Layer by Layer Silver Acetate based Coating on Glass and Cement Substrates to Tailor Reflectance and Conductance

Tailoring reflectance and conductance was achieved through layer by layer assembly of a silver acetate based multilayer coating. The coating was applied over glass and cement substrates by sol-gel spin coating and by brush painting, respectively. The structural, optical and electrical characteristics and the composition of the coating were studied. The diffraction peaks for all films revealed that the face-centered cubic lattice of the silver crystal structure and the films with more layers had a higher degree of crystallinity. The optical characteristics showed that having more layers leads to decreasing transmittance and increasing reflectance. The I-V characteristics of all samples showed typical ohmic contacts in a voltage range of -1 to 1 V. The conductance increased drastically as the coating developed into multiple layers. The eight-layer coated glass and cement based substrates had very low surface resistance, at 4 Ω and 2 Ω at 1 V, respectively. The study also revealed that the resistance behavior of a multilayered film generally is thermally stable for annealing up to 400 °C. The coating resistance was significantly increased by further increasing the post-annealing beyond 500 °C. The studied multilayered coating can be used to tailor the reflectance and conductance of dielectric substrate surfaces for various optoelectronics and sensor device applications

Evaluating The Effects of Micro and Nano Size of Silica Filler on Asphalt Cement Properties

This research study examines the practicability of using micro and nano size silica to improve the asphalt characteristics. Asphalt cement penetration grade of (60 /70) was prepared using (0%, 2%, 4% and 6%) of silica filler by weight of asphalt and investigated in terms of the softening point, penetration, and penetration index, viscosity, and ductility values. To modify the asphalt binder, the silica powder was mixed by a mechanical blender set at (2000) rpm at a mixing temperature of 140°C. However, the main challenge is an agglomeration of nano-silica powder which can reduce the ductility of nano silica modified binder. Therefore, this paper studies the efficiency of mixing period to obtain a homogeneous composite binder while alleviating the agglomeration issue. To do so, the effect of periods of mixing ranged between (30 to 60) minutes were examined on characteristics of modified asphalt binders. Overall, the addition of silica filler has an encouraging impact on the asphalt binder rheological properties. Also, the ductility value decreases with the addition of nano-silica content, attributed to the huge surface area and degree of agglomeration. Furthermore, results exhibited that 6% of micro silica powder and 4 % of nano silica powder were reasonable to develop the rheological properties

Pozzolanic Activity and Compressive Strength of Concrete Incorporated nano/micro Silica

This paper aims to give a recommendation about the suitable nano silica proportion and curing method for testing its strength pozzolonic activity, in addition to suggest a mixing or batching procedure of this material with other concrete ingredients. Theinfluence of nanoand micro silicaon concrete compressive strength is also studied. Three proportions of nano silica (0.5, 5, &10%) , two curing methods (accelerated in oven and normal in water) and two tested agesare used in pozzolonic activity test of nano silica. For compressive strength test, eleven mixes are considered:without-adding (two mixes), three micro silica (M) mixes with replacement ratios of 5, 10 & 15%, four nano silica (N) mixeswith replacement ratiosof 0.5,1.5, 3 & 5%, and three micro plus nano silica mixes (0.5N+9.5M,1.5N+8.5M and 3N+7M%) are adopted.Results of pozzolanic activity test denoted that nano silica has remarkable pozzolanic activity for all tested replacements.However, it is suggest using 5% nano silica for performing this testby usingeither accelerated or water curing. Additionally, it was found that nano silica had more impact on compressive strength of concrete than micro silica for all tested ages.Where, maximum enhancement ratios of compressive strength were about 33% and 27% for 3% nano silica mix at 7 and 90 days age respectively, and 22% for 5% nano silica mix at 28 days age. For micro silica mixes, higher improvement ratios were found in 15% micro silica mix: 2%,5%&7% at 7,28 &90 days age respectively

Effect of Steel Fibers, Polypropylene Fibers and/ or Nanosilica on Mechanical Properties of Self-Consolidating Concrete

