Testing Of A New Supercritical Orc Technology For Efficient Power Generation From Geothermal Low Temperature Resources

Recent international focus on the value of increasing renewable energy supply highlights the need for revaluating all alternatives, particularly those that are large and well-distributed. One such option is geothermal energy from hydrothermal low temperature resources. The most efficient and cost-effective way to exploit this type of reservoir is based on the use of binary cycles. Purpose of ENEL Research in this field is to develop and design an optimized and highly flexible binary cycle to be applied to the exploitation of water dominant geothermal resources acquired by ENEL worldwide and to study options for its integration with solar energy. Different Rankine cycles for geothermal resources at temperature levels between 120°C and 180°C have been extensively studied and optimized to maximize overall conversion efficiency and to minimize plant costs, in collaboration with Politecnico di Milano. This analysis allowed the assessment both of subcritical optimized cycles and supercritical innovative advanced cycles using different working fluids (e.g. hydrocarbons and refrigerants). Moreover the carried out studies showed that in a supercritical cycle the possibility to operate outside the fluid saturation curve during the heat adduction phase guarantees a greater power production (no pinch-point problems) and operational flexibility with respect to subcritical cycles (e.g. reduced performance decline due to external condition variability such as brine temperature and mass flow rate and environment air temperature). Based on the carried out theoretical analysis, the decision to demonstrate an advanced, high efficient binary cycle at the pilot scale was taken. A preliminary design of the main components for a 500 kWe prototypal-sized supercritical binary power plant was carried out in collaboration with Turboden and Politecnico di Milano. The plant was designed and realized by Turboden and was installed in the Enel experimental platform (Livorno, Italy) at December 2011. In the first part of 2012 the pilot plant was put in operation and characterized for different geo-fluid conditions (e.g. temperature and flow rate) and ambient conditions. The experimental tests carried out on the supercritical pilot plant validate the achieved theoretical results, taking special care to plant performance flexibility and main component design criteria. This paper will give an overview of the theoretical and experimental activities carried out in order to characterize the ORC supercritical technology

Digital design of medical replicas via desktop systems: shape evaluation of colon parts

In this paper, we aim at providing results concerning the application of desktop systems for rapid prototyping of medical replicas that involve complex shapes, as, for example, folds of a colon. Medical replicas may assist preoperative planning or tutoring in surgery to better understand the interaction among pathology and organs. Major goals of the paper concern with guiding the digital design workflow of the replicas and understanding their final performance, according to the requirements asked by the medics (shape accuracy, capability of seeing both inner and outer details, and support and possible interfacing with other organs). In particular, after the analysis of these requirements, we apply digital design for colon replicas, adopting two desktop systems. ,e experimental results confirm that the proposed preprocessing strategy is able to conduct to the manufacturing of colon replicas divided in self-supporting segments, minimizing the supports during printing. ,is allows also to reach an acceptable level of final quality, according to the request of having a 3D presurgery overview of the problems. ,ese replicas are compared through reverse engineering acquisitions made by a structured-light system, to assess the achieved shape and dimensional accuracy. Final results demonstrate that low-cost desktop systems, coupled with proper strategy of preprocessing, may have shape deviation in the range of ±1 mm, good for physical manipulations during medical diagnosis and explanation

Design of high gradient, high repetition rate damped C-band rf structures

The gamma beam system of the European Extreme Light Infrastructure–Nuclear Physics project foresees the use of a multibunch train colliding with a high intensity recirculated laser pulse. The linac energy booster is composed of 12 traveling wave C-band structures, 1.8 m long with a field phase advance per cell of 2π=3 and a repetition rate of 100 Hz. Because of the multibunch operation, the structures have been designed with a dipole higher order mode (HOM) damping system to avoid beam breakup (BBU). They are quasiconstant gradient structures with symmetric input couplers and a very effective damping of the HOMs in each cell based on silicon carbide (SiC) rf absorbers coupled to each cell through waveguides. An optimization of the electromagnetic and mechanical design has been done to simplify the fabrication and to reduce the cost of the structures. In the paper, after a review of the beam dynamics issues related to the BBU effects, we discuss the electromagnetic and thermomechanic design criteria of the structures. We also illustrate the criteria to compensate the beam loading and the rf measurements that show the effectiveness of the HOM damping

New materials for Li-ion batteries : synthesis and spectroscopic characterization of Li2(FeMnCo) SiO4 cathode materials

