2,831 research outputs found

    Il tema della madre nella poesia di Venanzio Fortunato

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    Si esamina il tema della madre nell'opera omnia di Venanzio Fortunato nelle sue diverse espressioni: mater spiritualis; mater regni; mater doloros

    Prediction of crack propagation via local constitutive models with a scheme to track the discontinuity path

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    Estudam-se os aspectos referentes à qualidade e objetividade das respostas obtidas com as diferentes formulações (simétrica e não-simétrica) de elementos incorporados com descontinuidade forte regularizada, assim como com a abordagem contínua (distribuída), combinando-se a lei de abrandamento dependente do tamanho do elemento com um esquema de construção progressiva da trajetória de descontinuidade. O estudo é realizado com base nos conceitos de consistência cinemática e estática das formulações de elementos com descontinuidade incorporada.This paper addresses the study of the quality and objectivity of responses obtained with the distinct formulations (symmetric and non-symmetric) of the discontinuity embedded finite elements, as well as with the local continuum approach (smeared model), in which the softening law dependent on the element size is combined with a scheme to track the discontinuity path. The study is based on the concepts of kinematic and static consistency of the embedded discontinuity formulations.Peer Reviewe

    Boosting the characterization of heterogeneous catalysts for H2O2 direct synthesis by infrared spectroscopy

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    Infrared (IR) spectroscopy is among the most powerful spectroscopic techniques available for the morphological and physico-chemical characterization of catalytic systems, since it provides information on (i) the surface sites at an atomic level, (ii) the nature and structure of the surface or adsorbed species, as well as (iii) the strength of the chemical bonds and (iv) the reaction mechanism. In this review, an overview of the main contributions that have been determined, starting from IR absorption spectroscopy studies of catalytic systems for H2O2 direct synthesis, is given. Which kind of information can be extracted from IR data? IR spectroscopy detects the vibrational transitions induced in a material by interaction with an electromagnetic field in the IR range. To be IR active, a change in the dipole moment of the species must occur, according to well-defined selection rules. The discussion will be focused on the advancing research in the use of probe molecules to identify (and possibly, quantify) specific catalytic sites. The experiments that will be presented and discussed have been carried out mainly in the mid-IR frequency range, between approximately 700 and 4000 cm−1, in which most of the molecular vibrations absorb light. Some challenging possibilities of utilizing IR spectroscopy for future characterization have also been envisaged
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