This research concerned studying the combined effect of using nano-silica and/ or hybrid fibers on key mechanical properties of self-consolidating concrete SCC. A comprehensive experimental work has been carried out, using steel fiber (SF) with volume fraction (0, 0.5% and 1.5%), polypropylene fiber (PPF) (0%, 0.05% and 0.15%) and SiO2 nanoparticles (0%, 2% and 4%) by weight of powdered material (silica fume- Sf ) with constant w/c ratio (0.48) to produce eleven different mixtures and tested at different ages (7, 28 and 90 days). Results showed that adding fibers adversely affect SCC workability and thus more dosage of super plasticizer (SP) should be added to stay within the standard limits. comparable to conventional concretes, the presence of steel fibers with SCC provide slight increase in compressive strength at 28 days, (up to 11%), while significant enhancement in tensile properties were observed (up to 24% and 32% for splitting and flexural strength respectively). Polypropylene or hybrid fibers however, provide lower enhancement compared with steel fibers. In contrast, implementation of nanosilica leads to significant improvement in concrete strengths particularly at 4% dosage. Combined effect of 4% nanosilica and 1.5% of steel fibers provide the superior hardening effect on the flexural performance compared with softening effect provided by other added dosages. Scanning Electron Micrograph (SEM) images confirm the matrix densification effect due to nanosilica adding. Flexural strength of SCCs without nanosilica was generally higher than splitting testing results. This fact does not change even with the presence of nanosilica and/ or fibers

Mechanical Properties of Polymer-, Pozzolanic Cement- Based Repairing Materials

In this study, the mechanical properties of five different cement based repairing materials were evaluated. These materials were classified into two groups: laboratory made materials with or without admixtures (3 types), and other two types of commercial proprietary pre-packaged with additives. Mechanical properties, such as compressive strength, modulus of rupture and drying shrinkage were studied. Results show that these mechanical properties were varying significantly from each other. The drying shrinkage of the commercial proprietary repair materials was less than that of the conventional mortar. This will lead to a reduced cracking risk in the former repair materials compared to the latter. Through the regression analysis on the experimental data collected, power relation with coefficient of determination of 0.766 is obtained between compressive and modulus of rupture

Microscopic trans-cerebellar approach for infratentorial cavernous malformation near the lateral recess associated with developmental venous anomaly: Case report

Background: Reports showed the intimate association of the developmental venous anomaly with infra-tentorial cavernous malformation. This association has several clinical and surgical implications, sometimes this association will be a surgical challenge and affect the selection of the safest approach to the lesion. Surgery for infratentorial cavernoma is indicated for accessible symptomatic lesion only. Case scenario: we present a case of deep cerebello-pontine CM adjacent to the lateral recess, presented with acute clinical deterioration to the emergency department of the Neurosurgery Teaching Hospital in Baghdad, Iraq, with the only possible approach was Trans-cerebellar approach because of the medial location of the associated DVA. Conclusion: The association of developmental venous anomaly with infratentorial cavernous malformation has a pivotal role in selection the most appropriate and safe surgical approach which should be based upon the individualized patient anatomy and the location of the target lesion

Saliva Proteins of Vector Culicoides Modify Structure and Infectivity of Bluetongue Virus Particles

Bluetongue virus (BTV) and epizootic haemorrhagic disease virus (EHDV) are related orbiviruses, transmitted between their ruminant hosts primarily by certain haematophagous midge vectors (Culicoides spp.). The larger of the BTV outer-capsid proteins, ‘VP2’, can be cleaved by proteases (including trypsin or chymotrypsin), forming infectious subviral particles (ISVP) which have enhanced infectivity for adult Culicoides, or KC cells (a cell-line derived from C. sonorensis). We demonstrate that VP2 present on purified virus particles from 3 different BTV strains can also be cleaved by treatment with saliva from adult Culicoides. The saliva proteins from C. sonorensis (a competent BTV vector), cleaved BTV-VP2 more efficiently than those from C. nubeculosus (a less competent / non-vector species). Electrophoresis and mass spectrometry identified a trypsin-like protease in C. sonorensis saliva, which was significantly reduced or absent from C. nubeculosus saliva. Incubating purified BTV-1 with C. sonorensis saliva proteins also increased their infectivity for KC cells ∼10 fold, while infectivity for BHK cells was reduced by 2–6 fold. Treatment of an ‘eastern’ strain of EHDV-2 with saliva proteins of either C. sonorensis or C. nubeculosus cleaved VP2, but a ‘western’ strain of EHDV-2 remained unmodified. These results indicate that temperature, strain of virus and protein composition of Culicoides saliva (particularly its protease content which is dependent upon vector species), can all play a significant role in the efficiency of VP2 cleavage, influencing virus infectivity. Saliva of several other arthropod species has previously been shown to increase transmission, infectivity and virulence of certain arboviruses, by modulating and/or suppressing the mammalian immune response. The findings presented here, however, demonstrate a novel mechanism by which proteases in Culicoides saliva can also directly modify the orbivirus particle structure, leading to increased infectivity specifically for Culicoides cells and, in turn, efficiency of transmission to the insect vector