Improving cathode materials is mandatory for next-generation Li-ion batteries. Exploring polyanion compounds with high theoretical capacity such as the lithium metal orthosilicates, Li2MSiO4 is of great importance. In particular, mixed silicates represent an advancement with practical applications. Here we present results on a rapid solid state synthesis of mixed Li2(FeMnCo)SiO4 samples in a wide compositional range. The solid solution in the P21/n space group was found to be stable for high iron concentration or for a cobalt content up to about 0.3 atom per formula unit. Other compositions led to a mixture of polymorphs, namely Pmn21 and Pbn21. All the samples contained a variable amount of Fe3+ ions that was quantified by Mössbauer spectroscopy and confirmed by the TN values of the paramagnetic to antiferromagnetic transition. Preliminary characterization by cyclic voltammetry revealed the effect of Fe3+ on the electrochemical response. Further work is required to determine the impact of these electrode materials on lithium batteries

Climate change as main driver of centennial decline in river sediment transport across the Mediterranean region

The analysis of suspended sediment transport and of its variations over time is crucial for understanding environmental evolution and it is the key to future challenges caused by current global warming. The Mediterranean area is a hot spot for global changes, and the variation of precipitation amount and intensity will modify the environment of this region. In this work, we analyse the time series of suspended sediment transport of two rivers located in central Italy by using statistical and artificial intelligence techniques. Our study aims to re-analyze time series of suspended sediment transport, in order to demonstrate that climate change is responsible for the substantial decrease in the amount of sediment over the past century, in relation to the atmospheric teleconnections of the North Atlantic. Anthropic pressures like reforestation, land use change, and dam building have influenced the sediment transport capacity of rivers, causing a reduction of sediment concentration in water. These results are key factors to determine the future management of the Mediterranean areas, where the future scenarios predict a greater drop in yearly precipitation, and therefore a possible further decrease in the sediment transport capacity of the rivers, with major consequences for coastal and fluvial environments

The Speciality Index as invariant indicator in the BKL Mixmaster Dynamics

The speciality index, which has been mainly used in Numerical Relativity for studying gravitational waves phenomena as an indicator of the special or non-special Petrov type character of a spacetime, is applied here in the context of Mixmaster cosmology, using the Belinski-Khalatnikov-Lifshitz map. Possible applications for the associated chaotic dynamics are discussed

The loess deposits of Buca Dei Corvi section (Central Italy): Revisited

Loess deposits have been described in the past for the upper section of Buca Dei Corvi succession (Central Italy). In this paper the depositswere re-analysed to clarify the depositional environment and to attempt a paleoclimate reconstruction. Two radiocarbon dates on pedogenic carbonate constrain the ages to the Late Glacial, and are consistent with previous OSL dating of the top of the succession. The non-marine mollusc assemblage shows typical character of cold and dry climatic conditions, testified by strong oligotypical composition. Mineralogy and geochemistry of the sediments indicate the abundant presence of exotic quartz mineral which can be explained only by wind transport. Probably,wind transportwas also responsible of deposition of carbonatewhich then dissolved and re-precipitated producing pedogenic concretions. Stable isotopes (13C/12C and 18O/16O ratios) of the concretions are consistent with a climate drier than present conditions, with an environment characterized by sparse vegetation

Exploring the Relationship between River Discharge and Coastal Erosion: An Integrated Approach Applied to the Pisa Coastal Plain (Italy)

Coastal erosion coupled with human-induced pressure has severely affected the coastal areas of the Mediterranean region in the past and continues to do so with increasing intensity today. In this context, the Pisa coastal plain shows a long history of erosion, which started at the beginning of the nineteenth century. In this work, shoreline positions derived from historical maps as well as airborne and DGPS (Differential Global Positioning System) surveys were analyzed in a GIS (Geographic Information System) environment to identify the main changes that have occurred in the last 142 years. These analyses were compared with 100 years of discharge data measured at the S. Giovanni alla Vena gauge to identify a possible correlation between the two sets of information. Finally, Sentinel-2 and Landsat images were studied to identify the dispersion of sediments transported by the Arno River. In particular, we found a minimum of fluvial discharge in the years 1954, 1978, and 2012 corresponding to a peak of erosion, while the reduced erosion rate and the fluvial discharge increased in the years 1928–1944, 1954–1975, and after 2012. The qualitative anticorrelation between discharge and erosion is particularly true if we take into account flood events with a value of discharge greater than 700 m3/s, which are those able to transport suspended sand. The remote sensing analyses of Sentinel-2 images acquired during the floods of 6 February 2019 and 3 December 2019, under the most typical wind and sea state conditions for this area (wind coming from SW and storms coming from W/SW and SW) show that during these events a consistent amount of sediment was transported by the river. However, the majority of these sediments are not deposited along the coastline but are dispersed offshore. Grain-size analyses on the transported sediment show that plumes are formed by coarse-to-medium sand, suitable for coastal nourishment, but the reconstructed sediment dispersion lines show that some sectors of the coastline are constantly in the shade. These areas are the most affected by erosion