Localized corrosion of high performance metal alloys in an acid/salt environment

Various vacuum jacketed cryogenic supply lines at the Space Shuttle launch site at Kennedy Space Center use convoluted flexible expansion joints. The atmosphere at the launch site has a very high salt content, and during a launch, fuel combustion products include hydrochloric acid. This extremely corrosive environment has caused pitting corrosion failure in the thin walled 304L stainless steel flex hoses. A search was done to find a more corrosion resistant replacement material. The study focussed on 19 metal alloys. Tests which were performed include electrochemical corrosion testing, accelerated corrosion testing in a salt fog chamber, and long term exposure at a beach corrosion testing site. Based on the results of these tests, several nickel based alloys were found to have very high resistance to this corrosive environment. Also, there was excellent agreement between the electrochemical tests and the actual beach exposure tests. This suggests that electrochemical testing may be useful for narrowing the field of potential candidate alloys before subjecting samples to long term beach exposure

Paper Session III-C - Corrosion Protection of Launch Infrastructure and Flight Hardware at the Kennedy Space Center

The Kennedy Space Center (KSC) is a major source of worldwide corrosion expertise. Corrosion studies began at KSC in 1966 during the Gemini/Apollo Programs with the evaluation of long-term protective coatings for the atmospheric protection of carbon steel. NASA’s KSC Beach Corrosion Test Site was established at that time. The site has provided over 30 years of technical information on the long-term performance of many materials and continues to be upgraded with state-of-the-art capabilities to meet the current and future needs of NASA, other government agencies, and industry for corrosion protection. With the introduction of the Space Shuttle in 1981, the already highly corrosive conditions at the launch pad were rendered even more severe by the acidic exhaust from the solid rocket boosters. In the years that followed, numerous studies have identified materials, coatings, and maintenance procedures for launch hardware and equipment exposed to the highly corrosive environment at the launch pad. KSC’s Materials Science Laboratories have conducted testing and research in the field of corrosion since 1968. The Corrosion Laboratory was established in 1985 and was outfitted with stateof- the-art equipment to conduct research and materials evaluation in many different corrosive environments. In 2000, the Corrosion Technology Testbed was created in order to achieve KSC’s goal of increased participation in research and development. The Corrosion Technology Testbed is staffed with scientists, corrosion engineers and technicians with extensive experience in the field of corrosion and is outfitted with state-of-the-art instrumentation and equipment to develop new corrosion control technologies and to investigate, evaluate, and determine materials behavior in many different corrosive environments. Its facilities include an Atmospheric Exposure Test Site, documented by the American Society of Materials (ASM) as one of the most corrosive naturally occurring environments in the world, an Electrochemistry Laboratory, a Seawater Immersion System, a Coatings Application Laboratory, and an Accelerated Corrosion Laboratory. The site has recently been outfitted with network connectivity for data acquisition through the Internet. A historical perspective highlighting the lessons learned in over thirty years of corrosion research, materials evaluation, and development work aimed at protecting and enhancing the safety and reliability of the nation’s launch infrastructure and hardware will be presented

Electrochemical Evaluation of Stainless Steels in Acidified Sodium Chloride Solutions

This paper presents the results of an investigation in which several 300-series stainless steels (SS): AISI S30403 SS (UNS S30403), AISI 316L SS (UNS S31603), and AISI 317L SS (LINS S31703), as well as highly-alloyed: SS 254-SMO (UNS S32154), AL-6XN (N08367) and AL29-4C (UNS S44735), were evaluated using DC electrochemical techniques in three different electrolyte solutions. The solutions consisted of neutral 3.55% NaCl, 3.55% NaCl in 0.1N HCl, and 3.55% NaCl in 1.0N HCl. These solutions were chosen to simulate environments that are less, similar, and more aggressive, respectively, than the conditions at the Space Shuttle launch pads. The electrochemical test results were compared to atmospheric exposure data and evaluated for their ability to predict the long-term corrosion performance of the subject alloys. The electrochemical measurements for the six alloys indicated that the higher-alloyed SS 254-SMO, AL29-4C, and AL-6XN exhibited significantly higher resistance to localized corrosion than the 300-series SS. There was a correlation between the corrosion performance of the alloys during a two-year atmospheric exposure and the corrosion rates calculated from electrochemical (polarization resistance) measurements

Molecular transport and flow past hard and soft surfaces: Computer simulation of model systems

The properties of polymer liquids on hard and soft substrates are investigated by molecular dynamics simulation of a coarse-grained bead-spring model and dynamic single-chain-in-mean-field (SCMF) simulations of a soft, coarse-grained polymer model. Hard, corrugated substrates are modelled by an FCC Lennard-Jones solid while polymer brushes are investigated as a prototypical example of a soft, deformable surface. From the molecular simulation we extract the coarse-grained parameters that characterise the equilibrium and flow properties of the liquid in contact with the substrate: the surface and interface tensions, and the parameters of the hydrodynamic boundary condition. The so-determined parameters enter a continuum description like the Stokes equation or the lubrication approximation.Comment: 41 pages, 13 figure

Coarse-grained models for fluids and their mixtures: Comparison of Monte Carlo studies of their phase behavior with perturbation theory and experiment

The prediction of the equation of state and the phase behavior of simple fluids (noble gases, carbon dioxide, benzene, methane, short alkane chains) and their mixtures by Monte Carlo computer simulation and analytic approximations based on thermodynamic perturbation theory is discussed. Molecules are described by coarse grained (CG) models, where either the whole molecule (carbon dioxide, benzene, methane) or a group of a few successive CH_2 groups (in the case of alkanes) are lumped into an effective point particle. Interactions among these point particles are fitted by Lennard-Jones (LJ) potentials such that the vapor-liquid critical point of the fluid is reproduced in agreement with experiment; in the case of quadrupolar molecules a quadrupole-quadrupole interaction is included. These models are shown to provide a satisfactory description of the liquid-vapour phase diagram of these pure fluids. Investigations of mixtures, using the Lorentz-Berthelot (LB) combining rule, also produce satisfactory results if compared with experiment, while in some previous attempts (in which polar solvents were modelled without explicitly taking into account quadrupolar interaction), strong violations of the LB rules were required. For this reason, the present investigation is a step towards predictive modelling of polar mixtures at low computational cost. These very simple coarse-grained models of small molecules developed here should be useful e.g. for simulations of polymer solutions with such molecules as solvent.Comment: J. Chem. Phys., accepte

Snyder's Quantized Space-time and De Sitter Special Relativity

There is a one-to-one correspondence between Snyder's model in de Sitter space of momenta and the \dS-invariant special relativity. This indicates that physics at the Planck length $\ell_P$ and the scale $R=3/\Lambda$ should be dual to each other and there is in-between gravity of local \dS-invariance characterized by a dimensionless coupling constant $g=\ell_P/R\sim 10^{-61}$.Comment: 8 page