Structure and dynamics of the fullerene polymer Li4 C60 studied with neutron scattering

The two-dimensional polymer structure and lattice dynamics of the superionic conductor Li4 C60 are investigated by neutron diffraction and spectroscopy. The peculiar bonding architecture of this compound is definitely confirmed through the precise localisation of the carbon atoms involved in the intermolecular bonds. The spectral features of this phase are revealed through ab-initio lattice dynamics calculations and inelastic neutron scattering experiments. The neutron observables are found to be in very good agreement with the simulations which predict a partial charge transfer from the Li atoms to the C60 cage. The absence of a well defined band associated to one category of the Li atoms in the experimental spectrum suggests that this species is not ordered even at the lowest temperatures. The calculations predict an unstable Li sublattice at a temperature of 200 K, that we relate to the large ionic diffusivity of this system. This specificity is discussed in terms of coupling between the low frequency optic modes of the Li ions to the soft structure of the polymer.Comment: 29 pages, 13 Figure

On Character Education: Self-Formation and Forms of Life in a Morphogenic Society

Abstract: The essay discusses the concept of character, and some related notions, as they emerge in the contemporary discourse on education. The aim of this article is to provide a sociological interpretation of the increasing relevance of such notions within education policy agendas at the global level. More precisely, the focus is on what could be described as an intensification of reflexivity upon the human being, and a growing interest in the 'whole child' in educational agendas, i.e. in personal development beyond the learning outcomes regarding academic topics. The argument develops three main points. First, the principal structural and cultural conditionings are examined that play a role in fostering the renewed importance of personhood. Furthermore, different conceptual frameworks are examined that result in different psycho-semantics. The essay shows how such concepts as character and social and emotional skills (SES) epitomize different, comprehensive conceptions of human selfhood. The article examines their divergence and convergence alike. Finally, some possibilities of integration between the approaches of character and SES are briefly sketched

An Exploratory Study of Users’ Preference for Different Planting Combinations along Rural Greenways

The literature highlights the importance of vegetation to enhance the ecological and visual qualities of streets and paths; however, when studies specifically focus on rural greenways they do not consider users' assessments of the planting design. This exploratory study aims to contribute to this issue. It is hypothesized that planting combinations characterized by greater variety and aesthetic flow may be more preferred and restorative. To this end, four virtual scenarios simulating bikers moving along a greenway at 25 km/h were created to find out the following: first, what kind of planting combination is the most preferred, and second, which planting combination is perceived as the most restorative by bicycle riders. To assess the experience, subjects were administered a questionnaire made up of: (i) the Perceived Restorativeness Scale-11 with additional items to assess compatibility, familiarity, and preference; (ii) a list of physical and aesthetic attributes; and (iii) information on bicycle use. The results show that participants' preferences were a ffected by the perception of the scenario's restorative value, which was not given exclusively by the degree of naturalness, but by the opportunity the greenway o ffered to engage in social/physical activities. This study shows that preference and restorativeness are not a "simple" matter of quantity of vegetation, but of quality instead, i.e., planting variety. Designers have to consider that the restorative value of greenways is related to the opportunities they offer to engage in physical/social activities

Interplay between static and dynamic polar correlations in relaxor Pb(Mg_{1/3}Nb_{2/3})O_{3}

We have characterized the dynamics of the polar nanoregions in Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) through high-resolution neutron backscattering and spin-echo measurements of the diffuse scattering cross section. We find that the diffuse scattering intensity consists of \emph{both} static and dynamic components. The static component first appears at the Curie temperature $\Theta \sim 400$ K, while the dynamic component freezes completely at the temperature T$_{f} \sim 200$ K; together, these components account for all of the observed spectral weight contributing to the diffuse scattering cross section. The integrated intensity of the dynamic component peaks near the temperature at which the frequency-dependent dielectric constant reaches a maximum (T$_{max}$) when measured at 1 GHz, i. e. on a timescale of $\sim 1$ ns. Our neutron scattering results can thus be directly related to dielectric and infra-red measurements of the polar nanoregions. Finally, the global temperature dependence of the diffuse scattering can be understood in terms of just two temperature scales, which is consistent with random field models.Comment: (8 pages, 5 figures, submitted to Phys. Rev. B

The effects of weathering on the physical and mechanical properties of igneous and metamorphic saprolites

