Sr isotopic signatures of Portuguese bottled mineral waters, their relationships with the geological setting and potential use for product authentication

The Sr isotopic ratios of nine bottled natural mineral waters from Portugal were measured in the Laboratory of Isotope Geology of the University of Aveiro (LGIUA). The results obtained show that the Sr isotopic variability of these waters is strongly correlated with the age and mineralogical composition of the aquifer source rocks. The lowest 87Sr/86Sr ratios are found in water samples from the Monchique aquifer (87Sr/86Sr = 0,70447), located in Late Cretaceous alkaline magmatic rocks of mantle origin. The Vimeiro waters are hosted in carbonate and evaporite formations of Jurassic age and have 87Sr/86Sr values of 0,70808, whereas the waters sourced in Cenozoic siliciclastic sediments tend to exhibit higher 87Sr/86Sr ratios, close to the rainwater value (São Silvestre; 87Sr/86Sr = 0,71078). Finally, the waters coming from granitic and/or metamorphic terrains of the Iberian Variscan basement (Vitalis, Luso, Carvalhelhos, Fastio, Serra da Estrela) display the most radiogenic Sr isotopic signatures (87Sr/86Sr > 0,7136). In the modern commercial context, the differences encountered provide a powerful tool for fingerprinting the mineral water origin and may be used for purposes of mineral water authentication. The use of 87Sr/86Sr ratios may also be extended to studies on the provenance of some foods and beverages, taking into account the influence of the geological / pedological factor on the Sr isotopic composition recorded by the plants

Drop distribution determination in a liquid-liquid dispersion by image processing

This paper presents the implementation of an algorithm for automatic identification of drops with different sizes in of a These image frames were obtained at our Laboratory, using a nonintrusive process, with a digital video camera, a microscope, and an illumination setup from a dispersion of toluene in water within a transparent mixing vessel. In this implementation, we propose a two-phase approach, using a Hough transform that automatically identifies drops in images of the chemical process. This work is a promising starting point for the possibility of performing an automatic drop classification with good results. Our for the analysis and interpretation of digitized images will be used for the calculation of particle size and shape distributions for modelling liquid-liquid systems.info:eu-repo/semantics/publishedVersio

Sr-Nd isotope signatures of surficial sediments from the Portuguese continental shelf

This study focus on the Sr-Nd isotope signatures of detrital and carbonate fractions of seven samples from surficial sediments deposited in the Portuguese continental shelf. 87Sr/86Sr and 143Nd/144Nd isotope compositions of the lithic component are used to constrain potential endmember contributions and determine sediment provenance. The 87Sr/86Sr ratios measured in the acid leachates of the seven sediment samples (carbonate fraction) lie within the range 0.7088 – 0.7092, close to the value for modern seawater (0.7091 – 0.7092), suggesting a dominant biogenic origin for this component. In contrast, the Sr isotope signatures for acid-leached silicate residues (lithic fraction) from the same samples are widely variable (87Sr/86Sr = 0.7179 to 0.7346) reflecting the input of terrigenous particles from three distinct sources (northern Iberian Variscan crust, southern Iberian Variscan crust and North African aerosols). The narrow range of ƐNd(0) values displayed by these samples (-8.5 to -10.6) does not allow effective discrimination between the different endmembers

Sustainability Improvement of a composite materials’ industry through recycling and re-engineering process approaches

Recent Advances in Mechanics and Materials in DesignThis case study was aimed at measuring and assessing the potential improvements that could be made on the eco-efficiency performance of a composite materials’ industry, specifically a glass fibre reinforced plastic (GFRP) pultrusion manufacturing company. For this purpose, all the issues involved in the pultrusion process of GFRP profiles were analysed, the current ecoefficiency performance of the company was determined, all the procedures applied in the production process were revised, and improvement strategies were planned and investigated with basis on the performed analysis. The new eco-efficiency ratios were estimated taking into account the implementation of new proceedings and procedures through re-engineering the manufacturing process and recycling approaches. These features lead to significant improvements on the sequent assessed eco-efficiency ratios, yielding to a more sustainable product and manufacturing process of pultruded GFRP profiles

A case study on the eco-efficiency performance of a composite processing industry: evaluation and quantification of potential improvements