Intraperitoneal drain placement and outcomes after elective colorectal surgery: international matched, prospective, cohort study

Despite current guidelines, intraperitoneal drain placement after elective colorectal surgery remains widespread. Drains were not associated with earlier detection of intraperitoneal collections, but were associated with prolonged hospital stay and increased risk of surgical-site infections.Background Many surgeons routinely place intraperitoneal drains after elective colorectal surgery. However, enhanced recovery after surgery guidelines recommend against their routine use owing to a lack of clear clinical benefit. This study aimed to describe international variation in intraperitoneal drain placement and the safety of this practice. Methods COMPASS (COMPlicAted intra-abdominal collectionS after colorectal Surgery) was a prospective, international, cohort study which enrolled consecutive adults undergoing elective colorectal surgery (February to March 2020). The primary outcome was the rate of intraperitoneal drain placement. Secondary outcomes included: rate and time to diagnosis of postoperative intraperitoneal collections; rate of surgical site infections (SSIs); time to discharge; and 30-day major postoperative complications (Clavien-Dindo grade at least III). After propensity score matching, multivariable logistic regression and Cox proportional hazards regression were used to estimate the independent association of the secondary outcomes with drain placement. Results Overall, 1805 patients from 22 countries were included (798 women, 44.2 per cent; median age 67.0 years). The drain insertion rate was 51.9 per cent (937 patients). After matching, drains were not associated with reduced rates (odds ratio (OR) 1.33, 95 per cent c.i. 0.79 to 2.23; P = 0.287) or earlier detection (hazard ratio (HR) 0.87, 0.33 to 2.31; P = 0.780) of collections. Although not associated with worse major postoperative complications (OR 1.09, 0.68 to 1.75; P = 0.709), drains were associated with delayed hospital discharge (HR 0.58, 0.52 to 0.66; P < 0.001) and an increased risk of SSIs (OR 2.47, 1.50 to 4.05; P < 0.001). Conclusion Intraperitoneal drain placement after elective colorectal surgery is not associated with earlier detection of postoperative collections, but prolongs hospital stay and increases SSI risk

Modeling Stability and Flow of Asphalt Mixes Using Optimum Asphalt content

The main aim of this study was to evaluate the asphalt mixture properties for samples that were taken from different sites and plants: Amanat Baghdad, Faluja municipality, and Baghdad Governorate, which almost produced in private plants. Forty seven asphalt mixtures samples were tested following Marshall Test. The tested properties were: Marshall Stability, Marshall Flow, specimen density, and air voids. Asphalt extraction was carried out according to quantative extraction of bitumen from paving mixtures test. A statistical analysis of the collected field data was performed and a prediction model was built. The variables such as asphalt content, stability and flow data were analyzed using computer software. The statistical analysis includes four stages: data extraction and evaluation, verification, calibration, and validation.Results of this study indicate that both of Marshall Stability and Marshall Flow correlate positively with asphalt content, but with different degree. Asphalt content affect Stability property much more than flow property of the asphalt mixes

AIR POLLUTANTS MITIGATION BY USING VARIOUS FORMS OF PHOTOCATALYTIC CEMENTITIOUS COATINGS MATERIALS

Nitric oxide generated from various sources like car combustion is one of the most surrounding pollutants, which can be transferred from one form to another in the presence of sunlight. Titanium dioxide considered one of the most environmentally friendly active photocatalytics that can be used with building materials safely and effectively to react with nitric oxides. To study the possibility for the reduction of air pollutants like nitric oxides, two types of substrates coatings were prepared. First, mixing nano particles of TiO2 with cement paste in two percents 3% and 6%. Second, mortar substrates coated with nano TiO2 aqueous solution. Two coating methods have been used dip and spray. A laboratory test procedure was adopted to assess the performance of the prepared photoactive specimens. The specimens were subjected to NO gas and there efficiency in gas removal was monitored with time. Results showed the effectivity of coating building materials with titanium dioxide, the removal of gaseous pollutants like nitric oxide reached to 98.85% when spray and dip methods are used. Mixing nano titanium with a percent of 3% was also efficient in the removal of nitric oxides, the removal reached to 97%. It was concluded that spray method was more practical to be used