The present paper presents three extensive datasets of laboratory testing on weathered geomaterials, which are emblematic of soil types widely found worldwide. The overall dataset includes soils originating from igneous and metamorphic rocks, either coarse or fine grained and having either felsic or mafic minerals. In particular, the data are interpreted to highlight the effects that weathering has on the physical and mechanical properties of these natural geomaterials comparing them with published data with the aim to provide a general framework of interpretation that takes into account this geological process and links soil mechanics to engineering geology. Generally, weathering induces a reduction in the grain size, both due to physical actions (e.g. opening of grain contacts) and to the chemical decomposition of minerals resulting in the formation of clay minerals. As weathering proceeds and the soil becomes finer, the in situ specific volume and the location of the normal compression and critical state lines move upwards in the volumetric plane. On the other hand, the clay minerals cause its angle of shearing resistance to reduce. When analysing the behaviour of the intact soil, in all cases positive effects of structure, albeit small compared to some sedimentary soils, were observed and these reduced as a consequence of weathering

Solid Surface Structure Affects Liquid Order at the Polystyrene/SAM Interface

We present a combined x-ray and neutron reflectivity study characterizing the interface between polystyrene (PS) and silanized surfaces. Motivated by the large difference in slip velocity of PS on top of dodecyl-trichlorosilane (DTS) and octadecyl-trichlorosilane (OTS) found in previous studies, these two systems were chosen for the present investigation. The results reveal the molecular conformation of PS on silanized silicon. Differences in the molecular tilt of OTS and DTS are replicated by the adjacent phenyl rings of the PS. We discuss our findings in terms of a potential link between the microscopic interfacial structure and dynamic properties of polymeric liquids at interfaces

Thermal dosimetry for bladder hyperthermia treatment. An overview.

The urinary bladder is a fluid-filled organ. This makes, on the one hand, the internal surface of the bladder wall relatively easy to heat and ensures in most cases a relatively homogeneous temperature distribution; on the other hand the variable volume, organ motion, and moving fluid cause artefacts for most non-invasive thermometry methods, and require additional efforts in planning accurate thermal treatment of bladder cancer. We give an overview of the thermometry methods currently used and investigated for hyperthermia treatments of bladder cancer, and discuss their advantages and disadvantages within the context of the specific disease (muscle-invasive or non-muscle-invasive bladder cancer) and the heating technique used. The role of treatment simulation to determine the thermal dose delivered is also discussed. Generally speaking, invasive measurement methods are more accurate than non-invasive methods, but provide more limited spatial information; therefore, a combination of both is desirable, preferably supplemented by simulations. Current efforts at research and clinical centres continue to improve non-invasive thermometry methods and the reliability of treatment planning and control software. Due to the challenges in measuring temperature across the non-stationary bladder wall and surrounding tissues, more research is needed to increase our knowledge about the penetration depth and typical heating pattern of the various hyperthermia devices, in order to further improve treatments. The ability to better determine the delivered thermal dose will enable clinicians to investigate the optimal treatment parameters, and consequentially, to give better controlled, thus even more reliable and effective, thermal treatments

Formation of octapod MnO nanoparticles with enhanced magnetic properties through kinetically-controlled thermal decomposition of polynuclear manganese complexes

Polynuclear manganese complexes are used as precursors for the synthesis of manganese oxide nanoparticles (MnO NPs). Altering the thermal decomposition conditions can shift the nanoparticle product from spherical, thermodynamically-driven NPs to unusual, kinetically-controlled octapod structures. The resulting increased surface area profoundly alters the NP's surface-dependent magnetism and may have applications in nanomedicine

The effect of the protein corona on the interaction between nanoparticles and lipid bilayers

Hypothesis It is known that nanoparticles (NPs) in a biological fluid are immediately coated by a protein corona (PC), composed of a hard (strongly bounded) and a soft (loosely associated) layers, which represents the real nano-interface interacting with the cellular membrane in vivo. In this regard, supported lipid bilayers (SLB) have extensively been used as relevant model systems for elucidating the interaction between biomembranes and NPs. Herein we show how the presence of a PC on the NP surface changes the interaction between NPs and lipid bilayers with particular care on the effects induced by the NPs on the bilayer structure. Experiments In the present work we combined Quartz Crystal Microbalance with Dissipation Monitoring (QCM-D) and Neutron Reflectometry (NR) experimental techniques to elucidate how the NP-membrane interaction is modulated by the presence of proteins in the environment and their effect on the lipid bilayer. Findings Our study showed that the NP-membrane interaction is significantly affected by the presence of proteins and in particular we observed an important role of the soft corona in this phenomenon