In this study, an attempt was made in order to measure and evaluate the eco-efficiency performance of a pultruded composite processing company. For this purpose the recommendations of World Business Council for Sustainable Development (WCSD) and the directives of ISO 14301 standard were followed and applied. The main general indicators of eco-efficiency, as well as the specific indicators, were defined and determined. With basis on indicators’ figures, the value profile, the environmental profile, and the pertinent eco-efficiency ratios were established and analyzed. In order to evaluate potential improvements on company eco-performance, new indicators values and eco-efficiency ratios were estimated taking into account the implementation of new proceedings and procedures, at both upstream and downstream of the production process, namely: i) Adoption of a new heating system for pultrusion die-tool in the manufacturing process, more effective and with minor heat losses; ii) Recycling approach, with partial waste reuse of scrap material derived from manufacturing, cutting and assembly processes of GFRP profiles. These features lead to significant improvements on the sequent assessed eco-efficiency ratios of the present case study, yielding to a more sustainable product and manufacturing process of pultruded GFRP profiles

Experimental study on polyester based concretes filled with glass fibre reinforced plastic recyclates – a contribution to composite materials sustainability

The development and applications of thermoset polymeric composites, namely fibre reinforced plastics (FRP), have shifted in the last decades more and more into the mass market [1]. Despite of all advantages associated to FRP based products, the increasing production and consume also lead to an increasing amount of FRP wastes, either end-of-lifecycle products, or scrap and by-products generated by the manufacturing process itself. Whereas thermoplastic FRPs can be easily recycled, by remelting and remoulding, recyclability of thermosetting FRPs constitutes a more difficult task due to cross-linked nature of resin matrix. To date, most of the thermoset based FRP waste is being incinerated or landfilled, leading to negative environmental impacts and supplementary added costs to FRP producers and suppliers. This actual framework is putting increasing pressure on the industry to address the options available for FRP waste management, being an important driver for applied research undertaken cost efficient recycling methods. [1-2]. In spite of this, research on recycling solutions for thermoset composites is still at an elementary stage. Thermal and/or chemical recycling processes, with partial fibre recovering, have been investigated mostly for carbon fibre reinforced plastics (CFRP) due to inherent value of carbon fibre reinforcement; whereas for glass fibre reinforced plastics (GFRP), mechanical recycling, by means of milling and grinding processes, has been considered a more viable recycling method [1-2]. Though, at the moment, few solutions in the reuse of mechanically-recycled GFRP composites into valueadded products are being explored. Aiming filling this gap, in this study, a new waste management solution for thermoset GFRP based products was assessed. The mechanical recycling approach, with reduction of GFRP waste to powdered and fibrous materials was applied, and the potential added value of obtained recyclates was experimentally investigated as raw material for polyester based mortars. The use of a cementless concrete as host material for GFRP recyclates, instead of a conventional Portland cement based concrete, presents an important asset in avoiding the eventual incompatibility problems arisen from alkalis silica reaction between glass fibres and cementious binder matrix. Additionally, due to hermetic nature of resin binder, polymer based concretes present greater ability for incorporating recycled waste products [3]. Under this scope, different GFRP waste admixed polymer mortar (PM) formulations were analyzed varying the size grading and content of GFRP powder and fibre mix waste. Added value of potential recycling solution was assessed by means of flexural and compressive loading capacities of modified mortars with regard to waste-free polymer mortars

