Presence of iron in polymers extruded with corrosive contaminants or abrasive fillers

Off-site measurements of the dimensions of extruder screws are used to monitor their wear. This wear causes the presence of metals in the processed polymer. We detected the presence of iron in polymers processed with corrosive contaminants or abrasive fillers. To this end we processed poly(ethylene terephthalate), PET, pure or contaminated with poly(vinyl chloride), PVC, and other thermoplastics reinforced with glass fibers, talc or vegetal fibers, and analyzed the metals in the processed materials by X-ray fluorescence spectroscopy. We show that iron dispersed in the polymer melt is generated by corrosion from the PET contaminated with PVC and by erosion from abrasive fillers. The contents of iron in the extruded polymers clearly indicate equipment wear. This contaminant acts as a polymer pro-degradant, decreasing its lifetime. Additionally, we show that the lower concentration of iron for composites with vegetal fibers indicates a lower abrasion in comparison to talc and glass fibers292FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP2010/17804-

The influence of age, sex and visual dysfunction on reading ability in school-children

t. Binocular and accommodative dysfunctions affect the efficiency and coordination of the eyes, and this may impair reading performance. Reading can be evaluated using accuracy and speed measures. In this study, we searched for evidence that dysfunctions of accommodation (i.e. accommodation insufficiency, IA) and binocular vision (i.e. convergence insufficiency, CI) and also hyperopia have impact on reading ability. A sample of 292 children read a text following vision screening. The sample was composed of control children and children with the conditions: AI; CI and hyperopia. Multilinear regression analysis was used to evaluate the influence of variables sex, age and visual condition (control, AI, CI and hyperopia) on reading accuracy and speed. The results showed that ~7% of the variation in reading accuracy was explained by a model where age (p=0.001), and presence of AI (p<0.001) and hyperopia (p=0.019) were statistically significant. On the other hand, ~38% of the variation in the index of speed was explained by age alone (p<0.001). These results confirm the importance of age on children’s ability to read, and suggests that AI and hyperopia, but not CI may affect reading accuracy. Reading speed does not appear to be affected by the presence of binocular or accommodative dysfunction.This work was supported by the Portuguese Foundation for Science and Technology (FCT) in the framework of the Strategic Funding UID/FIS/04650/2013

A controlled aquarium system and approach to study the role of sponge-bacteria interactions using Aplysilla rosea and Vibrio natriegens

Sponge-bacteria interactions are very important due to their ecological and biological significance. To understand the impact of interactions between sponges and bacteria (both associated with and external to sponges) on sponge-associated microbial diversity, sponge metabolite profiles and bioactivity, we used a controlled aquarium system and designed an experimental approach that allows the study of sponge-bacteria interactions in a well-defined manner. To test the feasibility of this approach, this system was used to study the interaction between a sponge Aplysilla rosea and a marine bacterium commonly found in seawater, Vibrio natriegens. Sponge explants were exposed to V. natriegens, at 5 × 106 cfu/ml, and changes were monitored for 48 hours. Pyro-sequencing revealed significant shifts in microbial communities associated with the sponges after 24 to 48 hours. Both the control (sponge only without added bacteria) and Vibrio-exposed sponges showed a distinct shift in bacterial diversity and abundance with time. Vibrio exposure significantly increased bacterial diversity, the abundance of a number of taxa compared to control sponges. The result experimentally supports the notion of dynamic and concerted responses by the sponge when interacting with a bacterium, and demonstrates the feasibility of using this controlled aquarium system for the study of sponge-bacteria interactions.Mohammad F. Mehbub, Jason E. Tanner, Stephen J. Barnett, Jan Bekker, Christopher M. M. Franco and Wei Zhan

Validation of a rapid analytical method by HPLC for determining coumarin in guaco (Mikania glomerata Sprengel) confirmed with mass spectrometry

The species Mikania glomerata Sprengel, popularly known in Brazil as guaco , is widely used as an expectorant to treat respiratory diseases. Its pharmacological activity is mainly attributed to coumarin. The results showed that the method for determining coumarin presented linearity from 0.05 to 0.8 mg mL-1. It was considered selective, accurate, and precise according to the specific resolution from ANVISA, the Brazilian regulatory agency. The proposal of a rapid method for the determining coumarin in extracts of guaco is interesting for routine industrial quality control in order to obtain standardized, efficient, and safe phytotherapic medicines.A espécie Mikania glomerata Sprengel, popularmente conhecida no Brasil como guaco, é amplamente utilizada como expectorante para tratar doenças respiratórias e tem a sua atividade farmacológica atribuída principalmente a cumarina. Os resultados mostraram que o método apresenta linearidade de 0,05 a 0,8 mg mL-1. Ele foi considerado seletivo, exato e preciso. A proposta de um método rápido para determinação de cumarina em extratos de guaco torna-se interessante para a rotina de controle de qualidade industrial, visando à obtenção de medicamentos fitoterápicos padronizados.A espécie Mikania glomerata Sprengel, popularmente conhecida no Brasil como guaco, é amplamente utilizada como expectorante para tratar doenças respiratórias e tem a sua atividade farmacológica atribuída principalmente a cumarina. Os resultados mostraram1811316325The species Mikania glomerata Sprengel, popularly known in Brazil as “guaco”, is widely used as an expectorant to treat respiratory diseases. Its pharmacological activity is mainly attributed to coumarin. The results showed that the method for determinin

D-brane Deconstructions in IIB Orientifolds

With model building applications in mind, we collect and develop basic techniques to analyze the landscape of D7-branes in type IIB compact Calabi-Yau orientifolds, in three different pictures: F-theory, the D7 worldvolume theory and D9-anti-D9 tachyon condensation. A significant complication is that consistent D7-branes in the presence of O7^- planes are generically singular, with singularities locally modeled by the Whitney Umbrella. This invalidates the standard formulae for charges, moduli space and flux lattice dimensions. We infer the correct formulae by comparison to F-theory and derive them independently and more generally from the tachyon picture, and relate these numbers to the closed string massless spectrum of the orientifold compactification in an interesting way. We furthermore give concrete recipes to explicitly and systematically construct nontrivial D-brane worldvolume flux vacua in arbitrary Calabi-Yau orientifolds, illustrate how to read off D-brane flux content, enhanced gauge groups and charged matter spectra from tachyon matrices, and demonstrate how brane recombination in general leads to flux creation, as required by charge conservation and by equivalence of geometric and gauge theory moduli spaces.Comment: 49 pages, v2: two references adde

Software engineering for self-adaptive systems:research challenges in the provision of assurances

The important concern for modern software systems is to become more cost-effective, while being versatile, flexible, resilient, dependable, energy-efficient, customisable, configurable and self-optimising when reacting to run-time changes that may occur within the system itself, its environment or requirements. One of the most promising approaches to achieving such properties is to equip software systems with self-managing capabilities using self-adaptation mechanisms. Despite recent advances in this area, one key aspect of self-adaptive systems that remains to be tackled in depth is the provision of assurances, i.e., the collection, analysis and synthesis of evidence that the system satisfies its stated functional and non-functional requirements during its operation in the presence of self-adaptation. The provision of assurances for self-adaptive systems is challenging since run-time changes introduce a high degree of uncertainty. This paper on research challenges complements previous roadmap papers on software engineering for self-adaptive systems covering a different set of topics, which are related to assurances, namely, perpetual assurances, composition and decomposition of assurances, and assurances obtained from control theory. This research challenges paper is one of the many results of the Dagstuhl Seminar 13511 on Software Engineering for Self-Adaptive Systems: Assurances which took place in December 2013