randomly assigned to a six-month intervention with 100, 200 or 300 μg selenium/d as high-selenium or placebo yeast. Adiponectin concentration was measured by ELISA at baseline and after six months of treatment in 473 participants with one or both plasma samples available. Results: Mean (SD) plasma selenium concentration was 88.5 ng/g (19.1) at baseline and increased significantly in the selenium-treatment groups. In baseline cross-sectional analyses, the fully adjusted geometric mean of plasma adiponectin was 14% lower (95% CI, 0-27%) in the highest than in the lowest quartile of plasma selenium (P for linear trend = 0.04). In analyses across randomized groups, however, selenium supplementation had no effect on adiponectin levels after six months of treatment (P = 0.96). Conclusions: These findings are reassuring as they did not show a diabetogenic effect of a six-month supplementation with selenium in this sample of elderly individuals of relatively low selenium status

Red Noise in Anomalous X-ray Pulsar Timing Residuals

Anomalous X-ray Pulsars (AXPs), thought to be magnetars, exhibit poorly understood deviations from a simple spin-down called "timing noise". AXP timing noise has strong low-frequency components which pose significant challenges for quantification. We describe a procedure for extracting two quantities of interest, the intensity and power spectral index of timing noise. We apply this procedure to timing data from three sources: a monitoring campaign of five AXPs, observations of five young pulsars, and the stable rotator PSR B1937+21.Comment: submitted to the proceedings of the "40 Years of Pulsars" conferenc

Micro-abrasion of Y-TZP in tea

The object of this work is to investigate the micro-abrasion of Y-TZP in tea. This material is a candidate replacement veneer in dental restoration and to date there has been very little work carried out to investigate the wear behaviour in oral cavity conditions. Various additions such as milk and sugar, which affect the solution viscosity and pH, were assessed as part of this work and the results were compared to the performance of the material in aqueous conditions. Wear maps were generated showing the change in wear rate as a function of applied load, viscosity and exposure time

Multipartite Einstein-Podolsky-Rosen steering and genuine tripartite entanglement with optical networks

The Einstein-Podolsky-Rosen (EPR) paradox established a link between entanglement and nonlocality in quantum mechanics. EPR steering is the nonlocality associated with the EPR paradox and has traditionally only been investigated between two parties. Here, we present the first experimental observations of multipartite EPR steering, and of the genuine tripartite continuous variable entanglement of three mesoscopic optical systems. We explore different linear optics networks - each one with optimised asymmetries - that create multipartite steerable states containing different numbers of quantised optical modes (qumodes). By introducing asymmetric loss on a 7-qumode state, we characterize 8 regimes of directional steering, showing that N + 1 regimes exist for an N-qumode state. Further, we reveal the directional monogamy of steering, and experimentally demonstrate continuous variable one-sided semi device-independent quantum secret sharing. Our methods establish principles for the development of multiparty quantum communication protocols with asymmetric observers, and can be extended to qubits, whether photonic, atomic, superconducting, or otherwise.Comment: 7 pages, 4 figures. Comments are most welcome. Edited version to appear Jan 2015 in peer-reviewed journa

Some views on the construction of bio-tribo-corrosion maps for Ti in Hanks solution : Particle concentration and applied loads effects

Tribology of bio-implants is a major limiting issue in materials selection of the appropriate implant for the appropriate patient activity level [1]. For example, for wear of replacement hip joints, wear caused by the sliding action of the bearing surface of the femoral head against the counterface occurs in synovial fluid. Hence, the major challenge of materials scientists in replacement of such materials is to optimize the wear resistance, minimize any potential tribo-corrosion interaction and adverse biocompatibility effects caused by such interactions and reduce wherever possible any adsorption of wear debris into the surrounding tissue. In Tribology, and in Aqueous Corrosion, various mapping methodologies[1-7] have been developed to characterize the various interactions. The wear map developed by Lim and Ashby [2] classifies the wear regimes at ambient conditions in terms of applied load and velocity, illustrating significant temperature rises and attendant corrosion reactions as a function of the tribological variables. The Pourbaix diagram[8] considers various transitions in terms of potential and pH, therefore presenting corrosion regimes as a function of the driving force of the electrochemical reaction and the hydrogen ion concentration. In tribo-corrosion, there is an extensive recent literature combing the concepts of both approaches to construct tribo-corrosion maps [2-8]. Despite such work, there has been very little work carried out until very recently[9] on the construction of tribo-corrosion maps for application to bio-tribo-corrosion environments. This is despite the fact that such maps may have significant application in optimizing materials for specific patient activity/mass combinations, all of which are important in selection of the most appropriate material combination in total replacement joint procedures. In studies of wear of candidate hip joint materials, it has been observed that particle concentration of wear debris can have an adverse effect on loosening of the joint, leading to osteolysis and potential revision of the replacement joint material [10]. In such cases, it is important to identify the effects of wear debris on the tribo-corrosion mechanism [12]. Assessing the effects of such particle concentrations with load is also of significance as it will indicate what dependency, if any, particle concentration has at various body masses as defined by variation of applied load. Hence, in this paper, the effect of applied load and abrasive concentration were assessed at a range of applied loads for Ti rotating against an inert Zirconia ball, in which abrasive particles of SiC were entrained in Hanks solution. The results were used to construct micro-abrasion-corrosion maps for application to biological environments. The significance of the bio-tribo-corrosion map in identifying mechanisms of wastage and the extent of synergy between the tribological and corrosion processes is addressed in this paper

Examining an Online Microbiology Game as an Effective Tool for Teaching the Scientific Process

This study investigates the effectiveness of the online Flash game Disease Defenders in producing knowledge gains for concepts related to the scientific process. Disease Defenders was specifically designed to model how the scientific process is central to a variety of disciplines and science careers. An additional question relates to the game's ability to shift attitudes toward science. Middle school classes from grades six to eight were assigned to the experimental group (n = 489) or control group (n = 367) and asked to participate in a three-session intervention. The sessions involved completing a pretest, a game play session, and taking a post-test. Students in the experimental group played Disease Defenders while students in the control group played an alternative science game. Results showed a significant increase in mean science knowledge scores for all grades in the experimental group, with sixth grade and seventh grade students gaining more knowledge than eighth grade students. Additionally, results showed a significant positive change in science attitudes only among sixth graders, who also rated their satisfaction with the game more favorably than students in higher grades. No differences in mean test scores were found between genders for science knowledge or science attitudes, suggesting that the game is equally effective for males and females