New insights from U–Pb zircon dating of Early Ordovician magmatism on

The Central Iberian–Ossa-Morena transition zone (SW Iberian Massif) represents a segment of the northern Gondwana margin with a long geodynamic evolution, characterized by the superposition of Cadomian and Variscan events. The Early Ordovician is mainly represented by porphyritic felsic volcaniclastic rocks (the Urra Formation) that pass up into a siliciclastic sediments typical of the Central Iberian Zone (Lower Ordovician Armorican Quartzite Formation). The Urra Formation unconformably overlies the previously deformed and metamorphosed Ediacaran sediments of the Série Negra (with Ossa-Morena Zone paleogeographic affinity). New SHRIMP zircon data obtained from the Urra Formation volcaniclastic rocks indicate an Early Ordovician age (206Pb/238U ages ranging from 494.6±6.8 Ma to 488.3±5.2 Ma) for this magmatic event. The inherited zircon cores indicate the presence of multicycle protoliths with different Precambrian ages: Neoproterozoic (698–577 Ma), Paleoproterozoic (2.33 Ga) and Paleoarchean (3.2–3.3 Ga). There is a noticeable lack of Meso- to Neoarchean and Mesoproterozoic ages. The data support the hypothesis that the volcaniclastic rocks were derived by partial melting of Cadomian basement (linked to a West African Craton provenance). The Urra Formation volcaniclastic rocks have rhyolitic to dacitic compositions, are peraluminous and similar to calc-alkaline high-K series suites elsewhere. Isotopic signatures present a wide range of values (87Sr/86Sr)t=0.7085–0.7190, more restricted εNdt (−2.65 to −0.35) and δ18O=9.63–10.34‰, compatible with magmas derived from crustal rocks, including portions of the lower crust. Some samples show disturbance of the Rb–Sr system as shown by unrealistic values for (87Sr/86Sr)tb0.703, probably due to Variscan deformation and metamorphism. The volcaniclastic rocks with a significant sedimentary contribution (upper unit) are distinguished from the others by the lowest values of εNdt (−5.53 to −4.85). The geochemical data are compatible with an orogenic geodynamic environment. However, the “orogenic” signature can be considered to represent, in part, an inherited feature caused by melting of the Cadomian basement which also has calc-alkaline affinities. The Early Ordovician crustal growth and associated magmatism, represented by the Urra felsic volcaniclastic rocks and associated calc-alkaline granitoids, diorites and gabbros, can be interpreted in terms of the underplating and temporal storage of mantle-derived magmas as the potential source for the “orogenic melts” that were intruded during Early Paleozoic extension. This record of Early Ordovician magmatism has striking similarities with other correlatives from the Iberian, Bohemian and Armorican massifs that are discussed in this paper. This comparison reinforces the probable existence of a large-scale crustal melting process linked to a significant episode of extension on the northern Gondwana margin that probably resulted in the birth of the Rheic Ocean

Noncommutative massive Thirring model in three-dimensional spacetime

We evaluate the noncommutative Chern-Simons action induced by fermions interacting with an Abelian gauge field in a noncommutative massive Thirring model in (2+1)-dimensional spacetime. This calculation is performed in the Dirac and Majorana representations. We observe that in Majorana representation when $\theta$ goes to zero we do not have induced Chern-Simons term in the dimensional regularization scheme.Comment: Accepted to Phys. Rev. D; 9 pages, Revtex4, no figures, references added, minor improvements, Eq.31 correcte

Research of the optical communications groups at University of Aveiro and Institute of Telecommunications - Aveiro Pole

This paper summarizes the research activities of the optical communications group at University of Aveiro and Institute of Telecommunications – Aveiro pole. Several activities like clock recovery systems, both electrical and all optical, electrical equalizers for very high bit rate DST systems, post-detection filters for multigigabit optical receivers, soliton systems, simulation work on WDM, DST, EDFA and short pulse generation for high bit rate systems are presented

Copper- versus palladium-catalyzed aromatization of 2-(methoxycarbonyl) tetralones: synthesis of methyl 1-hydroxy-2-naphthoates

The aromatization of α-tetralones substituted at the β-position by an ester group is reported using either CuI or Pd2(dba)3. In the case of using CuI (10 mol %) as catalyst and Cs2CO3 as base in dioxane, 2-(methoxycarbonyl)-α-tetralones are smoothly converted into the corresponding methyl 1-hydroxy-2-naphthoates at 70 °C under air. Alternatively, Pd2(dba)3 (1.25 mol %) can also be used as catalyst in the presence of K3PO4 as base in toluene also at 70 °C under argon. These are the most straightforward methodologies for the aromatization of these types of α-tetralones. CuI is the catalyst of choice due to higher efficiency, economical and practical reasons.The Spanish Ministerio de Ciencia e Innovación (MICINN) (projects CTQ2010-20387, and Consolider Ingenio 2010, CSD2007-00006), the Spanish Ministerio de Economia y Competitividad (MINECO) (projects CTQ2013-43446-P and CTQ2014-51912-REDC), the Generalitat Valenciana (PROMETEO 2009/039 and PROMETEOII/2014/017) and the University of Alicante are gratefully acknowledged for financial support. Financial support from Brazilian agencies: CAPES-DGU (Project 200/09), Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (BJT-2014), Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (PVE-2015), Conselho Nacional de Desenvolvimento Científico e Tecnológico, Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro and UFRJ is also acknowledged