756 research outputs found
Thermal Conductivity, Thermopower, and Figure of Merit of La_{1-x}Sr_xCoO_3
We present a study of the thermal conductivity k and the thermopower S of
single crystals of La_{1-x}Sr_xCoO_3 with 0<= x <= 0.3. For all Sr
concentrations La_{1-x}Sr_xCoO_3 has rather low k values, whereas S strongly
changes as a function of x. We discuss the influence of the temperature- and
the doping-induced spin-state transitions of the Co ions on both, S and k. From
S, k, and the electrical resistivity rho we derive the thermoelectric figure of
merit Z=S^2/(k*rho). For intermediate Sr concentrations we find notably large
values of Z indicating that Co-based materials could be promising candidates
for thermoelectric cooling.Comment: 7 pages, 5 figures included, submitted to Phys. Rev.
Magneto-elastic coupling and unconventional magnetic ordering in triangular multiferroic AgCrS2
The temperature evolution of the crystal and magnetic structures of
ferroelectric sulfide AgCrS2 have been investigated by means of neutron
scattering. AgCrS2 undergoes at TN = 41.6 K a first-order phase transition,
from a paramagnetic rhombohedral R3m to an antiferromagnetic monoclinic
structure with a polar Cm space group. In addition to being ferroelectric below
TN, the low temperature phase of AgCrS2 exhibits an unconventional collinear
magnetic structure that can be described as double ferromagnetic stripes
coupled antiferromagnetically, with the magnetic moment of Cr+3 oriented along
b within the anisotropic triangular plane. The magnetic couplings stabilizing
this structure are discussed using inelastic neutron scattering results.
Ferroelectricity below TN in AgCrS2 can possibly be explained in terms of
atomic displacements at the magneto-elastic induced structural distortion.
These results contrast with the behavior of the parent frustrated
antiferromagnet and spin-driven ferroelectric AgCrO2
Stability of geometrically frustrated magnetic state of Ca3CoRhO6 to applications of positive and negative pressure
The influence of negative chemical pressure induced by gradual replacement of
Ca by Sr as well as of external pressure (up to 10 kbar) on the magnetism of
Ca3CoRhO6 has been investigated by magnetization studies. It is found that the
solid solution, Ca(3-x)Sr(x)CoRhO6, exists at least till about x= 1.0 without
any change in the crystal structure. Apart from insensitivity of the spin-chain
feature to volume expansion, the characteristic features of geometrical
frustration interestingly appear at the same temperatures for all compositions,
in sharp contrast to the response to Y substitution for Ca (reported
previously). Interestingly, huge frequency dependence of ac susceptibility
known for the parent compound persists for all compositions. We do not find a
change in the properties under external pressure. The stability of the magnetic
anomalies of this compound to the volume change (about 4%) is puzzling
Inhomogeneous ferrimagnetic-like behavior in Gd2/3Ca1/3MnO3 single crystals
We present a study of the magnetic properties of Gd2/3Ca1/3MnO3 single
crystals at low temperatures. We show that this material behave as an
inhomogeneous ferrimagnet. In addition to small saturation magnetization at 5
K, we have found history dependent effects in the magnetization and the
presence of exchange bias. These features are compatible with microscopic phase
separation in the clean Gd2/3Ca1/3MnO3 system studied.Comment: 7 pages, 6 figures, submitted Journal of Magnetism and Magnetic
Material
Coupled Negative magnetocapacitance and magnetic susceptibility in a Kagome staircase-like compound Co3V2O8
The dielectric constant of the Kagome staircase-like Co3V2O8 polycrystalline
compound has been measured as function of temperature and magnetic field up to
14T. It is found that the application of an external magnetic field suppresses
the anomaly for the dielectric constant beyond 6.1K. Furthermore, its magnetic
field dependence reveals a negative magnetocapacitance which is proportional to
the magnetic susceptibility, suggesting a common magnetostrictive origin for
the magnetic field dependence of the two quantities. This result is very
different from that obtained from the isostructural compound Ni3V2O8 that
presents a peak in the dielectric constant at the incommensurate magnetic phase
transition coupled to a sign change of the magnetocapacitance
Inhomogeneous Magnetism in La-doped CaMnO3. (II) Mesoscopic Phase Separation due to Lattice-coupled FM Interactions
A detailed investigation of mesoscopic magnetic and crystallographic phase
separation in Ca(1-x)La(x)MnO3, 0.00<=x<=0.20, is reported. Neutron powder
diffraction and DC-magnetization techniques have been used to isolate the
different roles played by electrons doped into the eg level as a function of
their concentration x. The presence of multiple low-temperature magnetic and
crystallographic phases within individual polycrystalline samples is argued to
be an intrinsic feature of the system that follows from the shifting balance
between competing FM and AFM interactions as a function of temperature. FM
double-exchange interactions associated with doped eg electrons are favored
over competing AFM interactions at higher temperatures, and couple more
strongly with the lattice via orbital polarization. These FM interactions
thereby play a privileged role, even at low eg electron concentrations, by
virtue of structural modifications induced above the AFM transition
temperatures.Comment: 8 pages, 7 figure
Transport properties and magnetic field induced localization in the misfit cobaltite [BiBaKCo][CoO] single crystal
Resistivity under magnetic field, thermopower and Hall coefficient are
systematically studied for
[BiBaKCo][CoO] single crystal.
In-plane resistivity ((T)) shows metallic behavior down to 2 K with
a dependence below 30 K; while out-of-plane resistivity ()
shows metallic behavior at high temperature and a thermal activation
semiconducting behavior below about 12 K. Striking feature is that magnetic
field induces a ln(1/) diverging behavior in both and
at low temperature. The positive magnetoresistance (MR) could be
well fitted by the formula based on multi-band electronic structure. The
ln(1/) diverging behavior in and could arise from
the magnetic-field-induced 2D weak localization or spin density wave.Comment: 7 pages, 8 figure
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